G-Probe-1 - An International Proficiency Test for Microprobe Laboratories - Report on Round 1 : February 2002 (TB-1 Basaltic Glass)

Results are presented for round one of a new international proficiency testing programme designed for microprobe laboratories involved in the routine analysis of silicate minerals. The sample used for this round was TB-1, a basaltic glass fused and prepared by the USGS. Thirty nine laboratories contributed data to this round, the majority of major element results being undertaken by EPMA and the majority of trace elements by LA-ICP-MS. Assigned values were derived from the median of results produced by nine selected laboratories that analysed powdered material by conventional ICP-MS, INAA and XRF techniques using bulk powders of the sample. Submitted microprobe results were evaluated using a target precision calculated using the Horwitz function, adopting the same criteria as those used for "applied" geochemistry laboratories in the companion GeoPT proficiency testing programme for laboratories involved in the routine bulk analysis of silicate rocks. An evaluation of results from participating microprobe laboratories indicated that overall, data were compatible with this precision function. A comparison between the performance of bulk and microprobe techniques used in the analysis of the basaltic glass showed remarkably good agreement, with significant bias only observed for the major oxide MgO.     

Sulfur Content and Isotopic Ratio of Cambro-Ordovician Carbonate Rocks from South Korea: A Possible Source for Mesozoic Magmatic-hydrothermal Ore Sulfur

Abstract: Carbonate rocks of Cambrian (18 samples) and lower-middle Ordovician (11 samples) ages from South Korea were analyzed for sulfur contents of structurally substituted sulfate (SSS) and sulfides and their δ³⁴S values. The δ³⁴S values of SSS ranging from +25.9 to +45.2 permil, are averaged as +33.6 and +33.5 permil for the Cambrian and Ordovician rocks, respectively, which indicate high δ³⁴S values of the Cambro-Ordovician seawater. The SSS contents in the carbonate rocks are low being 2.9 to 17.3 ppm S (averaged as 7.0 ppm S). Sulfide sulfur, on the contrary, is much abundant containing 3 to 1,880 ppm S and the δ³⁴S values range widely between –17.6 and +31.1 permil. Sulfide sulfur of the studied rocks excluding impure carbonates has an average content of 187 ppm S and δ³⁴S value of +12.8 permil (n=24). The estimated δ³⁴S (sulfate–sulfide) values, which range from 13.8 to 25.4 permil in general with a few exceptions from 36.5 up to 52.3 permil for some impure carbonates, may provide evidence for the persistent oceanic anoxia with its temporary recovery during the Cambro-Ordovician time.
The SSS and sulfide sulfurs have often higher δ³⁴S values than the Mesozoic-Cenozoic ore sulfur (Ishihara et al., 2000). Since carbonate rocks are very reactive with circulating hydrothermal ore solution, high δ³⁴S values of the Korean ore deposits might be caused to some extent by ³⁴S enrichment from the host carbonates, resulting in the low SSS contents observed.     

深井水氡主要干扰因素及映震效能分析

对甘肃省玉门青6井和平凉泾川泾3井两口深水井的水氡及辅助项目观测资料采用多元逐步回归、相关距平、一阶差分等方法进行处理，分析并排除了主要干扰因素，显示出两井在肃南5.4级、托莱6.0级和礼县5.1级地震前有明显异常，对两井的映震效能和地震预报前景进行了评价。     

中原地区M≥6级地震后的减(增)震效应

通过对中原地区1500年－2000年所有19次M≥6级地震后空间图像的分析，初步认为M≥6级地震发生后平均63年内，在距原震中平均176km内无M≥5级地震发生，全部19次震例均呈现出内部减震效应，而在其外围出现地震增强的活动图像特征，增震效应对应率为72％。这种强震后的减（增）震效应，不仅对地震危险性分析，而且对1年尺度以上的地震趋势预测均有一定的意义。     

Verification of the dualism ordering method by the canonical correspondence analysis: fish community samples

Two ordination techniques (Romaniszyn diagram, RD, and Canonical correspondence analysis, CCA) were applied to the same data set (fish assemblage composition along two Paraná river tributaries and associated environmental variables), to identify spatial community patterns and further to evaluate the performance of RD. The major patterns in these Brazilian streams were successfully revealed by both methods (i.e. clear separation of both tributaries on the basis of fish assemblage composition and environmental factors), but more complex situations may limit the application of RD in comparison with CCA.     

ARTIFICIAL NEURAL NETWORK CORRECTION OF ROUGH ERRORS OF OBSERVATIONS*

In the context of tower measured radiation datasets.following the correction principle meeting a diagnostic equation in data quality control and in terms of a technique for model construction on data and ANN (artificial neural network) retrieval for BP correction of radiation measurements with rough errors available,a BP model is presented.Evidence suggests that the developed model works well and is superior to a convenient multivariate linear regression model,indicating its wide applications.     

流动成像测井研究进展

流动成像测井属于对非均匀介质动态的非线性测量，通过对油气井内多相流体信息的投影扫描和反演处理，实时成像显示流体分布及流动状况，国外研制的电导法，电容法仪器采用电导探针或电容元件构成阵列测量探头，分别利用油气与水的导电特性和介电特性差异辨识井内流体，对流动截面的测量局限于个别点上，已在水平井中见到应用效果，但对物场信息投影测量的数据量和分辨率未能满足成像要求。我国提出的电磁法采用环状阵列电极构成测量探头，综合利用油气与水的导电和介电特性差异辨识井内流体，可以测量获得多相流体流动截面的清晰图像，为研究开发全新的流动成像测井系统奠定了良好基础。     

2001年11月14日新疆-青海交界8.1级地震

简要介绍了2001年11月14日新疆－青海交界8．1级地震的预测情况，给出了中、美、日等对此次地震的震源参数测定和震源机制，以及余震的分布和加卸载响应比随时间的变化。进而对震区近期地震趋势进行预测。     

A discussion on the records of water level ‘precursors’ in Well Shuozhou, Shanxi Province

A lot of slow fluctuations of water level have been observed in the original recording maps of subsurface fluid in Well Shuozhou, Shanxi Province. Some typical recording maps of the “precursors” are introduced in the paper and the features of the “precursors” recorded by the well are analyzed. The results show that 38% strong earthquakes possess this kind of record, which has a fluctuation period arranging from several to tens of minutes and appear mostly two days before the earthquakes. Moreover, the mechanism, transmission and responding conditions of well water level are discussed, as well as the scientific meaning and practical value of the “precursor” of the well water level in earthquake predictions. Foundation item: State Natural Science Foundation of China (19973011).     

大姚地热动态特征分析

通过大姚高精度水温观测井水地质、井孔条件的分析，震例观测资料、实验观测数据的处理，以及井水水质分析结果，表明大姚水温周期性变化的突出位置是井深75m左右，根本原因是该地层石膏脉稳定释热，含水层热水与井内冷水混合过程中，在通道内形成钙盐类沉淀物（如CaSO4CaCO3），堵塞对流通道，含水层内外压差突破被阻塞通道，热水反复侵入井内，便形成水温周期性变化。地震的孕育、发生和调整过程，由于应力场作用，产生附加地热场，水温基值发生变化，周期畸变或消失，这种附加地热动态是可以恢复的。所以认为大姚地热动态是井区特殊地层地热信息的反映。