内蒙古额仁陶勒盖银矿床锰矿物的矿物学初步研究

额仁陶勒盖银矿床出现的锰矿物主要为软锰矿、水锰矿、六方锰矿、锰铅矿、锰钾矿、菱锰矿、铁菱锰矿及锰方解石。解主要以独立矿物和离子吸附状态的形式赋存于地表锰铅矿和锰钾矿中；而软锰矿、六方锰矿、锰铅矿、锰钾矿等锰的氧化物和锰的氢氧化物是原生锰碳酸盐矿物的氧化分解而形成的，而水锰矿可能为热液形成；菱锰矿等原生锰的碳酸盐类矿物形成于后期热液阶段。     

贵州松桃普觉超大型锰矿床主要特征与找矿实践

贵州松桃普觉超大型锰矿床受南华纪普觉Ⅳ级地堑成锰盆地控制,由于同沉积断层作用,两界河组、含锰岩系、锰矿体、大塘坡组第二段、南沱组等地层均从南往北由薄变厚,盆地中存在2个呈NE65°方向展布的渗漏沉积中心。锰矿产于南华系下统大塘坡组第一段(含锰岩系)下部黑色碳质页岩中,呈层状、似层状缓倾斜顺层产出,矿体长大于6 000 m、宽大于2 000 m,盆地中心部位矿体中夹一层含碳玻屑晶屑凝灰岩透镜体。该矿床是近年来运用古天然气渗漏沉积型锰矿床成矿模式与找矿模型理论发现的又一个隐伏超大型锰矿床,锰矿石资源量(332+333) 1. 92亿吨,位居亚洲第一、世界第五位。     

Bi0.5Ca0.5Mn1-xCoxO3体系中的电荷有序和相分离

利用固相反应法制备了Bi_0.5Ca_0.5Mn_1-xCo_xO₃(0≤x≤0.12)系列多晶样品.研究了Co掺杂对Bi_0.5Ca_0.5MnO₃电荷有序的影响.结果表明,Co掺杂导致电荷有序相逐渐融化、铁磁相互作用的增强;当x≥0.08时,电荷有序转变峰完全消失,但残留的反铁磁电荷有     

锰钾矿处理高浓度含酚废水研究

对人工合成锰钾矿氧化降解高浓度含酚废水的特性进行了研究。结果表明,体系酸度和矿物用量是影响废水处理效果的重要因素。加酸量为0.12 mol/L,矿物用量20 g/L,温度70℃,反应时间3 h时效果最佳,废水总酚含量由1269 mg/L降低至268 mg/L,同时CODCr与TOC去除率为31.2%和70.5%。经GC/MS测定,水中酚类物质为苯酚、甲基苯酚、二甲基苯酚,最佳条件下,酚类物质浓度已低至检测限以下,水中残余吲哚、长链烷烃、喹啉及其衍生物等难降解有机物。     

贵州松桃高地隐伏超大型锰矿床主要特征与找矿实践

位于贵州省松桃县乌罗镇高地村的高地锰矿床,是贵州省地质矿产勘查开发局103地质大队应用南华纪锰矿裂谷盆地古天然气渗漏成矿理论和方法,在贵州铜仁松桃国家锰矿整装勘查区找矿实践检验中,继近年新发现普觉、道坨、桃子坪等三个隐伏超大型锰矿床之后,又新发现的隐伏超大型锰矿床。该矿床属于典型的古天然气渗漏沉积型锰矿床,地处李家湾-高地-道坨南华纪地堑盆地中心区域,位于古天然气渗漏喷溢成矿系统的中心相区,以致该矿床的矿体平均厚度、锰矿平均品位是目前该地区该类型所有锰矿床之最。地表发育成矿后期(燕山期)以冷水溪断层(F_3)为代表的犁式正断层,目前控制的隐伏菱锰矿体均分布在其下盘,由于地表相关系列断层均未穿过F_3断层,故深部隐伏锰矿体保存完好,尚未圈边,深部仍有较大找矿潜力。     

基于OLI和GF-2数据的锰矿化信息提取分析与对比 —以新疆西昆仑玛尔坎苏锰矿带为例

本文在充分分析锰矿样品的实测波谱典型特征和矿化蚀变信息提取方法的基础上,基于Landsat OLI数据和国产GF-2数据影像,利用主成分分析法（PCA）对新疆西昆仑玛尔坎苏锰矿带进行了锰矿化异常信息提取,并对这两类数据的锰矿化信息提取结果进行了对比分析,进而讨论两类数据在锰矿化信息提取精度上的差异。研究表明：基于OLI和GF-2两类多光谱数据提取的锰矿化信息都取得了良好的效果,将已有的锰矿区与锰矿化点全部提取了出来,同时也提取出了未开采的锰矿化异常信息,验证了所采用信息提取方法的有效性;相比空间分辨率较低的OLI数据,高空间分辨率的国产GF-2遥感数据能够更好地区分锰矿化异常与阴影,更能精确地识别锰矿化异常的分布。因此,高空间分辨率多光谱数据在区分光谱特征差异较小的地物时具有较大优势,可为研究区下一步遥感找矿预测提供有利线索。     

Compositional Characteristics of Wolframite in Tin Dposits,Dupangling,Guangxi

Statistical data on major,trace and rare-earth elements in wolframite from the quartz vein-and greisen-type tin deposits in the Dupangling orefield reveal(1)The components in wolframite can be divided into two relatively independent groups:the WO3-Nb-Ta-Sc-REE group,in which WO3 is negatively correlated with the others and the FeO-MnO-Sn group,in which MnO is negatively corre-lated with the other two;(2)In general ,REE fractionation is not significant,reflected mainly by the separation of Eu from other REE‘s.LREE and HREE increase or decrease simultaneously ,with HREE being more variable;(3)Nb,Ta,Sc,REE substitute for W, and Sn may enter into wolframite lattice accompanied by Fe-Mn substitution;(4)In contrast to wolframite in quartz veins,which is poor in REE,Nb,Ta and has high δEu values and LREE/HREE and Nb/Ta ratios,wolframite in greisen is rich in REE, Nb,Ta,Sc and has low δEu values and LREE/HREE and Nb/Ta ratios ;and (5)The contents and ratios of trace elements and REE parti-tioning parameters of wolframite can be used as guide for prospecting.     

麻栗坡三保银—锰矿床氧化矿石的选冶性能及其矿床类型

麻栗坡三保及国内２０余外银－锰矿床,绝大多数只是氧化矿石才有工业价值。其共同特征是银锰（铁）氧化物吸附,浮选难以回收,常采用强磁选提高其品位,达到冶炼高炉富锰渣的要求,并综合回收含银粗铅、生铁及氧化锌粉。基于此特点,建议在我国银矿床分类上,将其单独列出一类,即银－锰型银矿床。     

Analysis of F, Al, Mn, Zn, Fe, Cu, Ca and Mg concentrations in brick teas from main producing areas in China

Brick-tea-type fluorosis is a peculiar endemic disease in China, which had been discovered in minority areas of western China since 1980, and distributed mainly in Tibet, Inner Mongolia, Gansu, Xinjiang, Qinghai and parts of Sichuan Province. The prevalence rate of fluorosis in Tibetan and Mongolian nationality people was higher. Epidemiological investigation showed that fluorosis morbidity and degrees were different in different brick-tea drinking areas, and it was probably caused by drinking various kinds of brick tea from different regions. Therefore, we collected 33 samples of brick tea from six provinces where minority nationalities were accustomed to drinking a large quantity of brick tea. F concentrations were determined by the combustion hydrolysis-ion selective electrode method. The results showed that among the brick teas, the F concentrations ranged from the minimum 74.1 mg/kg in Yunnan Province to the maximum 991.2 mg/kg in Sichuan Province. Besides, there was a great difference among the various kinds of brick tea, and F concentrations decreased in the order of Kang brick tea, Green brick tea, Black brick tea, Mi brick tea, Fu brick tea, Chitsu ping tea, Puerh tea, and Tuo tea. The average F concentration in brick teas was 431.92 mg/kg.