Petrochemistry,Age and Petrogenesis of the Shexian Pluton in Southern Anhui

The Shexian gneissic granodiorite in southern Anhui trends NE 55° from Shexian in the west to Guitoujian in the east with a length of 22 km and an outcrop area of 32 km. It was considered formerly to be Caledonian on the basis of a biotite K-Ar age of 474 Ma (1982). However, new evidence indicates that it may be Early Jinning in age as shown by: (1) it is found intruding into the Mid-Proterozoic Shangxi Group and is unconformably overlain by the Sinian Xiuning Formation, and (2) a zircon U-Th-Pb age of 928 Ma is obtained for the pluton. The pluton is composed of plagioclase (An=27.37%), K-feldspar(14%), biotite(16%) and quartz(32%). Accessory minerals are ilmenite (150g/T), xenotime (15g/T). garnet(25g/T), monazite(10g/T), zircon (20g/T) and apatite (104g/T). Petrochemical characteristics of the intrusion are:(l) Al-enrichment (A/NKC=1.30); (2) H₂O enrichment (H₂O= 1.74%); and (3) low oxidation index (f ’=0.10). It belongs to the continental crust transformation type as evidenced by: (1) MF and Mg/Y values of biotite are 0.41 and 0.31 respectively; (2) (⁸⁷Sr/⁸⁶Sr)=0.71119; (3) δ Eu=0.52; and (4) A/NKC=130. The Shexian pluton is therefore considered as a product of melting of phyllite at depth in the light of similarities in trace element and REE contents with the phyllite of the Banxi Group. Calculations of REE batch partial melting indicate that it may have resulted from 75% melting of the Banxi phyllite.     

研究超镁铁岩中八面体假象蛇纹石和绿泥石的地质意义

继1981年首次报导八面体假象蛇纹石之后,在同一超镁铁岩中又发现了一些八面体假象含铬绿泥石,后者是交代前者的产物。通过研究我们认为:1)八面体假象绿泥石中的Al、Cr等元素来自铬铁矿石;2)和八面体假象蛇纹石一样,八面体假象绿泥石的最初原生矿物也应为γ一橄榄石,后者的形成压力为140×10~8Pa(140Kb),相当于500公里的深度;3)包有八面体假象蛇纹石和绿泥石的铬铁矿可能是一种直接来自深部地慢的铬铁矿类型;4)藏北岩带的两处(安多和阿里地区)超镁铁岩中出现八面体假象矿物说明藏北超镁铁岩带(或岩带的几处超镁铁岩)形成的构造环境可能深于藏南超镁铁岩带。     

中国东部地幔岩包体的产出及其与地球内部构造的关系

中国东部橄榄岩和榴辉岩深源包体的地理分布构成了全球环太平洋深源包体分布带的重要组成部分。深源包体的产出与地球内部构造密切相关。尖晶石橄榄岩和镁铝榴石橄榄岩两种包体与上地幔的构造分带相一致,榴辉岩包体代表上地幔中局部的分凝体。碱性玄武岩浆的活动和深源岩石带的形成应为板块构造运动的结果。     

红辉沸石合成P型沸石试验研究

以广西资源红辉沸石为原料进行合成P型沸石的最佳工艺流程及相关技术参数研究，提出了工艺流程为红辉沸石（酸处理）→水热反应→晶化→洗涤、过滤→烘干→P型沸石产品，最佳工艺技术参数为硅铝摩尔比[n(SiO2)/n(Al2O3)]3-4，碱度4－5mol/L NaOH，晶化温度95－100℃，晶化时间6－8h。     

青藏高原北缘火山岩中辉石岩包体研究

青藏高原北缘可可西里鲸鱼湖、雄鹰台、双泉子火山岩中含有辉石岩包体 ,其主要矿物组成为单斜辉石和斜方辉石。辉石的化学成分与国内外幔源包体 -橄榄岩和辉石岩中的类似 ,与麻粒岩中的明显不同 ;辉石温压计计算结果表明 ,辉石形成的温度为 110 1～ 140 0℃ ,压力为 30× 10 8～ 6 0× 10 8Pa,结合岩浆动力学计算结果 ,推测岩浆的来源深度大于 15 0km ,这与地球物理研究得出本区地下深处存在低速层的结果相吻合。     

肇东陨石低钙辉石超微结构的研究

在肇东陨石低钙辉石中观察到各种堆垛缺陷,包括斜方-单斜辉石相转变、畴结构、2.7nm长周期结构以及自然界极为罕见的奇数倍八面体层堆垛缺陷——1.35nm等。高分辨像所揭示的1.35nm的新特征是可以重复两次。文中提出1.35nm的结构是“A+B+A-”型。1.35nm片晶仅见于3,4型球粒陨石,因而它可作为由原顽火辉石淬冷形成的、末遭受后期热变质的典型结构。奇数倍0.9nm宽度单斜辉石片晶在吉林陨石(H5)、安龙陨石(H5)及东台陨石(LL6)中均有出现,它表明这些陨石的辉石都曾由原顽火辉石转变而成。 肇东陨石低钙辉石中相当频繁的相变以及高能量的奇数倍0.45nm层堆垛缺陷的存在,可能表明该陨石形成于退变质过程。     

Geology and Genesis of the Mafic—Ultramafic Complexes in the Huangshan—Jingerquan（HJ） Belt,East Xinjiang

More than twenty mafic-ultramafic complexes, which host several mediumor large-sized Cu−Ni deposits, occur along the Huangshan-Jingerquan (HJ) belt in East Xinjiang. Rock types in these complexes are predominated by peridotite, pyroxene peridotite, olivine pyroxenite, gabbronorite, orthopyroxene gabbro, troctolite, gabbro and diorite. The ultramafic rocks are relatively Fe-enriched and are characterized by an assemblage of olivine+orthopyroxene+clinopyroxene+hornblende±plagioclase without obvious metamorphic textures. Chemically, these complexes are relatively Fe-enriched and show a tholeiitic trend of evolution. The complexes in this belt are intruded under the extensional environment in a Mid-Carboniferous back-arc basin. They can be considered as a new type of mafic-ultramafic complexes in orogenic belts, as designated by the name of the East-Xinjiang-type complexes. This project was financially supported by the National Natural Science Foundation of China.     

冀北水泉沟偏碱性杂岩体中云辉闪长岩的发现及其地质意义

作者在冀北水泉沟偏碱性杂岩体中发现了一种钙碱性岩石──云辉闪长岩。根据其矿物组成，可能为一种新的岩石类型。该岩石由黑云母（约占１５％）、普通辉石（约占１５％）、更一中长石（约占６５％）、钾长石（约占５％）以及其它一些副矿物（＜１％）组成。与水泉沟杂岩体的其它岩类相比，该岩石以相对高含量的ＬＲＥＥ、高场强元素和Ｆｅ、Ｍｇ、Ｃａ等元素以及相对低的ＳｉＯ＿２、Ｋ＿２Ｏ＋Ｎａ＿２Ｏ和Ａｌ＿２Ｏ＿３为特征。