回注地下——解决气候变化问题

从地球内部开采石油、煤和天然气来供给我们能量。在这类化石燃料燃烧和释放能量时产生了不需要的二氧化碳气体,这会对全球气候产生影响。可以捕集这种二氧化碳,输送到地下并且封存,这样可从根本上减少温室气体的放出量,有助于缓解气候变化,成为向持久供应能量过渡的关键因素。     

Gold Solubility in SiO2—HCl—H2O System at 200℃：a Preliminary Assessment of the Implications of Silicification with Regard to Gold Mineralization

The complexation between gold and silica was experimentally, confirmed and calibrated at 200 °C: $$\begin{gathered} Au^ + + H_3 SiO_4^ - \rightleftharpoons AuH_3 SiO_4^0 \hfill \\ \log K_{(200^\circ C)} = 19.26 \pm 0.4 \hfill \\ \end{gathered} $$ Thermodynamic calculations show that AuH₃SiO ₄ ⁰ would be far more abundant than AuCl ₂ ^? under physicochemical conditions of geological interest, suggesting that silica is much more important than chloride as ligands for gold transport. In systems containing both sulfur and silica, AuH₃SiO ₄ ⁰ would be increasingly more important than Au (HS) ₂ ^? as the proportion of SiO₂ in the system increases. The dissolution of gold in aqueous SiO₂ solutions can be described by the reaction: $$\begin{gathered} Au + 1/4O_2 + H_4 SiO_4^0 \rightleftharpoons AuH_3 SiO_4^0 + 1/2H_2 O \hfill \\ log K_{(200^\circ C)} = 6.23 \hfill \\ \end{gathered} $$ which indicates that SiO₂ precipitation is an effective mechanism governing gold deposition, and thus explains the close association of silicification and gold mineralization.     

大别山榴辉岩一片麻岩杂岩的成因

大别山榴辉岩由辉长岩、大陆拉斑玄武岩和少量泥灰质经高压变质作用形成。大别地块可划分出四个形成条件不同的榴辉岩区,它们代表一种构造－岩石组合体。片麻岩杂岩中各种高压变质岩类的发现证明它们与榴辉岩一起经历了原地高压变质过程。二者变质作用Ｐ－Ｔ参数的差异归因于抬升过程中退变质反应速度的不同。不同地区榴辉岩退变质组合及Ｐ－Ｔ条件与围岩的一致性表明,大别杂岩现今所展示的“递增”变质带是由榴辉岩相退变质作用形成的。高压榴辉岩－片麻岩杂岩的产生是印支期扬子与华北两个大陆板块碰撞的结果。     

华南二叠－三叠系的事件地层与生物地层界线

华南二叠－三叠系界线研究应严格区分事件地层界线与生物地层界线。“界线粘土”层的底界即为事件地层界线。生物地层界线定义不能与“混生层”或“过渡层”的概念连在一起。长兴煤山忠心大队剖面是最好的二叠－三叠系全球界线层型剖面点（ＧＳＳＰ）。二叠－三叠系生物地层界线定义为ＨｉｎｄｅｏｄｕｓｐａｒｖｕｓＭｏｒｐｈｏｔｙｐｅ１的首次出现,其位置就在长兴剖面界线层（混生层）２的内部,比事件地层界线高１５ｃｍ。ＨｉｎｄｅｏｄｕｓｐａｒｖｕｓＭｏｒｐｈｏｔｙｐｅ１的首次出现,即为长兴阶的顶界。     

中国南方离子吸附型稀土矿床成矿类型及其母岩控矿因素探讨

传统认为中国南方的离子吸附型稀土矿床可划分为以“足洞式”为代表的重稀土型和以“河岭式”(或“花山式”)为代表的轻稀土型两种矿化类型。然而，近年来发现的许多矿床(如清溪、寨背和馒头山等)的赋矿风化壳中出现了轻稀土矿与重稀土矿并存现象，表现出特殊的“上轻下重”双层矿体结构。这指示了除重稀土型和轻稀土型之外，还存在着轻重稀土共生型的过渡类型。本研究通过对三种不同成矿类型的若干典型矿床系统对比，指出成矿类型的多样性与母岩性质密切相关，尤其是母岩的稀土元素地球化学和稀土载体矿物属性是制约成矿类型变化的关键因素。统计数据表明，从重稀土型→轻重稀土共生型→轻稀土型，成矿母岩的全岩稀土总量变化不大(ΣREY: 200×10-6~450×10-6→200×10-6~500×10-6→200×10-6~800×10-6)，但轻重稀土配分值出现较显著的区间性差异(ΣLREE/ΣHREY: 02~1→1~5→2~10)。与之同时，母岩中能为离子相稀土提供物源且具有重稀土配分属性的稀土副矿物类型和数量明显减少，这与全岩稀土元素地球化学特征中重稀土分量占比的降低趋势也互相匹配。该结果指示，以往认为重稀土配分母岩形成重稀土矿床、轻稀土配分母岩形成轻稀土矿床的传统观点需要外延，即一部分具有低度轻稀土配分属性(1＜ΣLREE/ΣHREY＜5)且含有丰富易风化稀土副矿物的母岩还可能形成轻重稀土共生型矿床，该认识可为今后离子吸附型稀土矿床勘查工作提供新的找矿依据。     

四川木里耳泽岩溶型金矿床形成条件和成矿机制

四川本里耳泽金-菱铁矿建造矿床,赋存于上二叠统海相碳酸盐岩层中,矿化受古岩溶的严格控制,组成矿石的基本矿物为菱铁矿,金不均匀地分布于菱铁矿矿体内。成矿溶液来自加热的循环地下水。成矿过程分为早阶段和中-晚阶段。成矿温度为156-210℃,成矿深度小于1km.成矿物质主要来自地层。成矿热液呈碱性和弱还原性,贫硫,含中等盐度。矿床形成时的地质构造环境较稳定。这是我国仅见的一种特殊金矿类型。     

扬子地台前寒武纪－寒武纪界线地层的微体植物化石群

前寒武纪一寒武纪界线地层在扬子地台发育良好、分布广泛,并有包括微体植物群、海藻、瓶形原生物、具硬体动物及‘澄江动物群’等化石的发现。因而,扬子地台成为研究前寒武纪－寒武纪界线生物地层的代表地区之一。基于对扬子地台前寒武纪－寒武纪界线地层已知微体植物化石记录的回顾和论定,总结概括了下寒武统微体植物化石组合：寒武系最底部硅质磷块岩中的Ｍｉｃｒｈｙｓｔｒｉｄｉｕｍ－Ｐａｒａｃｙｍａｔｉｏｓｐｈａｅｒａ－Ｍｅｇａｔｈｒｉｘ组合和较高层位页岩的Ｓｋｉａｇｉａ－Ａｎｎｕｌｕｍ－Ａｒｃｈａｅｏｄｉｓｃｉｎａ组合。它们分别与Ａｎａｂａｒｉｔｅｓ－Ｃｉｒｃｏｔｈｅｃａ－Ｐｒｏｔｏｈｅｒｔｚｉｎａ小壳动物化石带和Ｐａｒａｂａｄｉｅｌｌａ及Ｅｏｒｅｄｌｉｃｈｉａ三叶虫带相对应。与东欧地台疑源类生物地层相对照,扬子地台Ｍｉｃｒｈｙｓｔｒｉｄｉｕｍ－Ｐａｒａｃｙｍａｔｉｏｓｐｈａｅｒａ－Ｍｅｇａｔｈｒｉｘ组合的纵向分布大体和东欧地台Ａｓｔｅｒｉｄｉｕｍｔｏｒｎａｔｕｍ－Ｃｏｍａｓｐｈａｅｒｉｄｉｕｍｖｅｌｖｅｔｕｍ组合带相一致,而以上两地台的化石组合产出层位可能都略高于纽芬兰东部剖面,依据Ｐｈｙｃｏｄｅｓｐｅｄｕｍ所厘定的寒武系底界?     

硫铅酸盐“S”型瞬凝水泥干法护壁堵漏技术研究

介绍了硫铝酸盐“Ｓ”型瞬凝水泥干法者漏时使用的配方,阐述了输送工具和扫孔钻具的设计以及灌注工艺技术。     

Sulfur Isotope Fractionation in Magmatic Systems：Models of Rayleigh Distillation and Selective Flux

The effect of Rayleigh distillation by outgassing of SO2 and H2S on the isotopic composition of sulfur remaining in silicate melts is quantitatively modelled.A threshold mole fraction of sulfur in sulfide component of the melts is reckoned to be of critical importance in shifting the δ^34S of the melts mith respect to the original magmas.The partial equilibrium fractionation in a magmatic system is evaluated by assuming that a non-equilibrium flux of sulfur occurs between magmatic volatiles and the melts,while an equilibrium fractionation is approached between sulfate and sulfide within the melts.The results show that under high fo2 conditions,the sulfate/sulfide ratio in a melt entds to increase,and the δ^34S value of sulfur in a solidified rock might then be shifted in the positive direction.This may either be due to Rayleigh outgassing in case the mole fraction of sulfide is less than the threshold,or due to a unidirectional increase in δ^34S value of the sulfate with decreaing temperature,Conversely,at low fo2,the sulfate/sulfide ratio tends to decrease and the δ^34S value of total sulfur could be driven in the negative direction,either because of the Rayleigh outgassing in case the mole fraction of sulfide is greater than the threshold,or because of a unidirectional decrease inδ^34S value of the sulfide.To establish isotopic equilibrium between sulfate and sulfide,the HM,QFM or WM buffers in the magmatic system are suggested to provide the redox couple that could simultaneously reduce the sulfate and oxidize the sulfide.CaO present in the silicatte Melts is also called upon to participate in the chemical equilibrium between sulfate and sulfide,Consequently,the δ^34S value of an igneous rock could considerably deviate from that of its original magma due to the influence of oxygen fugacity and temperature at the time of magma solidification.