Electronic Structures of Square Planar Coordinated Transition Metal Ions in Compounds with Gillespite Structure

Electronic structures of square planar coordinated transition metal ions in BaCuSi₄O₁₀ and CaCrSi₄O₁₀ are investigated using the ligand-field theory (LFT), angular overlap model (AOM) and iterative extended Hückel molecular orbital theory (IET). The electronic energy levels of the natural mineral dioptase are also investigated, in which the Cu²⁺ ions occupy the sites of pseudo D_4h symmetry. Both LFT and AOM predict that the crystal-field levels of transition metal ions in these compounds follow such an order that E (²B_1g <E(²B_2g <E(²A_1g )<E(²E_g ), and the frequencies of the crystal-field transitions obtained from point charge calculations are in good agreement with those observed. However, the energy-level order cannot be determined unambiguously from the IET calculation because it depends on the values of parameters chosen for the calculation.     

细分红外光谱遥感图象色调异常机理初探——以新疆阿尔泰某多金属矿区为例

本文以新疆阿尔泰某多金属矿区为例,对岩矿光谱特征、不同岩性段岩石化学特征、细分红外光谱遥感图象色调异常进行研究并通过野外验证后提出:Fe³⁺除在900nm 处具有强吸收特征外,在2150nm 附近有一个反射峰特征;细分红外光谱遥感图象色调异常的形成机理是与 Fe³⁺的2150nm 附近的反射峰特征有关的综合光谱信息的反映。     

Pressure Solution of Sulphides in Some Massive Sulphide Zinc—lead Deposits of Western Canada：Its Significance in Mobilization of Ore—forming Materials

Pressure solution is a common phenomenon in massive sulphide zinc-lead deposits of western Canada and may have been an important factor leading to the mobilization of ore-forming materials during diagenesis, deformation and metamorphism of sedimentary ores.The control of ductile shear zones over gold mineralization could be explained in view of pressure solution of gold-bearing miner-als under shearing stress and the tesultant mobilization of this metal.     

一株红酵母的抗镉机制

研究了分离自矿区土壤的一株对镉具有较强抗性和富集能力的红酵母菌(Y11)的抗镉机制.结果发现不同方式处理的菌体吸附的镉在细胞不同部位的分布不同,在菌体培养过程中添加浓度为100mg/L镉时,菌体吸附的镉有3.29%进入细胞内,但用在有镉和无镉条件下培养好的菌体,冻干后吸附镉,菌体吸附的镉只有1%可进入原生质体,其余99%都分布在细胞壁周围.利用碱、乙醇-氯仿和蛋白酶分别对Y11细胞与细胞壁进行处理,对其吸附镉的能力有不同影响,红外光谱分析结果表明几丁质酰胺基团主要参与吸附作用.探讨了Y11产金属硫蛋白(MT)的情况,结果表明镉诱导能明显促进Y11菌体产生MT的量,菌体经诱导后MT产量达到638.8μg/g,是非诱导菌体的85倍,远大于报道的酵母菌中MT的产量.纯化后的MT经SDS-PAGE电泳检测,分子量为6500Da.