中俄原油管道沿线典型土样冻胀性试验研究

中俄输油管道穿越约500 km的多年冻土区,管道沿途地形起伏,水系和沼泽发育,使得管道工程地质条件复杂.沿线地貌单元主要可分为沼泽湿地、阶地、河漫滩、坡地以及基岩山脊等5种,不同地貌单元的岩性和冻土赋存条件均不相同.选取各地貌单元的典型土样进行颗粒分析、冻胀率等试验,分析了土样冻胀率与天然含水率、干容重、粘粒含量之间的关系.结果表明:全-强风化花岗岩冻胀率最小,冻土工程地质条件最好;含有机质粉质粘土冻胀率最大,管基需要进行特殊处理;粘土和粉土冻胀率介于二者之间,对管基进行常规处理即可.该试验定量评价了中俄输油管道沿线不同地貌单元的冻胀性,为管道在确保工程长期稳定性的基础上,选择经济、环保的施工方式提供了试验依据.     

滇西北小中甸盆地湖相粘土沉积特征与工程特性研究

滇西北小中甸盆地是上新世末期以来在青藏高原强烈隆起过程中形成的NNW向第四纪断陷湖盆地,从深切的小中甸河谷剖面可见盆地上部发育中晚更新世湖相粘土.规划建设中的滇藏铁路将从小中甸盆地穿过.野外调查发现小中甸湖相粘土厚数十米以上,粘土细腻、层理发育.室内试验表明:小中甸湖相粘土是一种高分散性、高含水量、高塑性和高孔隙性的结构性粘土,其力学性质指标表现为高粘聚性、以中低膨胀性为主.工程开挖卸荷、浅表层土体暴露在干湿交替环境中,土体收缩强度衰减,由此产生土体差异变形和粘土边坡滑塌破坏.     

Cd2+在甘肃靖远坡缕石粘土上的吸附作用研究

以提纯后的甘肃靖远坡缕石粘土作吸附剂,常温下对水中Cd2 进行吸附实验,考察了吸附时间、吸附剂用量、振荡速率及pH值对吸附效果的影响,并对吸附动力学过程和吸附平衡进行了探讨.XRD和红外光谱分析结果显示,原矿在提纯后杂质石英被有效分离,得到了坡缕石含量较高的提纯样品.吸附实验结果显示,约60 min吸附反应可达平衡;pH值对吸附效果有显著影响,吸附率随pH值的升高而增加,当平衡溶液pH>8时吸附率超过99%;吸附过程与pseudo-second-order Lagergren动力学模型方程有较好的一致性,吸附平衡同时符合Langmuir和Freundlich等温吸附模型,由Langmuir方程得到饱和吸附量为31.65 mg/g.     

海拉尔盆地贝尔凹陷兴安岭群储层粘土矿物组成及成因研究

油田注水开发是保持地层能量,提高采收率的有效手段.海拉尔地区由于粘土矿物含量高,在开发过程中储层遇水易泥化、坍塌,严重影响油气的有效开采.通过X射线衍射、偏光显微镜观察和扫描电镜分析,确定了海拉尔盆地贝16断块兴安岭群储层自上而下存在三种粘土矿物组合:蒙脱石 高岭石 (绿泥石)→高岭石 伊/蒙间层 伊利石 (绿泥石)→伊利石 绿泥石 绿/蒙间层 伊/蒙间层.粘土总量在9.1%～69.1%之间,由地层浅部到深部呈现由高到低的变化规律.详细研究了水敏性极强的钠蒙脱石及其间层矿物,认为凝灰物质的水解蚀变以及长石和中、酸性岩屑在成岩过程中的次生变化是造成海拉尔地区粘土含量高的主要因素.     

Effect of Cyclic Loading Frequency on Undrained Behaviors of Undisturbed Marine Clay

Based on a series of cyclic triaxial tests, the effect of cyclic frequency on the undrained behaviors of undisturbed marine clay is investigated. For a given dynamic stress ratio, the accumulated pore water pressure and dynamic strain increase with the number of cycles. There exists a threshold value for beth the accumulated pore water pressure and dynamic strain, below which the effect of cyclic frequency is very small, but above which the accumulated pore water pressure and dynamic strain increase intensely with the decrease of cyclic frequency for a given number of cycles. The dynamic strength increases with the increase of cyclic frequency, whereas the effect of cyclic frequency on it gradually diminishes to zero when the number of cycles is large enough, and the dynamic strengths at different frequencies tend to the same limiting minimum dynamic strength. The test results demonstrate that the reasons for the frequency effect on the undrained soil behaviors are beth the creep effect induced by the loading rate and the decrease of sample effective confining pressure caused by the accumulated pore water pressure.     

软粘土中插入式大直径薄壁圆筒结构的一种极限状态分析模型

根据插入式大直径薄壁圆筒结构的工作特点建立了其合理的破坏机制，以此为基础建立了受横向荷载作用的插入式大直径薄壁圆筒结构的上限法极限分析模型，从中可以得到作用于插入式大直径薄壁圆筒结构上的横向极限荷载近似的上限解；并根据上限法模型计算结果，提出了计算受横向荷载作用的插入式大圆筒结构侧壁极限抗力的简化修正模型，利用此修正模型，基于极限平衡法，可以求解作用于插入式大直径薄壁圆筒结构上的横向极限荷载。     

水溶液中聚合物在粘土上的吸附

水溶液中聚合物在粘土上的吸附对于聚合物污染防治和污水处理等都有重要意义。Scheutjens-Fleer理论是应用范围最广的聚合物吸附理论,适应于从单体到长链高聚物,从链无相互作用的稀溶液到纯聚合物的吸附研究。本文简要介绍了有关聚合物吸附的重要参数,包括吸附量、耦合分数或直接表面覆盖、平均层厚度和链段密度,以及相应的测定方法。文中分析了影响聚合物吸附研究发展的主要问题,指出水溶液中聚合物在粘土上的吸附研究的发展方向是综合研究吸附等温线和A/V效应、耦合分数、吸附层厚度、吸附分级现象和对粘土层间的影响,并与Scheutjens-Fleer理论计算结果进行比较。     

A Note on Soil Structure Resistance of Natural Marine Deposits

It has been well documented that natural normally-consolidated marine soils are generally subjected to the effects of soil structure. The interpretation of the resistance of soil structure is an important issue in the theory study and engineering practice of ocean engineering and geotechnical engineering. It is traditionally considered that the resistance of soil structure gradually disappears with increasing stress level when the applied stress is beyond the consolidation yield stress. In this study, however, it is found that this traditional interpretation of the resistance of soil structure can not explain the strength behavior of natural marine deposits with a normally-consolidated stress history A new interpretation of the resistance of soil structure is proposed based on the strength behavior. In the preyield state, the undrained strength of natural marine deposits is composed of two components: one developed by the applied stress and the other developed by the resistance of soil structure. When the applied stress is beyond the consolidation yield stress, the strength behavior is independent of the resistance of soil structure.