钙钠离子对蒙脱石吸水特性的影响

本文测定蒙脱石胶体和膨润土吸水率及吸水比,研究钙钠离子对其吸水特性的影响。研究结果表明,钙质蒙脱石、膨润土在吸水24h内的吸水率和吸水速度均高于钠质的;而24h后则前者低于后者。钙质蒙脱石和膨润上的吸水比>50％,而钠质的<50％。     

Mineral characteristics and their geological significance of black shales in southeastern Ordos Basin by X-ray diffraction analysis

X-ray diffraction analysis of black shale of Upper Triassic Member Chang 7 of the Yanchang Formation in southeastern Ordos Basin showed that black shales were deposited in brackish, strongly reducing, semi-deep-deep lacustrine facies, and mainly composed of quartz, feldspar, carbonate （dolomite）, clay minerals （illite and il- lite/smectite） and a certain amount of pyrite. The mineral composition characteristics of this set of black shales are similar to those of highly productive shale gas in North America, for example shallow burial, low clay mineral and abundant brittle mineral, so the strata are conducive to the development of cracks and fractures. Thus, this area is favorable for shale oil/gas exploration and development.     

软粘土中插入式大直径薄壁圆筒结构的一种极限状态分析模型

根据插入式大直径薄壁圆筒结构的工作特点建立了其合理的破坏机制，以此为基础建立了受横向荷载作用的插入式大直径薄壁圆筒结构的上限法极限分析模型，从中可以得到作用于插入式大直径薄壁圆筒结构上的横向极限荷载近似的上限解；并根据上限法模型计算结果，提出了计算受横向荷载作用的插入式大圆筒结构侧壁极限抗力的简化修正模型，利用此修正模型，基于极限平衡法，可以求解作用于插入式大直径薄壁圆筒结构上的横向极限荷载。     

末次盛冰期末期以来南海北部陆坡的陆源物质输入及其控制因素

通过对南海北部陆坡KNG5孔沉积物粒度、粘土矿物和14C年龄的综合分析, 探讨了南海北部陆坡的沉积物来源及其控制因素。物源分析表明, KNG5孔17.5-12.5ka BP的沉积物主要来源于珠江, 12.5ka BP 时粘土矿物组合突然发生改变, 并且自12.5ka BP以后, 高岭石含量总体稳定, 说明12.5ka BP时海平面已上升到相当的高度, 并且可能当时南海的现代环流系统已开始形成, 西行的广东沿岸流导致向外扩散的珠江物质减少, 由于受北太平洋深层水(NPDW)和黑潮(KC)南海分支的作用, 台湾成为此时沉积物的主要贡献者。KNG5孔17.5-11ka BP时期的粘土矿物和粒度变化主要受控于海平面和洋流系统的变化。全新世早期(11.0-8ka BP)平均粒径达到最细和1-2.2m 粒级含量达到最高值可能是强盛的夏季风作用的结果。全新世中晚期(8—0ka BP) 1-2.2?m组分含量的减少是8ka BP以来东亚夏季风减弱的具体体现, 1-2.2m 粒级含量指示的东亚夏季风变化能和北半球其它季风指标能很好地对应起来, 说明这次季风减弱是北半球各个季风系统的共同现象。     

柴达木盆地第三系咸水湖相生油岩古沉积环境地球化学特征

在系统分析柴达木盆地西部第三系咸水湖相生油岩样品的微量元素、有机物、粘土矿物组成的基础上,揭示了研究区生油岩的无机元素和有机质组成特征;并结合沉积环境的无机与有机地球化学指标,重建了生油岩沉积时的古沉积环境。生油岩的B、Cl-及伽玛蜡烷含量表明,沉积时的水介质条件是半咸水—咸水环境,并伴随湖盆沉积中心北迁过程各层位地层的盐度发生规律性时空]化;生油岩的Fe2 /Fe3 、S2-、Pr/Ph比值、藿烷碳数分布模式及黄铁矿含量反映其沉积时的沉积环境为强还原性;粘土矿物组合特征及含量揭示这些生油岩的沉积相带介于中心咸湖相和边缘咸湖相之间。     

清淤输泥的新方法新设备

为解决中低滩涂沉积的深厚软粘土层的输送难题,提出了一种清淤输泥的新方法,研制了能远距离输送高浓度、大粘度、低含水量的淤泥和软粘土的土方施工新设备:包括进料口、推送器、表面膜发生器、脉冲切割器、定位系统、智能控制系统、输料管道、管道浮子等。该设备具有能耗低,工效高,效益好;结构简单,故障少,运行维护方便;定位准确性高;自动化程度高等特点。可广泛应用于水利、环保、建筑工程中的淤泥和软粘土输送。     

AAB-02新生代两极古气候记录在百万年尺度上的联系 北冰洋海底沉积物的粘土矿物组合及其对新生代气候变化的指示（IODPLeg302）

粘土矿物的组成可以通过红外吸收光谱（IR）和x射线衍射（XRD）方法来测定,其中,红外吸收光谱法能在数量上模拟和比较粘土矿物组合的比值特征。粘土矿物的半定量分析是以Biscaye方法为基础建立的（Biscaye,1965）。通过100个样品的两种程序分析对比后,粘土矿物的半定量分析得到了巩固。其中,第一种程序是将粘土矿物固定在玻璃片上（Moore和Reynolds,1997）,     

粘土-MMH体系对赤潮生物的絮凝作用机制研究

根据粘土表面改性对其絮凝作用影响的理论模型,提出在粘土中引入ＭＭＨ（混合金属层状氢氧化物正电胶体）的改性方法,考察了ＭＭＨ浓度及ｐＨ值对絮凝作用的影响。结果表明,粘土中引和ＭＭＨ后,显著提高了对赤潮异弯藻（Ｈｅｔｅｒｏｓｉｇｍａａｋａｓｈｉｖｏ）和新月菱形藻（Ｎｉｔｚｃｈｉａｃｌｏｓｔｅｒｉｕｍ）的去除效率,二者的适宜配比为ＭＭＨ;粘土＝０．１ｇ：１ｇ,在此基础上,进一步研究了ＭＭＨ促进粘土絮凝作     

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.