Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.     

探测地雷技术研究综述

高敏感度、高可靠度、低花费传感器是全自动或半自动探雷机器人的首要和绝对的选择。当前,有许多技术能够被选来综合使用以满足上述的要求。金属探测器是一种传统的、成熟可靠的探测技术。但是,现在多种地雷含有少量的金属或者不包含任何金属,造成了用金属探测器探雷的困难。目前迫切需要研究发展新颖的探测技术以消除100万颗地雷对许多国家的影响。     

阿尔金地区构造应力场及其对金属矿产分布的控制作用

构造应力场研究可以为区域矿产预测提供依据。主要根据节理、擦痕的测试分析，结合区域构造解析，确定阿尔金山东西向拉配泉－－红柳沟构造带经历了三期不同方向的应力作用：印支期以前的南北向挤压作用，印支－燕山期的北西－南东向的挤压和中生代晚期－新生代北东东－南南西向的挤压；并利用有限元数值模拟前两期构造应力场的演变过程，进而讨论了区域构造应力场对内生金属矿产分布规律的控制作用指出了区域寻找大型内生金属矿产的有利地段。     

得尔布干成矿带中段八大关——新峰山成矿地质条件分析

得尔布干成矿带中段八大关—新峰山地区断裂构造发育 ,北东向得尔布干深大断裂是重要的控岩控矿构造。与成矿有关岩浆岩主要为燕山期的中性—中酸性侵入岩及次火山岩。赋矿层位主要有上库力组、塔木兰沟组及谢尔塔拉组。在分析典型矿床的成矿地质特征基础上 ,进一步指出找矿方向     

桂北地区锡多金属矿找方向

文章通过对前人资料的收集整理，结合大调查项目的找矿成果和信息分析，认为桂北地区锡多金属找矿前景乐观，远景区可划分为二区（九万大山、越城岭）三带（丹池、观音阁、花山-姑婆山），找矿重点应放在3条成矿带上。     

冲积物覆盖区活动态金属在土壤中的分配规律

以我国山东省北部为例，研究了冲积物覆盖区土壤中金属的存在形式，特别是活动态金属的分配规律。通过研究发现，活动态Au在土壤全量Au中大约占到70％的比例，而Cu、Pb、Zn等元素在土壤中所占的比例相对较小。每种金属在四种活动态中的分配比例也存在较大差别。造成这些差别的主要原因是元素的地球化学性质不同，特别是地球化学性质极为不活泼的Au，反而大部分以活动形式存在，主要是因为Au在表生环境中以纳米或亚微米等超微细颗粒形式存在，使其化学性质发生了很大的变化。     

张八岭构造带两种类型金矿次显微金赋存状态的质子探针分析

金属硫化物中次显微金的赋存状态已引起人们的重视。张八岭构造带蚀变构造岩型和石英脉型两类金矿金属硫化物中次显微金质子探针分析显示，Au与As、Fe、S、Cu、Pb呈正相关关系，Au以显微包裹体形式存在于金属硫化物中。与蚀变构造岩型金矿相比，晚期的石英脉型金矿可见自然金含量较高，硫化物中显微包裹体金含量较低，可能预示中低温热液金矿中，不仅普遍存在时空分异的金属硫化物中的类质同象金和自然金，还可能存在一定程度的时空分异的自然金和次显微包裹体金。     

山东月湖的沉积物分布特征及搬运趋势

1998年 11～ 12月和 1999年 8～ 9月各一个月对月湖进行的野外工作 ,共取得表层沉积物样品 131个 ,应用激光粒度仪并结合传统的筛分法对这些样品进行粒度分析 ,进行矩法计算获得粒度参数。采用Gao命名方法 ,将沉积物划分出 5种主要类型。利用Gao -Collins粒径趋势分析模型 ,计算该区沉积物粒径趋势所显示的沉积物净搬运方向 ,结果表明 ,沉积物从四周向湖中心搬运 ,同时显示湾顶的西部和北部、涨潮三角洲以及湖心等地貌单元是沉积的优势区域。     

大洋多金属结核中1nm锰矿相的相变及其主要控制因素研究

多金属结核样品在室温中放置或加热干燥后 ,其中的 1nm锰矿相会部分或全部地相变为 0 7nm锰矿相 ,这说明 0 7nm锰矿相可能不是多金属结核的原生锰矿相 ,而仅仅是 1nm锰矿相的相变产物。研究结果表明 :1nm锰矿相结构中的Cu2 + 、Co2 + 、Ni2 + 等金属阳离子的含量与其结构稳定性有正相关关系 ,即金属离子含量越高 ,其结构越稳定 ,1nm锰矿相越不易相变为 0 7nm锰矿相 ,反之亦然 ;另外 ,不同金属阳离子稳定 1nm锰矿相结构的能力也不同 ,结核中几种主要金属阳离子对 1nm锰矿相结构的稳定能力从大到小为 :Ni2 + >Cu2 + >Co2 + >Zn2 + >Ca2 + =Mg2 + 。     

The Role of Organic Matter During Metal Enrichment in Permian Kupferschiefer of the Rudna Mine,Southwest Poland

The bulk composition of organic matter and saturated and aromatic hydrocarbons extracted from 16 samples collected from two Kuperschiefer profiles in the Rudna mine,Southwest Poland has been analyzed to study the role of organic matter during base metal enrichment in the Kupferschiefer shale.The results indicated that the extract yields and saturated hydrocarbon yields decreased with increasing base metal contents.GC and GC/MS analyses indicated that n -alkanes and alkylated aromatic compounds were depleted and may have served as hydrogen donators for thermochemical sulfate reduction.The enrichment of base metal is closely connected with the destruction of hydrocarbons.