加压色层法分离稀土元素的研究

本文简要地比较了分离稀土的几种方法。重点论述了加压色层法在分离稀土元素速度快、效率高的优点。在采用比常压法高得多的线性流速和低的分配比时,加压色层法的分离效果仍优于常压法,甚至用常压法在低流速下不能分离的,用加压法在高的线性流速下仍然得到很好的分离。     

Geochemistry of the Rare Earth Elements in Natural Terrestrial Waters：A Review of What Is Currently Knows

The range of observed chemical compositions of natural terrestrial waters varies greatly especially when compared to the essentially constant global composition of the oceans.The concentrations of the REEs in natural terrestrial waters also exhibit more variation than what was reported in seawater,In terrestrial waters ,pH values span the range from acid up to alkaline,In addition,terrestrial waters can range from very dilute waters through to highly concentrated brines.The REE concentrations and their behavior in natural terrestrial waters reflect these compositional ranges,Chemical weathering of rocks represents the source of the REEs to natural terrestrial waters and ,consequently,the REE signature of rocks can impart their REE signature to associated waters,In addition,Because of the typical low solubilities of the REEs both surface and solution complexation can be important in fractionating REEs in aqueous solution.Both of these processes are important in all natural terrestrial waters,however,their relative importance varies as a function of the overall solution composition,In alkaline waters,for example,Solution complexation of the REEs with carbonate ions appears to control their aqueous distributions whereas in acid waters,the REE signature of the labile fraction of the REEs is readily leached from the rocks.In circumneutral pH waters,both processes appear to be important and their relative significance has not yet been determined.     

鄂尔多斯盆地东胜煤田高岭土的物质组成及质量特征

东胜煤田延安组含煤岩系砂岩型高岭土矿石属杂砂岩，基质含量高，矿物组成简单，石英和高岭石分别构成砂岩的碎屑和基质，其它组分含量低碎屑与粘土在粒度和物性上的差异，使两者易于分离。精选漂白的高岭土纯工高，细料组分个体户量和自然白度均较高，是一种优良高岭土。分选出的石英等尾砂ＳｉＯ２含量大于９０％，可综合利用。     

中国东部上地壳化学组成

在中国东部(东经105°以东)约计330万km~2系统采集了28253个岩石样品,组合成2718件分析样,选用了15种可靠的分析方法,以国家一级标准物质监控分析质量,提出了76种化学元素在中国东部出露地壳、沉积盖层、出露基底和上地壳的平均化学组成.     

东风山前寒武纪含铁建造金矿床中的稀土元素

东风山含铁建造金矿床中稀土元素含量普遍较低。东风山群是含矿层,其不同层位岩石和矿物的稀土含量有所差别。大理岩和含铁层中铁闪石的稀土含量最低,甚至低于稀土地壳丰度;上部角岩、下部角岩和石榴子石中稀土含量近似其他壳丰度;而板岩和花岗岩中稀土含量远高于其他壳丰度。稀土元素分布的特点反映了东风山金矿床形成于一个半封闭和较还原的海盆地,金矿化是在弱碱性条件下产生。黄铁矿中出现独居石类矿物,这可能与陆壳重熔改造形成花岗岩时产生的局部富轻稀土热液沿黄铁矿裂隙渗入有关。     

Isotopic Characteristics and Key Factors Favoring the Formation of Fuwan Super-large Silver Deposit in Guangdong Province

Rb-Sr isochron age of fluid inclusions in quartz from the Fuwan super-large silver deposit is 68 - 6 Ma, the silver deposit is characterized by high μ values (10.67 - 10.95 ), which are much higher than those of the ore-hosted Paleozoic strata and are close to those of ores hosted in the Proterozoic metamorphic basement in western Guangdong Province. Based on the Pb isotopic characteristics, coupled with much high background silver contents (200-1000ng/g) in the Proterozoic basement and relatively low silver contents in the Paleozoic strata in the region of the Sanshui Basin, it is concluded that the ore-forming material of the super-large silver deposit came mainly from the old basement. The super-large silver deposit related genetically to the intense volcanic activities during the Upper Cretaceous to Eogene. The formation of the Fuwan super-large silver deposit is controlled by the following favorable geological conditions : ( 1 ) The intersection of deep faults and contemporaneous faults at the margin of the Sanshui Basin led to the formation of an excellent structure as passageway for ore fluids; (2) The special ore-hosted rock association forms a ore gathering-trap structure that favors the precipitation of ore; (3) The silver-rich old basement, multi-stage mineralization and multi-episode volcanic activities which constitute a geothermal convection system.     

湖北蕲春花岗岩类锆石SHRIMP年龄：大别山造山带内弱变质—未变质晋宁期花岗岩类的发现

蕲春花岗质杂岩体包括斑状二长花岗岩和花岗岩两部分,它们之间在化学性质上存在着很大的差异,前者表现为高Al 2O3(15.73%)、相对高CaO(2.46%)、Na2O含量明显高于K2O(Na2O/K2O=1.27),尤以强烈亏损重稀土元素和极强的轻、重稀土元素分馏程度[(La/Yb)N=46.8]为特征而类似于太古宙高Al2O3的TTG岩石.而后者则以较低的Al2O3含量(14.05%)、贫CaO(0.82%)、K2O含量明显高于Na2O(Na2O/K2O=0.81)为特征,轻、重稀土元素的分馏程度[(La/Yb)N=10.89]也较片麻状二长花岗岩中弱得多.两类岩石中锆石的U-PbSHRIMP年龄分别为824.6±17.6 Ma和784±20 Ma,该时代与大别山造山带内花岗片麻岩的原岩形成年龄类似.大别山造山带内弱变质-未变质晋宁期花岗岩的出现表明扬子板块印支期向北俯冲时,该花岗质杂岩处于俯冲板片的后缘,可代表造山带内扬子基底的原地露头.而岩体周围的高压变质杂岩应是折返上来的无根构造岩片,大别山造山带内高压超高压变质杂岩的出露不是整体性抬升剥蚀的结果.     

东濮凹陷白庙地区天然气及凝析油地球化学特征及成因

白庙构造是东濮凹陷南部地区的一个含凝析油的富气构造.在研究油藏基本地质特征的基础上,应用多种地球化学手段研究了气藏中天然气组分、甲烷同位素及惰性气体同位素变化规律、凝析油族组成、饱和烃色谱、色质生物标志物特征,进行了油气源分析,探讨了气藏的形成时间与次序,白庙气藏具有多源、多期、复合成藏的特点.     

页岩、煤、沥青和原油的生气实验研究

选取了有代表性的页岩(海相页岩与油页岩)、煤、沥青与原油样品进行了真空封闭体系生气模拟实验,研究了不同生气母质的生气高峰阶段及其在不同热演化阶段的气产率及气体组成 ,综合探讨了不同生气母质的生气机制与生气规律及母质类型、热演化程度等对气产率及所生天然气组成的影响.为有效气源岩的判识提供了实验依据.     

RTK高差、水准高差组成混合网代替四等水准可行性的分析和研究

GPS RTK新技术在一级及以下的平面控制测量中应用较为广泛，但由于RTK的高程精度明显比平面精度要低．因此在生产中直接采用RTK高程成果较少。本文结合生产实测，对RTK高程的精度进行了一定的分析和处理，采用部分RTK高差代替四等水准高差，组成混合水准网进行平差，并进行精度分析和比较，以供大家参考。