光释光测年中石英样品提纯方法的改进

为了解决光释光前处理中遇到的传统方法无法获得满足纯度石英的问题,通过大量对比实验,结合玻璃工艺中石英分离研究成果,最后获得了新的石英提纯流程,与传统方法相比,新方法通过化学分离避免了密度变化对石英长石分离的影响,从而解决了斜长石和岩屑在传统的重液分离中无法剔除的问题,新方法能够获得满足纯度要求和量要求的石英,同时,新方法比传统方法实验室工作效率更高。     

西藏驱龙斑岩铜钼矿床中UST石英的发现:初始岩浆流体的直接记录

单向固结结构(UST)是浅成侵位的岩浆出溶过程中形成的一种特殊结构,一般由梳状石英与细晶(斑岩)岩交互生长而成,少数产于斑岩与围岩接触部位,其内的原生包裹体被认为是初始流体出溶的可靠记录.作者在西藏驱龙铜矿床中首次发现了具有单向固结结构的石英.研究表明,驱龙UST石英存在于后期侵位的二长花岗斑岩与花岗闪长岩的接触部位,部分为高温β石英;UST石英中原生包裹体的成分主要为高盐度液相,除石盐子矿物外,还含有硬石膏等其他子矿物.阴极发光及显微测温结果表明,初始流体的出溶发生在高温(t≥573℃)、高压(P≥150～200 MPa)条件下,出溶的流体为高温、高盐度[w(NaCkeq)为44.5%～58%]流体,同时还具有较高的氧逸度.因形成压力较高,判断UST石英不可能由较浅侵位的二长花岗斑岩岩枝冷凝出溶而形成,从而推测驱龙铜矿床深部存在着孕育成矿斑岩的大型岩基.     

东昆仑南缘布青山构造混杂岩带哥日卓托闪长岩体年代学、地球化学特征及其地质意义

对东昆仑南缘布青山构造混杂岩带哥日卓托闪长岩体进行了锆石U-Pb年代学和岩石地球化学研究,以便对其形成时代和岩石成因进行约束.结果表明,哥日卓托闪长岩锆石Th/U比值(0.63～1.28)较高,阴极发光图像显示锆石内部发育振荡环带,具岩浆成因特点;LA-ICP-MS锆石U-Pb年龄为225.8±1.5Ma(MSWD=0.53),表明其形成时代为晚三叠世早期.岩体的SiO2含量在53.07％～58.74％之间,Al2O3(14.66％～16.17％)含量相对较高,全碱含量较低(4.76％～6.04％),高钾(1.60％～2.90％),里特曼指数σ在1.69～2.66之间,属高钾钙碱性系列.稀土元素总量(∑REE)为158.36×10-6～211.50×10-6,δEu为0.85～0.97,稀土元素配分曲线呈右倾型,具有弱的负铕异常.高场强元素(Nb、Ta、P等)和大离子亲石元素(Ba、Sr、Ti等)具有明显的负异常,而Rb、U、La、Hf、Nd等元素具有明显的正异常.哥日卓托闪长岩形成于高温环境(800℃±),具有后碰撞岩浆活动的特征,是东昆仑地块与巴颜喀拉地块碰撞后地壳部分熔融的产物.     

Association of Late Paleozoic Adakitic Rocks and Shoshonitic Volcanic Rocks in the Western Tianshan, China

The late Paleozoic adakitic rocks are closely associated with the shoshonitic volcanic rocks in the western Tianshan Mountains, China, both spatially and temporally. The magmatic rocks were formed during the period from the middle to the late Permian with isotopic ages of 248-268 Ma. The 87Sr/86Sr initial ratios of the rocks are low in a narrow variation range (-0.7050). The 143Nd/144Nd initial ratios are high (-0.51240) with positive εND(t) values (+1.28-+4.92). In the εNd(t)-(87Sr/86Sr)i diagram they fall in the first quadrant. The association of the shoshonitic and adakitic rocks can be interpreted by a two-stage model: the shoshonitic volcanic rocks were formed through long-term fractional crystallization of underplated basaltic magma, while the following partial melting of the residual phases formed the adakitic rocks.     

秦岭地区黄铁矿特征与金矿关系的研究

根据秦岭地区金矿床中黄铁矿特征,总结出典型的微细浸染型和含金石英脉型两种类型矿床特征。黄铁矿与金矿关系密切,含金黄铁矿多产于成矿的富集地段。通过对该区黄铁矿标型特征(晶形、粒级与热电性和微量元素)的系统研究,认为黄铁矿标型特征的研究,对深部找金矿与远景评价具有指导意义。     

大坪金矿床石英的标型特征及其地质意义

文章论述石英的物理性质、化学成分、包裹体特征及同位素组成,从而提供了有关大坪金矿床的成矿作用、矿床成因及找矿远景等方面的矿物学标志.     

广西佛子冲矿区花岗闪长岩成岩时代讨论

广西佛子冲铅锌矿区岩浆岩发育,其中花岗闪长岩与矿化存在密切的空间分布关系,在花岗闪长岩与围岩接触带形成矽卡岩化,主要铅锌矿体分布于矽卡岩蚀变带中。本文通过对花岗闪长岩和伟晶岩中锆石的研究,并采用LA—ICP-MS对单颗锆石进行了年龄测定,分别获得～228Ma和～248Ma两组和谐年龄,以及一批锆石稀土元素数据。在空间上,伟晶岩脉仅仅分布于花岗闪长岩附近,在伟晶岩中有花岗闪长岩残留。两组锆石样品中的稀土配分特征十分相似,两者的单颗粒锆石同位素年龄值也基本一致,这一时间与广西钦防海槽开始闭合,华夏板块与扬子板块发生碰撞的时间一致;反映出在海西．印支早期沿岑溪．博白深大断裂有一次岩浆上侵于老地层中,形成侵入岩和铅锌矿床。     

桂东北大宁岩体中镁铁质微粒包体的混合成因——来自野外分形特征的制约

大宁岩体是一个多期次侵入的复式岩体,主要由石英闪长岩、花岗闪长岩和二长花岗岩等花岗质岩石组成,其中富含镁铁质微粒包体(MME),MME主要出露在花岗闪长岩中.花岗闪长岩中部和边部MME个数与单位测量面积的特征值(直径)之间均存在对数线性关系(p>0.75),表明MME-花岗质侵入岩体系为分形体.结合MME的形态、结构特征,认为大宁岩体中MME为岩浆混合成因.花岗闪长岩中部和边部MME的分维数分别是1.293和0.991,表明混合程度在空间上具有不均一性.MME长轴展布方向与寄主岩体的原生流动线理方向一致,暗示着在镁铁质岩浆注入之前,长英质岩浆已部分结晶.对流作用可能是MME分布、变形和岩浆混合程度差异的主要驱动力.     

石英-α型SiO_2高压相变的分子动力学研究

采用在经典离子晶体作用势中附加Morse势 ,并进行必要的量子化修正 ,对石英 α型SiO2 结构随压力变化特性进行分子动力学计算模拟 ,获得了压力高于 2 4 .6GPa ,从晶相向非晶相相变模拟结果 ,并利用其离子间相互作用势、摩尔体积变化、键角等重要信息对模拟结果作了深入的探讨 ,获得了与实验结果较一致的模拟结果。     

TL dating of loess in China

TL ages of 56 loess samples collected from Xinjiang and the middle reaches of the Yellow River were determined by using fine-grained quartz and man-made light source bleaching techniques.The results indicate that :1.The well-preserved loess sections in Xinjiang began depositing 400000 a ago.The loess/paleosol series may be comparable with that observed in the middle reaches of the Yellow River but the depositing time was probably delayed by 30000-50000a.2.The bottom boundary age of the Malan loess varies from one place to another.The TL dates can be divided into two group:70000-130000 a and 30000-50000 a.The TL data are con-sistent with the appearance of two warmer climate periods since the Pleistocene,indicating obvious regional differences in stratigraphic development of loess,i.e.,paleosol occurred in the warm climate period in the same location,but loess was deposited in other locations.The initial age of loess deposition tends to become older from west to east and from south to north .In contrast ,the cold cli-matic belt showed an opposite trend.The TL ages of loess provide strong evidence for the Quaternary stratigraphy throughout geological times and the shift tendency of climatic belt.3.The depositing rate of the Malan loess along the middle reaches of the Yellow River varies from place to place but the TL age shows a linear relationship with the depositing thickness.The de-positing rate of loess in the north is higher than that in the south,suggesting that loess materials are derived from desert areas of northern China.