绿色交通目标下集装箱“公转铁”的CO2减排潜力评估

为提高集装箱“公转铁”减排潜力评估结果的准确性,在分析“公转铁”减排原理的基础上,综合考虑空箱调运和重箱运输“门到门”运输链的干线运输、端点装卸、电力设备作业、集卡短驳、公铁中转等排放,引入反映活动类型、设备结构、能源生命周期排放的参数,对作业活动-方式结构-能耗强度-排放因子（ASIF）方法进行改进,建立“公转铁”减排潜力评估框架。以义乌—宁波港域出口集装箱运输为例,通过实地调研和公开文献获取数据,进行实证研究。结果表明,如果忽略必要因素将会导致每TEU运输需求“公转铁”的CO₂减排率被高估0.50~36.73个百分点;最佳“公转铁”情景可减排3.42万t CO₂,相应减排率为13.58%。研究结果可为政府相关部门客观评估“公转铁”的减排潜力、制定有效的“公转铁”政策措施提供理论支持。     

H_2O_2增效TiO_2/凹凸棒石光催化体系降解亚甲基蓝

以钛酸四丁酯为前驱体,天然凹凸棒石为载体,采用溶胶凝胶法制备了TiO_2/凹凸棒石复合光催化剂,并用XRD、TEM对其进行表征.以亚甲基蓝染料为模拟污染物,采用300 W汞灯为紫外光源,以光催化实验来评价该催化剂的活性,并研究了H_2O_2的引入对光催化活性的影响.实验结果表明,H_2O_2能显著提高染料的脱色效率:亚甲基蓝的初始浓度为50 mg/L,催化体系为2 mmol/L H_2O_2+0.5 g/L TiO_2/凹凸棒石+UV(紫外线),光催化10 min后其脱色率为95%,相对于单独的0.5 g/L TiO_2/凹凸棒石+UV催化体系,其脱色率提高了约50%.全波段扫描显示,加入H_2O_2后,亚甲基蓝在290 nm对应的苯环吸收蜂急剧下降,665 nm对应的最大吸收峰则近乎消失,且没有新的吸收峰产生.     

Uncertainty analysis of CO_2 flux components in subtropical evergreen coniferous plantation

We present an uncertainty analysis of ecological process parameters and CO2 flux components (Reco, NEE and gross ecosystem exchange (GEE)) derived from 3 years’ continuous eddy covariance meas-urements of CO2 fluxes at subtropical evergreen coniferous plantation, Qianyanzhou of ChinaFlux. Daily-differencing approach was used to analyze the random error of CO2 fluxes measurements and bootstrapping method was used to quantify the uncertainties of three CO2 flux components. In addition, we evaluated different ...     

深部咸水层二氧化碳地质储存场地选址储盖层评价

深部咸水层CO2地质储存属于环保型工程项目,开展地质评价来确定良好的储盖层是实现CO2地质储存长期、有效、安全封存的首要前提。储层地质评价内容主要包括储层的物理性质及其注入能力等;盖层地质评价内容主要包括盖层发育特征及封闭能力等。在规划选址到工程选址的不同阶段,储盖层评价的内容和对象应根据不同阶段的目的依次提高精度和量化程度。通过国内深部咸水层CO2地质储存工程场地选址阶段划分,结合储盖层地质评价的主要内容,初步建立了储盖层适宜性评价指标及其分级标准,对国内深部咸水层CO2地质储存工程场地选址中的储盖层地质评价及适宜性评价工作具有一定的指导意义。     

几种再分析地表气温资料在中国区域的适用性评估

应用台站观测资料对ERA-40、NCEP/NCAR、NCEP/DOE和JRA-25等几种再分析地表(2m)气温资料在中国不同区域、不同年代和季节的气候均值、年际变化和变率特征及其气候趋势等所反映出来的适用性问题进行了系统评估.结果表明,几种再分析产品在全国大多数地区的气候变化研究中都具有一定的合理性,特别是1979年以后的资料可靠性更高一些.但相比而言,它们在冬季的可信度一般要高于夏季,东部地区的可信度一般要高于西部地区;ERA-40和JRA-25再分析产品的适用性要高于NCEP/NCAR和NCEP/DOE再分析产品;其中,JRA-25在均值、年际变化和变率特征的描述上具有更高的可靠性,而ERA-40在长期气候变化趋势(44年)的描述上则要明显优于NCEP/NCAR再分析产品.     

珠江三角洲城市群对夏季降雨影响的初步研究

利用TRMM 2A25卫星降水数据和CMORPH同化数据对珠三角洲地区的降水分布特征进行了探讨,观测表明：珠三角城市群区域总体处于降水的低值中心,且对流降雨的低值中心尤为明显;同时近10 a珠三角核心城市区域降雨有减少的趋势,这种降水减少的趋势可能与珠三角城市化效应有关。本文进一步利用WRF模式模拟分析了珠三角城市群发展对夏季降雨的影响,结果表明珠三角城市化使得该区域降雨减少,其原因为城市化使得地表的蒸发减弱及其大气中的水分供应减少,同时也抬升了珠三角区域边界层高度相应增强了低层大气水汽垂直混合。     

Influence of leaf water potential on diurnal changes in CO2 and water vapour fluxes

Mass and energy fluxes between the atmosphere and vegetation are driven by meteorological variables, and controlled by plant water status, which may change more markedly diurnally than soil water. We tested the hypothesis that integration of dynamic changes in leaf water potential may improve the simulation of CO₂ and water fluxes over a wheat canopy. Simulation of leaf water potential was integrated into a comprehensive model (the ChinaAgrosys) of heat, water and CO₂ fluxes and crop growth. Photosynthesis from individual leaves was integrated to the canopy by taking into consideration the attenuation of radiation when penetrating the canopy. Transpiration was calculated with the Shuttleworth-Wallace model in which canopy resistance was taken as a link between energy balance and physiological regulation. A revised version of the Ball-Woodrow-Berry stomatal model was applied to produce a new canopy resistance model, which was validated against measured CO₂ and water vapour fluxes over winter wheat fields in Yucheng (36°57′ N, 116°36′ E, 28 m above sea level) in the North China Plain during 1997, 2001 and 2004. Leaf water potential played an important role in causing stomatal conductance to fall at midday, which caused diurnal changes in photosynthesis and transpiration. Changes in soil water potential were less important. Inclusion of the dynamics of leaf water potential can improve the precision of the simulation of CO₂ and water vapour fluxes, especially in the afternoon under water stress conditions.     

Geochemical evidence of paleogeography and paleoclimate during deposition of the 2nd Member of Kongdian Formation in Kongnan area

The 2nd Member of Kongdian Formation has been made up of a large number of oil shale and mudstone in the Kongnan aera of Huanghua depression around the Bohai Bay. In the Kongnan area, the lake basins were very large and deep during the deposition of the 2nd Member of Kongdian Formation. During that period,the lakes were sealed, uncommunieated with the sea water and the paleoclimate was very warm and wet in Kongnan area. Analyzing the content of the trace element and the rare earth element, carbon and oxygen isotope in the disquisition, The authors prove the two views correct.     

古气候演化特征、驱动与反馈及对现代气候变化研究的启示意义

古气候与现代气候变化研究如何有效结合,特别是古气候研究如何为理解现代气候变化过程提供背景条件、边界约束和理论框架,值得深入探讨。文章以现代、历史时期、全新世、晚第四纪和新生代为时间基线,回顾阐述了过去气候演变特征、成因机制及其对现代气候变化研究的启示意义,探讨了过去与现代气候变化融合研究中存在的不确定性。过去气候演化过程的研究,加深了人们对地球气候系统运行机制的理解。研究表明,各个时期中,地球气候经历了不同相位、幅度和速率的变化,气候系统各分量之间发生了复杂的相互作用,以地表温度为代表的地球表面热力环境演化是各不同阶段气候变化的基本表现形式。全球温度变化不仅受到太阳输出辐射、地球轨道参数和地球构造运动等的影响,而且与地球表层水圈中的海洋、冰冻圈中的大陆冰盖、生物圈中的海洋浮游生物和陆地植被,以及大气圈中的温室气体、粉尘气溶胶、水汽和云等活跃组分之间,存在着多尺度复杂反馈作用。在同一时间尺度上,气候系统分量的互馈通路可能是同向的、可比的,各分量之间的对应关系或具有一致性,研究结论对于预估未来气候变化有借鉴意义;但在不同时间尺度上,气候系统各分量之间的相互联系机制可能难有一致性和可比性,古今互鉴,就需要慎重。

     

Dynamic responses of atmospheric carbon dioxide concentration to global temperature changes between 1850 and 2010

Changes in Earth's temperature have significant impacts on the global carbon cycle that vary at different time scales, yet to quantify such impacts with a simple scheme is traditionally deemed difficult. Here, we show that, by incorporating a temperature sensitivity parameter(1.64 ppm yr~(-1) ?C~(-1)) into a simple linear carbon-cycle model, we can accurately characterize the dynamic responses of atmospheric carbon dioxide(CO_2) concentration to anthropogenic carbon emissions and global temperature changes between 1850 and 2010(r~2 0.96 and the root-mean-square error 1 ppm for the period from 1960onward). Analytical analysis also indicates that the multiplication of the parameter with the response time of the atmospheric carbon reservoir(～12 year) approximates the long-term temperature sensitivity of global atmospheric CO_2concentration(～15 ppm?C~(-1)), generally consistent with previous estimates based on reconstructed CO_2 and climate records over the Little Ice Age. Our results suggest that recent increases in global surface temperatures, which accelerate the release of carbon from the surface reservoirs into the atmosphere, have partially offset surface carbon uptakes enhanced by the elevated atmospheric CO_2 concentration and slowed the net rate of atmospheric CO_2 sequestration by global land and oceans by ～30%since the 1960 s. The linear modeling framework outlined in this paper thus provides a useful tool to diagnose the observed atmospheric CO_2 dynamics and monitor their future changes.