桂西北地区三条铷—锶等时线年龄

铷锶等时线法测定地质体年龄是目前普遍应用而准确度较高的方法之一,用该法测得金牙金矿床(JY金矿床)的成矿年龄为206Ma±12,为中三叠世晚期;含金黄铁矿、毒砂矿物包体年龄为276Ma±28,代表成矿物质来源地层的时代,和桂西基性岩时代相同。用铷锶等时线法测得桂西北地区辉绿岩时代为263.1Ma,和峨眉山玄武岩相当,属海西晚期。因此,有根据认为,金牙金矿床的硫砷金等成矿物质主要来自下伏晚二叠世基性岩和基性火山碎屑沉积岩。     

湖南道县正冲稀有金属云英斑岩的特征和成因

正冲云英斑岩产于燕山期金鸡岭复式花岗岩基内,富含锂、铷、锡、铯、钨等稀有金属元素,岩体即是矿体。初步研究表明,它是一种新的岩浆岩类型和矿床类型,由富含稀有金属的云英质岩浆超浅成结晶而成。这种云英质岩浆是在富氟、锂花岗质岩浆液态分异作用的基础上进一步演化形成的。     

碳棒涂膜式PVC膜铯离子选择电极的研制和应用

本文作者研制成功以四苯硼铯为活性物质的碳棒涂膜式PVC膜铯离子选择性电极。电极最佳膜组成:四苯硼铯5mg,邻苯二甲酸二丁酯0.4ml,硝基苯0.2ml,PVC粉0.2g。电极性能优良,制作简单,操作方便。结合大粒度磷钼酸铵和结晶形锑酸分离K~+,Na~+,巳将此电极用于卤水样中铯的测定,结果令人满意。     

Geochemistry of the Baishitouquan Amazonite—and Topaz—bearing Granite in the Mid—Tianshan Belt,Xinjiang,China

The Baishitouquan amazonite and topaz-bearing granite is one of the typical high-rubidium and high-fluorine granites in the eastern part of the Mid-Tianshan belt. This intrusion is in sharp contact with Mid-Proterozoic schists, gneisses and marbles, and is composed of four zones transitional from the bottom upwards: leucogranite, amazonite granite, topaz-bearing amazonite granite and topaz quartz albitite. The Baishitouquan granite contains highly ordered K-feldspar, Li-rich mica, Mn-rich garnet, α-quartz and low temperature zircon and is chemically high in Si, K, Na, Al, Li, Rb, Cs and F, and low in Ti, Fe, Ca, Mg, P, Co, Ni, Cr, V, Sr and Ba, with Na₂O<K₂O. Amazonite from the amazonite granite zone contains 1867 ppm Rb. The F contents of bulk rocks are 3040 and 4597 for the amazonite granite and topaz-bearing amazonite granite zones, respectively. These two zones have δ¹⁸O values of 8.97–9.85‰ (SMOW) and show flat REE distribution patterns with strong Eu depletion. K-Ar and Rb-Sr ages of this intrusion are 226. 6 Ma and 209. 6 Ma respectively, with an initial⁸⁷Sr/⁸⁶Sr ratio of 0.987±0.213. The Baishitouquan granite is the product of crystallization of a low temperature, and water, rubidium and fluorine-rich magma, which may have been derived from partial melting of muscovite-rich crustal rocks. Consolidation of this granite involved two contrasting and successive stages: melt crystallization and hydrothermal metasomatism and precipitation. Various geological features of this granite were formed during the transition from the magmatic to the hydrothermal stage.     

陕西岐山黄土剖面Rb、Sr组成与高分辨率气候变化

陕西岐山五里铺全新世黄土剖面层次结构清晰完整。通过对该剖面Rb,Sr含量和磁化率系统测定表明，黄土中Rb,Sr含量和Rb/Sr值明显不同于古土壤，它们作为气候替代指标比磁化率更灵敏，分辨率更高。Rb,Sr高含量及低Rb/Sr值指示冬季风占优势的干旱期，相对低的Rb,Sr含量及高的Rb/Sr值指示夏季风占优势的湿润时期。揭示在大约6000－5000aBP曾出现一次以干旱为特征的明显气候恶化期，使全新世“大暖期”分裂形成两个主要的土壤期。黄土高原南部自全新世以来，经历了黄土沉积→土壤发育→黄土覆盖→土壤再度发育→黄土堆积及现代表土的发展演化阶段。     

侵入火山碎屑岩中的铷—锶系统

对泛高加索山脉前脊的华力西晚期流纹质侵入凝灰岩，利用Ｒｂ－Ｓｒ同位素素统来重建侵入火山碎屑岩的历史，在侵入火山碎屑岩建造中，石英和未蚀变黑云母中熔融包裹体的Ｒｂ－Ｓｒ系统可作为岩浆期的指示剂；钾长和钠长石的同位素系统可作为热液期的指示剂；绿泥石的Ｒｂ－Ｓｒ系统可作为风化物的成岩作用期的指示剂。