应用电化膜硫电极测定海水中的硫化物

当前，离子选择性电极已广泛用于海洋化学领域，对于海水中微量硫化物的测定，与碘量法和比色法相比较，电极法不仅灵敏、简便，而且能够实现对环境或体系中硫化物的连续自动监测。特别对于海洋底质间隙水中硫化物的现场测定，电极法更有独到之处。已往报导使用硫离子选择性电极测定天然水中硫化物的方法中，     

顶空气相色谱法测定海水二甲基硫和浮游植物细胞二甲基硫丙酸的研究

建立了顶空ＧＣ／ＦＰＤ测定海水中二甲基硫（ＤＭＳ）和浮游植物细胞中二甲基硫丙酸（ＤＭＳＰ）的方法，并研究盐度、温度、气液相比ＤＭＳ诸因素对ＤＭＳ顶空灵敏度的影响。该法对ＤＭＳ测定的相对标准偏差均小于６％，平均回收率为１０６％，最低检出限为２０ｎｇ／Ｌ。细胞ＤＭＳＰ先经碱作用转化为ＤＭＳ，在５０℃下作用时间不少于６ｈ，峰高与浓度的双对数线性相关系数大于０．９９。对１９９４年冬、１９９５年夏采自胶州湾     

红色无硫细菌处理高浓度鱼品废水的研究

本文从城市生活污水的沉降污泥中分离出三株红色无硫细菌,经鉴定R1为胶质红假单胞菌(Rhodopscudomonas gelatinosa),R2为沼泽红假单胞菌(R palustris)、RS-1为红螺属(Rhodosprillum)的一种。R1与R2均为兼性需氧和兼性光能利用菌,RS-1为专性厌氧光合菌。作者提出了它们的主要生理、生化特性和最适生长条件,最后确定R1、R2是较有利用前途的优势种类。作者利用上述分离的菌株对高浓度的鱼品废水进行了净化处理试验,得出R1对CODcr的去除率约为65％,R2的去除率为74％以上。二者混合使用可提高至87％。作者还发现废水中的非光合性杂生菌有助于提高光合细菌的净化力。     

海洋资源的化学——Ⅵ杀螟丹中间体硫氰化物的合成研究

This paper deals with the synthesis of 1,3-dithiocyanato-2-dimethylaminopropane by the reaction of 2, 3-dichloro-1-dimethylaminopropane with sodium thiocyanate in H2O,in polar organic solvents CH3OH and 95% CH3CH2OH, and in the presence of several phase transfer catalysts including quaternary ammomium salts and amines. These methods have given a respective yield of 58.4% ,69.5% ,74.1% and 80%,     

马克斯威尔湾和阿得米拉达湾底部硫的早期化学成岩

根据南极半岛西部海区两个海湾的三个站位沉积物样品分析测定结果指出,SO_4~(2-)的还原作用及迁移转化具有明显地区特点并受环境控制。在M_1和R_2站海底,SO_4~(2-)被还原为硫化物。在M_6站表层沉积物中,硫化物被氧化为SO_4~(2-)。     

Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters     

硫铅酸盐“S”型瞬凝水泥干法护壁堵漏技术研究

介绍了硫铝酸盐“Ｓ”型瞬凝水泥干法者漏时使用的配方,阐述了输送工具和扫孔钻具的设计以及灌注工艺技术。     

Sulfur Isotope Fractionation in Magmatic Systems：Models of Rayleigh Distillation and Selective Flux

The effect of Rayleigh distillation by outgassing of SO2 and H2S on the isotopic composition of sulfur remaining in silicate melts is quantitatively modelled.A threshold mole fraction of sulfur in sulfide component of the melts is reckoned to be of critical importance in shifting the δ^34S of the melts mith respect to the original magmas.The partial equilibrium fractionation in a magmatic system is evaluated by assuming that a non-equilibrium flux of sulfur occurs between magmatic volatiles and the melts,while an equilibrium fractionation is approached between sulfate and sulfide within the melts.The results show that under high fo2 conditions,the sulfate/sulfide ratio in a melt entds to increase,and the δ^34S value of sulfur in a solidified rock might then be shifted in the positive direction.This may either be due to Rayleigh outgassing in case the mole fraction of sulfide is less than the threshold,or due to a unidirectional increase in δ^34S value of the sulfate with decreaing temperature,Conversely,at low fo2,the sulfate/sulfide ratio tends to decrease and the δ^34S value of total sulfur could be driven in the negative direction,either because of the Rayleigh outgassing in case the mole fraction of sulfide is greater than the threshold,or because of a unidirectional decrease inδ^34S value of the sulfide.To establish isotopic equilibrium between sulfate and sulfide,the HM,QFM or WM buffers in the magmatic system are suggested to provide the redox couple that could simultaneously reduce the sulfate and oxidize the sulfide.CaO present in the silicatte Melts is also called upon to participate in the chemical equilibrium between sulfate and sulfide,Consequently,the δ^34S value of an igneous rock could considerably deviate from that of its original magma due to the influence of oxygen fugacity and temperature at the time of magma solidification.     

江西彭山锡多金属矿田地质地球化学特征研究

彭山锡多金属矿田位于长江中下游的九瑞地区，是近年来发现的一个以富锡、铅、锌矿产为主的大型矿田。以黑云母二长花岗岩与二云母碱长化岗岩组成的彭山隐伏岩体为中心，各类金属矿床呈“晕圈式”分布。矿床的形成分为2个成矿期共7个阶段，通过对彭山岩体、典型矿床及围岩中的硫同位素、铅同位素、包裹体及稀土资料进行分析，反映出燕山晚期钙碱性花岗岩体的缦位与多金属矿床的形成有着密切的联系，岩浆活动为本区提供了大量的成矿物质。