略阳东沟坝金、银、铅、锌、黄铁矿—重晶石型矿床的成因——成矿物理化学条件及稳定同位素地球化学研究

东沟坝金、银、铅、锌、黄铁矿重晶石型矿床的形成明显可以划分为两个不同的成矿期,本文主要讨论了变质热液叠加改造期的成矿物理化学条件。在此期间,成矿温度为176—263℃,成矿压力为50—100MPa,成矿流体的密度为0.845—0.935g/cm~3,成矿流体的盐度3×10~(-2)—6×10~(-2)(NaCl),成矿流体的氧逸度为10~(-31)—10~(-37),硫逸度10~(-15.7)—10~(-11.6),成矿流体的pH上限=5.80—6.00,pH下限=5.30—4.70,成矿流体的化学组成类型为Na~+-Ca~(2+)-K~+-Mg~(2+)-Cl~--HS~-(SO_4~(2-))-HCO_3~-型、金主要以硫金配合物的形式迁移。黄铁矿的δ~(34)S_(CDT)为0.1×10~(-3)—10.5×10~(-3)、重晶石的δ~(34)S_(ODT)为16.9×10~(-3)—20.3×10~(-3)、成矿流体的δ~(34)SΣ_S介于上述两者之间、明显偏离幔、源硫、系火山成因硫同海相硫的混合体。铅同位素组成在铅同位素演化曲线图解上,落在造山带,上地壳演化曲线附近,反映其多来源特征。成矿流体的δD积δ~(18)O_(H_2O)的变化范围较大,显示出海水变质水和大气降水的三要特征,说明东沟坝矿床的成矿流体的多来源特征。并指出该矿床为一受变质同生的火山沉积型金银多金属矿床。     

银催化HDEA电化学发光法测定矿样中的痕量银

在碱性介质中,痕量Ag(Ⅰ)对新试剂6-(2-羟基-4-二乙基氨苯偶氮)-2,3-二氢-1,4-酞嗪二酮(简称HDEA)的电化学发光具有显著的催化作用。基于此,提出了HDEA-KCI-KOH体系测定矿样中痕量Ag的新方法。方法的检测限为2.0×10~(-8)mol/L Ag,线性范围为5.0×10~(-8)—3.0×10~(-6)mol/L Ag。采用巯基棉富集分离,应用本法测定一些矿样中的Ag,结果良好。     

A New Variety of Mineral—Argentian Mercurian Gold

Argentian mercurian gold,golden-yellow in colour,is a variety of native gold containing Ag and Hg,coccurring as hexagonal and tetragonal crystals in hairy,milk-droplet or irregular forms.Its microhardness Hv=91kg/mm^2,equivalent to 3.04on Mons‘scale,and the reflectance is 70.35%(589nm).Chemical analysis gave:Au 56.05-67.33,Ag18.29-31.06 and Hg 10-14.82%,as well as minor Cu.In a few samples Bi or Fe was also detected.The simplified formula is (Au0.52Ag0.36Hg0.09Cu0.02)0.99.X-ray analysis suggests the mineral is of isometric system,with space group=Oh^5-Fm3m,a0=0.40803nm,V=0.06739nm^3,and Z=4.Argentian mercurian gold occurs in a Ag-multimetal deposit at Xiacun,Baiyu County,Sichuan Province,As observed in the mining district,the mineral is distributed along the fissures of the main metallic minerals pyrite,tetrahedrite,chalcopyrite,arsenopyrite,galena,sphalerite,etc.,or in the sulfide veinlets developed in the.fissures of these minerals.Also found in the mineral deposit are native gold,argentite,sulvanite,bournonite,boulangrite,etc.     

Exhalites Associated with Pb-Zn Mineralization in Devonian System and Their Prospecting Implications,Qinling,China

The exhalation origin of the ankerite-siliceous rocks associated with Pb-Zn mineralizations in the Devonian system of Qinling is discussed in the light of geologic setting,sedimentary-tectonic environment,lithological and chemical characteristics.On this basis,criteria for distinguishing them and their potential role as an indicator in prospecting are described.Ankerite-siliceous rocks are developed in the strata-bound Pb-Zn polymetallic belt in the Devonian system of Qinling.They are microcrystalline,dark grey and compact in appearance and are commonly carbonaceous,As a persistent ore-bearing horizon in the region,their genetic relation to the Pb-Zn deposits in generally accepted.However,a consensus has yet to be reached among geologists concerning their origein as a product of hydrothermal metasomtism at the late stage of sedimentation or as exhalite resulting from submarine exhalation.Accumulating evidence from direct observations on modern submarine hydrothermal systems strongly indicates that seafloor exhalation is a much more common geologic process than previously thought nd its metallogenic implications have long been overlooked.Characteristics of the ankerite-siliceous rocks as a product of exhalation and their significance as a guide in prospecting are described on the basis or geological setting,lithology,lithochemistry,REE,and isotopic and trace element features.     

云南澜沧老厂银铅矿床环形构造研究及其地质效果

根据老厂地区遥感图像上环形影像特征及对应地面环形构造的产出地质构造环境分析,结合岩浆岩的发现及围岩蚀变、矿床地质、地球化学特征等,证实该环形影像为隐伏花岗岩体上侵、成矿热液上涌形成的环形构造的反映。老厂银铅矿床不是火山岩矿床,而是与隐伏岩体有关的中偏高温热液的多因复成矿床,并伴有银铅锌和铜金两种矿床产出。通过预测,在矿区深部已新找到了中型以上的铜矿床及小型以上的金矿床。