黔西地区构造变形特征及其煤层气地质意义

黔西地区处于特提斯与滨太平洋两个构造域的交接地带,多期性质不同的构造作用形成了现今错综复杂的构造变形特征。根据构造变形的差异,可划分为织金-纳雍NE向构造变形区、水城-紫云NW向构造变形区和黔西南复杂构造变形区。在野外地质的基础上,结合微观变形特征和矿物流体包裹体测试分析,认为黔西地区构造变形属于上地壳低温-中低温环境下的脆性-脆韧性变形;由于黔西地区基底构造相对稳定,成煤期后断块内部变形较弱,煤储层形成了一定程度的构造裂隙,有助于渗透率的提高,煤层气勘探开发前景良好。     

http://www.sciencedirect.com/science/article/pii/S1674987113001333

The basement of the Romanian Carpathians is made of Neoproterozoic to early Paleozoic periGondwanan terranes variably involved in the Variscan orogeny,similarly to other basement terrains of Europe.They were hardly dismembered during the Alpine orogeny and traditionally have their own names in the three Carpathian areas.The Danubian domain of the South Carpathians comprises the Dragsan and Lainici-Paius peri-Amazonian terranes.The Dragsan terrane originated within the ocean surrounding Rodinia and docked with Rodinia at ~800 Ma.It does not contain Cadomian magmatism and consequently it is classified as an Avalonian extra-Cadomian terrane.The Lainici-Paius terrane is a Ganderian fragment strongly modified by Cadomian subduction-related magmatism.It is attached to the Moesia platform.The Tisovita terrane is an ophiolite that marks the boundary between Dragsan and Lainici-Paius terranes.The other basement terranes of the Romanian Carpathians originated close to the Ordovician NorthAfrican orogen,as a result of the eastern Rheic Ocean opening and closure.Except for the Sebes-Lotru terrane that includes a lower metamorphic unit of Cadomian age,all the other terranes(Bretila,Tulghes,Negrisoara and Rebra in the East Carpathians,Somes,Biharia and Baia de Aries in the Apuseni mountains,Fagaras,Leaota,Caras and Pades in the South Carpathians) represent late Cambrian—Ordovician rock assemblages.Their provenance,is probably within paleo-northeast Africa,close to the Arabian-Nubian shield.The late Cambrian-Ordovician terranes are defined here as Carpathian-type terranes.According to their lithostratigraphy and origin,some are of continental margin magmatic arc setting,whereas others formed in rift and back-arc environment and closed to passive continental margin settings.In a paleogeographic reconstruction,the continental margin magmatic arc terranes were first that drifted out,followed by the passive continental margin terranes with the back-arc terranes in their front.They accreted to Laurussia during the Variscan orogeny.Some of them(Sebes-Lotru in South Carpathians and Baia de Aries in Apuseni mountains) underwent eclogite-grade metamorphism.The Danubian terranes,the Bretila terrane and the Somes terrane were intruded by Variscan granitoids.     

http://www.sciencedirect.com/science/article/pii/S1674987114000395

The study of fluid inclusions in high-grade rocks is especially challenging as the host minerals have been normally subjected to deformation, recrystallization and fluid-rock interaction so that primary in- clusions, formed at the peak of metamorphism are rare. The larger part of the fluid inclusions found in metamorphic minerals is typically modified during uplift. These late processes may strongly disguise the characteristics of the ＂original＂ peak metamorphic fluid. A detailed microstructural analysis of the host minerals, notably quartz, is therefore indispensable for a proper interpretation of fluid inclusions. Cathodoluminescence （CL） techniques combined with trace element analysis of quartz （EPMA, LA- [CPMS） have shown to be very helpful in deciphering the rock-fluid evolution. Whereas high-grade metamorphic quartz may have relatively high contents of trace elements like Ti and A1, low- temperature re-equilibrated quartz typically shows reduced trace element concentrations. The result- ing microstructures in CL can be basically distinguished in diffusion patterns （along microfractures and grain boundaries）, and secondary quartz formed by dissolution-reprecipitation. Most of these textures are formed during retrograde fluid-controlled processes between ca. 220 and 500 ℃, i.e. the range of semi-brittle deformation （greenschist-facies） and can be correlated with the fluid inclusions. In this way modified and re-trapped fluids can be identified, even when there are no optical features observed under the microscope.     

http://www.sciencedirect.com/science/article/pii/S167498711400067X

The Proterozoic Bamble Sector, South Norway, is one of the world＇s classic amphiboliteto granulite- facies transition zones. It is characterized by a well-developed isograd sequence, with isolated ＇granulite-facies islands＇ in the amphibolite-facies portion of the transition zone. The area is notable for the discovery of C02-dominated fluid inclusions in the granolite-facies rocks by Jacques Touter in the late 1960＇s, which triggered discussion of the role of carbonic fluids during granulite genesis. The aim of this review is to provide an overview of the current state of knowledge of the Bamble Sector, with an emphasis on the Arendal-Froland-Nelaug-Tvedestrand area and off shore islands （most prominantly Tromay and Hisoy） where the transition zone is best developed. After a brief overview of the history of geological research and mining in the area, aspects of sedimentary, metamorphic and magmatic petrology of the Bamble Sector are discussed, including the role of fluids. Issues relevant to current geotectonic models for SW Scandinavia, directly related to the Bamble Sector, are discussed at the end of the review.     

Kuqaia孢型体在柴达木盆地的发现及对冷科1井地层时代再认识

长期以来,柴达木盆地冷科1井井深4666m~5200m井段地层的时代归属存在侏罗纪、石炭纪和三叠纪之争。为了进一步明确该套地层的地质时代,消除混乱,对该套地层及其上覆部分地层(4395m~4666m井段)的岩屑进行了孢粉分析,结果在39块样品中分析出丰富的孢粉化石,孢粉组合面貌基本一致。孢粉组合中,裸子植物花粉居统治地位,占总含量的93.6%以上,以本体无肋纹的两气囊花粉含量为主,占总含量的58.4%~92%;蕨类植物孢子的含量只有0~6.4%,主要是Osmundacidites(0~5.4%);且普遍含库车孢型体(Kuqaia),这两井段地层的时代同属早侏罗世。     

赣南白面石铀矿田成因再认识

赣南白面石铀矿田经上世纪60~80年代勘查,发现和探明了白面石、龙坑、双坑、马荠塘4个铀矿床和黄泥湖铀矿点,成为中国重要的铀资源基地。该矿田产于EW向南岭铀成矿带东段的白面石沉积-火山盆地内。该盆地的基底为印支期白面石花岗岩体;盖层为中侏罗统菖蒲组。盖层的底部为第一层砂岩,其上由基性-酸性双峰式火山岩组合与5层碎屑岩夹层组成。铀矿主要赋存在盖层底部的第一层砂岩中,其次是产在第一层玄武岩与第一层砂岩的接触带,有少量产在基底花岗岩顶部的风化壳中。关于该铀矿田的成因,有砂岩型沉积说、同生沉积后生富集说、成岩成矿热液叠加说、岩浆热液说,等等。为了厘定矿床成因类型,以确立今后的找矿方向,笔者对该矿田的资料进行了重新整理,应用Minesight软件选择典型的白面石铀矿床建立了三维地质模型,并收集了最新的同位素定年和岩石地球化学分析资料。研究表明,白面石铀矿田存在2次成矿（160~156 Ma和99~86 Ma）,其主成矿作用与第一层玄武岩的覆盖,在空间上相伴（铀矿体主要赋存于第一层砂岩及其与玄武岩的接触带）、时间上相近（成矿时间为160~156 Ma,玄武岩成岩时间为173 Ma）、成生上相关（矿化具有明显的中-低温热液蚀变）,为火山热盖成因类型,后期又有大量脉体活动,在岩脉两侧的砂岩层内又有热液型铀矿化叠加,从而形成了火山热盖及热液叠加的复成因矿床。该矿田的成矿条件是：富铀的基底,砂岩的沉积,洼沟的地形,岩浆的热盖,脉岩的入侵。     

内蒙古卓资县大苏计斑岩型钼矿床辉钼矿Re-Os同位素年龄及流体包裹体研究

内蒙古卓资县大苏计钼矿床位于华北克拉通北缘中段的凉城断隆内,是近年来在华北克拉通北缘发现的一个大型斑岩钼矿床,矿体主要产于印支期石英斑岩和正长花岗斑岩中。成矿过程可以划分为石英_钾长石_黄铁矿±辉钼矿±磁铁矿阶段(早阶段)、石英_绢云母_辉钼矿_黄铁矿阶段(中阶段)和石英_方解石_黄铁矿±闪锌矿±方铅矿阶段(晚阶段)。矿石中5件辉钼矿的Re_Os同位素模式年龄介于(223.6±3.1)Ma~(224.2±3.4)Ma之间,其加权平均值为(223.9±1.4)Ma(MSWD=0.017),等时线年龄为(223.5±5.5)Ma(MSWD=0.026),表明大苏计钼矿床形成于印支期。大苏计钼矿床发育富液型、富气型、H2O_CO2型、含子矿物型和纯气相包裹体。成矿早阶段主要发育富液型、富气型包裹体,另有少量H2O_CO2型包裹体,其均一温度介于342~430℃之间,盐度w(Na Cleq)介于3.4%~11.0%之间;中阶段主要发育富液型、富气型、H2O_CO2型和含子矿物型包裹体,另有少量纯气相包裹体,其均一温度为234~380℃之间,盐度w(Na Cleq)介于6.2%~34.9%之间;晚阶段仅发育富液型包裹体,其均一温度介于202~280℃之间,盐度w(Na Cleq)介于1.2%~11.7%之间,指示该阶段有大气降水的加入。成矿流体从早、中阶段的H2O_Na Cl_CO2体系演化为晚阶段的H2O_Na Cl体系。早、中阶段流体均为不混溶流体,流体沸腾是成矿物质沉淀的主要机制。集宁地区钼矿床主要为斑岩型,至少存在晚三叠世和晚侏罗世2期钼成矿事件。     

蒙古国满都拉探矿区地质特征及流体包裹体研究

满都拉探矿区位于蒙古国南戈壁省满都拉苏木。矿区地表中元古界白云岩中出露大面积含孔雀石、蓝铜矿和辉铜矿的硅化蚀变带,含铜矿物与石英脉在空间上紧密共生,石英中的流体包裹体可能保留了原生成矿流体特征。为确定其成矿地质体和成因类型,指导后续找矿工作,本文对硅化蚀变带中的石英进行了流体包裹体研究。根据石英中包裹体的产状可将包裹体分为早晚两个阶段,早阶段富含CO2(C型)和水溶液(W型)包裹体,偶见含子矿物(S型)包裹体,流体均一温度为195~384℃,盐度为2.77%~21.37%Na Cl.eqv,反映了原生成矿流体的特征。晚阶段仅出现水溶液(W型)包裹体,流体均一温度集中在95~213℃,盐度为1.27%~12.63%Na Cl.eqv。流体由早阶段的中高温、中盐度、富CO2流体向晚阶段低温、低盐度、贫CO2流体演化。据此推测成矿流体可能为岩浆流体,流体形成深度大约在5.7 km以上。     

塔里木盆地石炭系烃源岩成熟演化研究

尽管塔里木盆地石炭系富含有机质且已发现其生成的原油,但关于石炭系烃源岩热演化研究却很薄弱。根据基础地质资料、古地温梯度和实测镜质体反射率数据,本文定量模拟了塔里木盆地6口典型井的石炭系烃源岩热演化史和这套烃源岩底界、顶界在二叠纪末期、三叠纪末期、白垩纪末期及现今成熟度的平面分布规律。塔北隆起南部、塔西南坳陷和阿瓦提凹陷在石炭-二叠纪作为沉降中心接受了巨厚的沉积物,造成这些地区石炭系烃源岩底界成熟度在二叠纪末期达到0.9%～1.3%（中-高成熟）,顶界为0.5%～0.9%（低-中成熟）,成为有利生油区。中生代时期,塔里木盆地中、东部长期处于沉降状态,石炭系烃源岩处于成熟演化阶段。白垩纪末期,塔中低凸起和满加尔凹陷的石炭系底界成熟度为0.7%～0.9%（中成熟）,顶界为0.5%～0.7%（低成熟）,而塘古孜巴斯坳陷底界成熟度为0.9%～1.1%（中-高成熟）,顶界为0.7%～0.9%（中成熟）。受羌塘地体、拉萨地体、印度板块分别与欧亚板块南缘碰撞远程效应的影响,塔西南坳陷和巴楚隆起在中生代一直处于隆升剥蚀状态,烃源岩热演化进入停滞状态。新生代以来,塔西南坳陷和阿瓦提凹陷演化为前陆盆地,再次接受了巨厚沉积物,致使石炭系烃源岩快速成熟演化,底-顶界成熟度现今已超过2.0%,进入干气阶段。满加尔凹陷石炭系烃源岩自石炭纪至今一直处于成熟演化阶段,现今达到最大,为0.8%～1.0%。另外,热史研究表明塔西南坳陷和阿瓦提凹陷石炭系烃源岩具有二次生烃潜力。本研究不仅丰富了塔里木盆地石炭系烃源岩热史研究成果,而且对油气勘探与开发具有重要的指导意义。     

广西苍梧社垌石英脉型钨钼多金属矿床流体演化及来源示踪

广西苍梧社垌矿床是大瑶山隆起南侧新发现的一个大型斑岩-矽卡岩-石英脉型钨钼多金属矿床。本文重点对其中的石英脉型矿床进行了研究,依据脉体穿插关系及矿物共生组合将成矿过程划分为I石英-黄铁矿阶段、II石英-白钨矿-辉钼矿阶段、III石英-多金属硫化物阶段以及IV石英-方解石-萤石阶段,其中II和III阶段为主成矿阶段。从早到晚,均一温度逐渐下降(第一阶段550℃→370℃,第二阶段370℃→330℃,第三阶段330℃→210℃,第四阶段190℃→150℃),流体密度逐渐上升(0.61g/cm3→0.72g/cm3→0.82g/cm3→0.94g/cm3),盐度先升后降(第一阶段5.86%～8.55%NaCleqv,第二阶段4.49%～43%NaCleqv,第三阶段0.53%～46.37%NaCleqv,第四阶段0%～12.85%NaCleqv)。激光拉曼成分分析显示,社垌石英脉型矿床的成矿流体属于H2O-NaCl体系,但是该体系的流体成分在成矿前后发生了较大的变化,反映第I阶段以氧化环境为主,(II、III、)IV阶段则为还原环境。氢氧同位素研究显示成矿流体来自于岩浆水,后期大气降水的加入导致矿质发生沉淀。此外金属硫化物的δ34S组成(-3.8‰～+1.7‰)平均为-0.46‰,接近于零值,也表明为岩浆来源。引起矿质沉淀的主要原因是流体混合导致的温度下降等环境条件的改变。总体而言,社垌石英脉型钨钼多金属矿床的成矿流体主要来自岩浆热液,为中高温、中低盐度、低密度的NaCl-H2O流体体系,钨钼等多金属成矿与区内加里东期岩浆作用密切相关。