铜与间氯偶氮安替比林显色反应研究及铜的形态分析

在ｐＨ４８的邻苯二甲酸氢钾＿ＮａＯＨ缓冲介质中，Ｃｕ（Ⅱ）与间氯偶氮安替比林形成１∶２的蓝色配合物，其最大吸收峰位于６３０ｎｍ处，表观摩尔吸光系数为４２６×１０４Ｌ·ｍｏｌ－１·ｃｍ－１，Ｃｕ（Ⅱ）的质量浓度在０～２ｍｇ／Ｌ时符合比尔定律。应用该法测定了桃叶及牛肝标样中的铜含量，测定值与标准值一致。结合活性炭分离，建立了铜的形态分析流程，并测定了茶汤中铜的各种主要形态及其分布。     

金属成矿学研究的若干进展

主要讨论近１０年来国内外在金属矿床地质研究中的若干进展，内容包括：成矿地质环境和深部背景；矿床、成矿带和全球的成矿作用演化；成矿系统和成矿动力学；地质流体与成矿作用以及超大型矿床的形成条件等。在这５个重点研究领域中，分别介绍了对它们的研究和已取得的一些进展，又展望了其在今后的研究前景。认为上述５个方面的系统深入研究，将构成２１世纪上半世纪新的成矿理论基础，并将对金属矿产勘查工作有重大影响。     

乌鲁木齐河源1号冰川积累区透底冰芯地层及冰结构分析

对乌鲁木齐河源１号冰川积累区一支深达９１．６４ｍ的透底冰芯进行了详细的层位及冰结构分析，结果表明，在２０ｍ深度以内，很好地保存了原始沉积的特征，但在７０￣８０ｍ深处还发现小密度的乳白色冰占优势的冰层，可能形成于小冰期，中层具有动力变质及再结晶作用共存及反复消长的结构特征（冰晶尺寸、气泡），未见单极大型组构，但出现弱竖环形组构，底层出现弱宝石状的多极大组构。     

高分辨率地震技术探测采空区研究——以贾汪煤矿区为例

高分辨率地震技术可广泛用于工程物探。本文主要利用高分辨率地震勘探探测采空区的位置和范围，为建筑物地基稳定性的评价提供可靠的依据；同时，从理论分析和野外试验两方面探讨了高分辨地震技术的野外数据采集、资料处理和资料解释，并简单介绍了在贾汪矿区的应用效果。研究结果表明，高分辨率地震技术能查明建筑场地内的采空区     

提高迭后地震记录分辨率的频率振幅补偿方法

本论述了提高迭后地震记录分辨率的频率振幅补偿方法原理及实际应用效果，该方法利用了最大方差原理，使地震信号的修正方差模达到极大，迭代计算补偿地震记录的高频成份，并对其补偿后的地震记录振幅谱经予加权标定，使之逼近于资料实际反射系数振幅谱，从而达到提高地震记录分辨薄层的能力。     

淮南谢—矿煤的组成对甲烷吸附性的影响

从淮南谢—矿五层煤（Ｃ＿（１３）、Ｂ＿（１１ｂ）、Ｂ＿（１０）、Ｂ＿（４ｂ）和Ａ＿３）中精选出镜煤、壳质暗煤、惰性暗煤及构造煤，采用重量法，分别测定它们的甲烷吸附量，从而研究不同成分组成的煤其甲烷吸附性能。     

从天山乌鲁木齐河源1号冰川变化估计近百年来该地区夏季升温

通过冰川波动历史来揭示气候变化是一种重要的方法。然而，以往有关这一方面的研究大都是一些定性的。文章试图依据冰种变化来定量的研究气候变化，并且通过近百年来天山乌鲁木齐河源１号冰川的变化，揭示出本世纪以来该河源地区夏季气温上升约０．２３￣０．２５℃，同时，对于该冰川不同长度规模时的气候敏感性也进行了讨论。     

Kinetics of the Gas-Phase Reactions of OH Radicals, NO3 Radicals and O3 with Three C7-Carbonyls Formed From The Atmospheric Reactions of Myrcene, Ocimene and Terpinolene

Rate constants for the gas-phase reactions of OH radicals, NO₃ radicals and O₃ with the C₇-carbonyl compounds 4-methylenehex-5-enal [CH₂=CHC(=CH₂)CH₂CH₂CHO], (3Z)- and (3E)-4-methylhexa-3,5-dienal [CH₂=CHC(CH₃)=CHCH₂CHO] and 4-methylcyclohex-3-en-1-one, which are products of the atmospheric degradations of myrcene, Z- and E-ocimene and terpinolene, respectively, have been measured at 296 ± 2 K and atmospheric pressure of air using relative rate methods. The rate constants obtained (in cm³ molecule^–1 s^–1 units) were: for 4-methylenehex-5-enal, (1.55 ± 0.15) × 10^–10, (4.75 ± 0.35) × 10^–13 and (1.46 ± 0.12) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3Z)-4-methylhexa-3,5-dienal: (1.61 ± 0.35) × 10^–10, (2.17 ± 0.30) × 10^–12, and (4.13 ± 0.81) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3E)-4-methylhexa-3,5-dienal: (2.52 ± 0.65) × 10^–10, (1.75 ± 0.27) × 10^–12, and (5.36 ± 0.28) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; and for 4-methylcyclohex-3-en-1-one: (1.10 ± 0.19) × 10^–10, (1.81 ± 0.35) × 10^–12, and (6.98 ± 0.40) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively. These carbonyl compounds are all reactive in the troposphere, with daytime reaction with the OH radical and nighttime reaction with the NO₃ radical being predicted to dominate as loss processes and with estimated lifetimes of about an hour or less.     

Environmental Properties of Minerals and Contaminants Purified by the Mineralogical Method

The investigation of the environmental properties of minerals, i.e., environmental mineralogy, is a branch of science dealing with interactions between natural minerals and spheres of the Earth surface as well as a reflection of global change, prevention of ecological destruction, participation in biomineralogy, and remediation of environmental pollution. Pollutant treatment by natural minerals is based on the natural law and reflects natural self-purification functions in the inorganic world, similar to that of the organic world - a biological treatment. A series of case studies related to natural self-purification, which were mostly completed by our group, are discussed in this paper. In natural cryptomelane there is a larger pseudotetragonal tunnel than that formed by [MnO6] octahedral double chains, with an aperture of 0.462-0.466 nm2, filled with K cations. Cryptomelane might be a real naturally-occurring mineral of the active octahedral molecular sieve (OMS-2). CrⅥ-bearing wastewater can be treate