Experimental Studies of the Solubility of Cassiterite and the Extraction of Tin from Granitic Melts

Experiments indicate that the solubility of cassiterite can be enhanced by increasing either acidity or alkalinity in hydrothermal solutions as a consequence of the duality of tin.The minimum solubility of cassiterite is found in neutral solutions.F-and CL-coordination compounds of Sn can alternate with hydroxyl coordination compounds with changing pH in the solutions.In this case,F^- and Cl^- and OH^- can be substituted with each other.The dissolution reaction of cassiterite is of reducing nature.High temperature and acidic reducing environment are favorable for the dissolution of cassiterite and the trans-port of Sn^2 compounds in fluids or solutions.High-temperature fluoride and chloride fluids can all dissolve,extract and enrich Sn to form F^- and /or Cl-coordination compounds,However,Fplays a more important role than Cl.F-coordination compounds are more stable and efficient than Cl-coordination compounds during the transport an enrichment of Sn in melts or solutions.The solubili-ty of cassiterite and the amount of Sn extracted from granitic melt depend not only on T,P,pH and Eh in the fluids or solutions,but also on the amounts of dissociated F^- and Cl^- in the fluids.     

香花岭矿田矿床成矿分带及其成因探讨

本文概括了香花岭矿田的矿化分带型式,并从不同形态矿体在空间上的组合、矿化元素的空间分布及富集规律、矿物共生组合的空间分布及金属矿物中微量元素的含量变化等方面讨证了矿床的分带型式。作者认为,多次的构造岩浆活动和成矿的多阶段性、矿液性质的演化和成矿物理化学条件的规律变化,是产生矿化分带的主要原因。     

钨、锡流-熔分配实验结果及其矿床成因意义

本文用实验确定了钨、锡在成分不同的花岗质熔体相与共存水热流体相的流-熔分配系数(D_(Me)~(V/L))及其与介质溶液(NaF,KF,HF,NaCl等水溶液)摩尔浓度间的函数关系。实验结果表明,钨、锡的分配行为明显不同。在相同条件下,随体系的不同,D_W~(V/L)比D_(Sn)~(V/L)大几倍至二十倍。钠和钾对钨、锡的流-熔分配行为的影响基本相同,而氟和氯对钨、锡的分配行为的影响相差甚远,花岗质熔体的主成分对D_W~(V/L)和D_(Sn)~(V/L)有复杂的影响。利用这些结果探讨与花岗岩有关的钨、锡矿床的成矿机理,得出了一些与前人不同的新认识。     

浙江洋滨斑岩锡矿的同位素地质研究

洋滨斑岩锡矿的含矿母岩为燕山晚期黄玉花岗斑岩。高的（＾８７Ｓｒ／＾８６Ｓｒ）１和＾２０７Ｐｂ／＾２０４Ｐｂ值表明，它主要来源于地壳物质。根据氧，氧，硫，铅和锶同位素数据并结合矿床地质特征，笔者认为，成矿流全由岩浆水和大气降水混合组成，成矿物质主要原源于花岗斑岩，部分可能源于基底变质岩。     

内蒙古敖脑达坝斑岩型铜银锡多金属矿床围岩蚀变特征研究

在给出明确的命名原则基础上，将矿床的蚀变围岩划分为五类：黄玉石英交代岩、绿泥石石英交代岩、绢云母石英交代岩、电气石绿泥石化花岗斑岩、钾长石化花岗斑岩。在平面上岩体中心部位为黄玉石英蚀变带，其两侧为绿泥石石英蚀变带；在剖面上由上向下依次出现绿泥石石英蚀变带→黄玉石英蚀变带→绢英岩化带→钾化带→（电气石）绿泥石化带。从蚀变岩石地球化学角度阐述了铜银锡各自不同的成矿部位。