Geochronology of the Dahongshan Group

The Dahongshan Group is divided into five formations from the bottom to the top: the Laochanghe Formation; the Manganghe Formation; the Hongshan Formation, the Feiweihe Formation and the Potou Formation. As can be seen from the U-Pb concordia plot for zircon fractions collected from the metamorphic sodic lava of the Hongshan Formation, the upper intersect age with the concordia is 1665.55 _-10.86 ^+13.56 Ma. Sm-Nd dating of four whole-rock samples and one hornblende from the Manganghe and Hongshan formations yielded an isochron age of 1657 ± 82 Ma. This result is in good agreement with the zircon U-Pb age and thus can represent the formation age of the Dahongshan Group. The initial¹⁴³Nd/¹⁴⁴Nd ratio is estimated at 0.510646. with ENd (T) = + 3.1 ± 1.8. In addition the Dahongshan Group rocks are characterized by low REE contents, with δEu>1. All this goes to show that the original rocks of the Dahongshan Group were derived from a depleted mantle. The calculated Sm-Nd model ages range from ∼ 1900 to ∼ 2000 Ma. representing the time of crust/ mantle differentiation in the area studied. From the above results, in conjunction with the time-scale scheme for China, the Dahongshan Group should be assigned to the Middle Proterozoic.     

桂东南富钾岩浆岩岩的Nd同位素组成：华南中生代地幔物质上涌事件

广西东南部罗容杂岩体由辉长岩－闪长岩－二长岩－正长岩组成，马山由碱性辉长岩－正长岩－花岗闪长岩－花岗岩组成。它们富K、富大离子亲石元素（LIL），无Nb、Ta负异常等特征表明它们是形成于板内环境的钾玄质侵入岩。罗容杂岩体的各种岩石和马山的基性岩的εNd(T)稍低，为－0．6，此岩石单元是由幔源岩浆加热地壳使之熔融的壳源岩浆形成的，并伴有幔源岩浆的混合或交换。此二杂岩体形成于拉张构造环境。地幔物质上涌导致了中生代华南地壳张裂以及华南大规模花岗岩和相关矿床的形成。     

某些含钕固体吸收谱的初步研究

本文通过对三种含钕固体,包括玻璃、陶瓷釉层和NdP_5O_(14)晶体中Nd~(3+)的吸收谱进行测定,解释了这三种物质的呈色机理,探讨了在固体中引起Nd离子吸收光谱变化的因素,并给出了在谱图中各个吸收峰所对应的能级。     

The Geochemical Evolution of the Proterozoic Continental Crust in Northwestern Jiangxi and Western Zhejiang,China

The pertochemistry and Sm-Nd isotopic compositions and the geochemical characteristics of REE,U,Th,etc..in the Late Proterozoix and Early Palaeozoic strata in northwestern Jiangxi and western Zhejiang provinces are described in this paper.It seems to be sure that the middle Proterozoic strata of southeastern China are low in the degree of matrration .The strata contain much mantle-derived material.At the end of Late Proterozoic there was an abrupt turn with respect to the crustal geochemical evolution of the eastern part of South China .Since then ,the geochemical environment has undergone a change from a simple reducing environment to a complex oxidizing-reducing environ-ment, which would be geochemically beneficial to the formation of Late Sinian to Early Cambrian U-bearing formations.     

中国北方元古宙沉积岩中自生稀土矿物特征及其意义--以北京、大连地区为例

大连震旦系十三里台组首次发现自生稀土元素矿物独居石后 ,在北京十三陵中元古代长城系常州沟组、串岭沟组和大红峪组又发现了自生的独居石以及其他磷酸盐和硅酸盐稀土矿物。自生稀土矿物的形成和岩石中稀土元素含量较高有关 ;电子探针背散射图像和 P、Th、L a、Ce、Nd、Y等元素面分布图像研究表明 ,沉积岩中的自生稀土矿物与岩浆岩、变质岩和碎屑成因的截然不同。本文首次报道了元古宙长城系常州沟组沉积岩中碎屑锆石边部成岩过程中形成的自生磷钇矿。中国北方元古宙泥砂质碎屑沉积岩普遍具有高稀土组合 ,许多地区都可能存在独居石等自生稀土矿物 ,如天津蓟县、辽西、辽南和宣化等地 ,为利用离子探针 (SHRIMP)确定其同位素地质年代提供了可能。此外 ,本文对比了大连震旦系自生独居石和内蒙白云鄂博矿区东矿的独居石晶形和化学成分的相似性 ,再一次提出中国北方元古宙富稀土地层可能是内蒙古白云鄂博巨型稀土元素矿床的矿源层问题。     

大别山麻粒岩和TTG片麻岩的Sr,Nd,Pb同位素地球化学

北大别4个麻粒岩和4个TTG片麻岩样品的Sr,Nd同位素分析结果表明，样品普遍具有较高的锶同位素比值（^87Sr/^86Sr=0.7066-0.7461)，较低的Nd同位素比值（^143Nd/^144Nd=0.5108-0.5124)，表现出明显的壳源特征，结合铅同位素的组成来看，北大别麻粒岩及TTG片麻岩的同位素成分相当于－下地壳。岩石的特源为古老的地壳，大约在2－3Ga之间，少数样品的同位素特征可能暗示源区有年轻地壳物质的加入。     

对扬子克拉通西缘四川康定—冕宁变质基底的新认识——来自Nd同位素的证据

通过对四川冕宁沙坝及康定－泸定地区的斜长角闪岩－TTG片麻岩的系统Sm-Nd同位素的测定，在该区首次获得706Ma的Sm-Nd等时线年龄。据此等时线年龄及其他样品的Nd亏损地幔模式年龄证明长期以来这套被当作太古宙－古元古代的变质岩是新元古代大陆裂解与其后紧接着的地幔柱引起的热变质作用的产物。与已有数据相结合，初步认为扬子克拉通目前所出露的基底没有统一演化历史，对扬子克拉通的基底有待更深入的研究。     

西藏亚东淡色花岗岩Rb—Sr和Sm—Nd同位素研究——关于其年龄和源岩的证据

对西藏亚东淡色花岗岩Rb-Sr和Sm-Nd同位素的详细研究表明,亚东淡色花岗岩Rb-Sr和Sm-Nd同位素组成十分不均匀,其初始Sr值和ε-(Nd)(13 Ma)分别介于0.756～0.775和-11.6～-16.3。由于存在着显著的同位素变异,而难以获得其全岩Rb-Sr等时线年龄。但研究获得了12.9±0.95Ma矿物—全岩Rb-Sr等时线年龄,其锶初始值为0.7744±0.0008,该年龄可以与高喜马拉雅带其他淡色花岗岩的年龄对比。Rb-Sr和Sm-Nd同位素组成显示亚东淡色花岗岩的源岩很可能是聂拉木群副变质岩。年龄统计分析表明,喜马拉雅淡色花岗岩是在地壳伸展和快速隆起背景下形成的,因此它的形成年龄是碰撞造山后地壳强烈活动和快速隆起的重要标志。     

粤西连阳复式岩体的地球化学特征及其成因研究

粤西连阳复式岩体由燕山早期连阳花岗岩岩体(锆石 U-Pb 年龄为144.3±0.8Ma)和燕山晚期白浆花岗岩岩体(锆石 U-Pb 年龄为106.4±0.7Ma)组成。这两个岩体在岩石化学上均富硅,属准铝质,并相对富钾。在微量元素组成上,连阳岩体和白浆岩体都强烈亏损 Ba、Sr 和 Ti,轻微亏损 Nb 和 Ta。两岩体的稀土元素特征类似,总量比较高,分别为187.6～300.6×10~(-6)和185.5～294.3×10~(-6),轻稀土富集,LREE/HREE 分别为4.17～9.28和4.13～7.08,(La/Yb)_N 分别为3.66～9.03和3.29～5.16,Eu 明显亏损,δEu 值分别为0.04～0.53和0.04～0.16。连阳岩体的ε_(Nd)(t)为-9.1～-7.6,白浆岩体的ε_(Nd)(t)为-9.8～-7.8,两者具有相似的 Nd 同位素组成。钕模式年龄分别为1.56～1.68Ga 和1.54～1.71Ga。研究表明,连阳复式岩体燕山期花岗岩形成于地壳剪切-拉张的构造背景下,是中元古地壳部分熔融的产物。     

Carbon and Oxygen Isotopic Characteristics of REE—Fluorocarbonate Minerals and Their Genetic Implications,Bayan Obo Deposit,Inner Mongloia,China

REE－fluorocarbonates as major REE minerals in the Bayan Obo deposit,the largest REE deposit in the world,were analyzed for their stable isotopic compositions,The δ^13 C and δ^18 O values of huanghoite,cebaite and bastnaesite from late-stage veins vary in the ranges of 7.8--4.0‰ and 6.7-9.4‰,respectively,These data are relatively similar to those of bastnaesites from banded ores:δ^13C-5.6--5.2‰ andδ^18O3.6-5.5‰.The REE fluorocarbonates from both late-staege veins and banded ores are characterized by lower δ^13 C and δ^18O values,especially the δ^18O values of bastnaesites from banded ores.Compared with them,the disseminated bastnaesits the dolomite-type ores possess rather highδ^13 C and δ^18O values,i.e.,-2.1-0.4‰ and 8.6-12.9‰ respectively.The high values are typical of the sedimentary host dolomite rocks as well as of the dolomite-type-ores.The carbon and oxygen isotopic characteristics of REE fluorocarbonate minerals provide new evidence for the hypothesis on the origin of Bayan Obo deposit-epigenetic hydrothermal metasomatism.