A TEM Study on Fluid Inclusions in Coesite-bearing Jadeite Quartzite in Shuanghe in the Dabie Mountains

Fluid inclusions at a nano to sub-micron scale in quartz from jadeite quartzite at Shuanghe, Dabie Mountains, have been investigated by using the transmission electron microscopy (TEM). Most fluid inclusions are spherical or negative crystal shaped, forming wide swarm-like trails. The TEM reveals that the relationship between coesite and the host quartz is syntaxic and provides strong evidence of the occurrence of high-salty fluids at peak metamorphic conditions. The fluid inclusions are often connected to dislocations, which are undetected at the scale of optical microscopy. Non-decrepitation leakage of fluid inclusions may occur by pipe diffusion of molecule H2O or CO2 along dislocations from the inclusions into the host quartz, thus leading to original inclusion density and composition changes. It should be taken into full account for the correct petrological interpretation of micro-thermometric results.     

大陆俯冲带大规模的变质流体活动:来自大别造山带超高压硬玉石英岩的记录

硬玉石英岩是一种稀少且与流体作用相关的变质岩,同时出露于高压或超高压洋壳和陆壳俯冲带中.通过对中国东部大别造山带中出露达50 km2的含柯石英的超高压硬玉石英岩进行研究,综合全岩主微量元素、矿物Mg-O同位素和锆石学研究.结果表明,硬玉石英岩的原岩为古元古代TTG岩石,经历过弱化学风化和强物理风化作用,然后在三叠纪时期受到围岩富黑云母片麻岩分解脱水而产生的大量重Mg同位素流体交代,从而形成硬玉石英岩.考虑到这种受流体交代成因的硬玉石英岩在大别山广泛出露,表明其在三叠纪大陆深俯冲过程中存在着大规模的变质流体活动,这项研究首次报道了大陆俯冲带有大规模的流体活动存在,同时也挑战了传统观点认为的大陆俯冲带缺乏岛弧岩浆作用主要原因是缺乏足够量的流体活动.      

华中高压－超高压变质富铝岩石的温压条件研究及其地质意义

华中高压－超高压变质富铝岩石为陆壳岩石经变质而成，其典型的岩石类型为蓝晶石黄玉石英岩。矿物温压计估算其ｐ－Ｔ条件为Ｔ＝７００℃，ｐ＝１．２ＧＰａ；高温高压实验结果表明，蓝晶石＋黄玉组合在Ｔ＝１０００～１２００℃，Ｐ＝３．１～３．７７ＧＰａ范围内可以稳定存在，是高压－超高压变质作用产物。在蓝晶石石英岩中发现柯石英及柯石英假象，区域上其它岩石组合也有高压－超高压变质作用的证据。变质富铝岩石为榴辉岩相变质作用产物，从而证明陆壳岩石可以经历＞２．０ＧＰａ的变质压力条件。     

大别山双河硬玉石英岩的超高压变质和退变质事件——SHRIMP测年的证据

应用北京SHRIMPⅡ,精确地测定了大别山双河硬玉石英岩中超高压变质锆石的中心、幔和壳的年龄。大部分锆石中心和幔的年龄集中于239～255Ma之间,加权平均值为243±1Ma(n=23)。壳和含矿物包体的晶域年龄集中在225～234Ma,加权平均值为228±2Ma(n=8)。这些锆石的中心、幔和壳都具有极低的Th/U(0.01～0.09)和REE总量,以及重REE平坦型的配分模式。因此,以锆石内部结构、矿物包体、Th/U值和REE地球化学特征为依据,本文提出了大别山超高压变质作用发生于243±1Ma,退变质作用发生于228±2Ma的新观点。     

Geochemistry of the Shushui Complex,South Shanxi Province,China

The Shushui Complex can be divided into three rock units based on field investigation, petrography and geochemistry:(1) felsic gneisses, (2) supracrustal rocks consisting of amphibolite, marble and quartzite, and (3) late granites. Of the complex, felsic gneisses are dominant and formed in the Late Archaean, which were intruded by a basic dyke with a whole-rock Rb-Sr isochron age of 2264±219 Ma. The data on rare-earth elements as well as on major and trace elements presented for most of the rock types making up the complex suggest that (1) basic gneisses were produced by partial melting of mantle peridotite, followed by fractional crystallization, and (2) felsic gneisses produced by varying degree of melting of a mafic source. The most suitable tectonic setting to account for the generation of both types would be similar to the underplate setting.     

赞皇杂岩官都岩群时代与物源——来自黑云变粒岩与石英岩碎屑锆石U-Pb-Hf同位素与稀土元素组成的约束

官都岩群是华北克拉通中部造山带赞皇杂岩中重要的变质火山-沉积岩系,经历了高绿片岩相-高角闪岩相变质,准确限定其沉积时代与物质来源对探究中部造山带新太古代-古元古代构造演化过程具有重要意义。利用LA-MC-ICP-MS(多接收激光剥蚀电感耦合等离子质谱仪)与TIMA(矿物自动分析系统)对官都岩群中黑云变粒岩与石英岩进行了锆石矿物包体、U-Pb-Hf同位素与稀土元素原位分析。根据碎屑锆石内部矿物包体组成、阴极发光图像特征与U-Pb年龄结果,认为黑云变粒岩与石英岩中碎屑锆石中最年轻一组的²⁰⁷Pb/²⁰⁶Pb谐和年龄分别为2 544 Ma或2 536 Ma,大致限定了其原岩的最老沉积时代,结合区内黄岔花岗岩岩体侵入官都岩群的野外地质关系,推测官都岩群沉积时代为新太古代末期,并非古元古代。官都岩群黑云变粒岩与石英岩碎屑锆石年龄图谱十分相似,最主要的峰值年龄为2 512 Ma,结合碎屑锆石内部矿物包体与结构特征,认为官都岩群主要物源为新太古代晚期中酸性岩浆岩。两阶段锆石Hf模式年龄揭示2 850～2 700 Ma为赞皇杂岩最强烈的地壳生长阶段。综合本文...     

大别山菖蒲硬玉石英岩退变质作用过程中岩石地球化学的变异

在大别山菖蒲地区新鲜硬玉石英岩逐步退变为片麻岩的变质作用过程中,其岩相学以及地球化学元素发生了一系列有规律的变化。ＳｉＯ２,ＦｅＯ,微量元素Ｂａ,Ｚｒ,Ｇａ以及稀土元素Ｌａ,Ｃｅ,Ｐｒ,Ｎｄ,Ｓｍ,Ｅｕ逐步升高,而ＴｉＯ２,Ｎａ２Ｏ,Ｆｅ２Ｏ３微量元素Ｒｂ,Ｙ,Ｎｂ以及稀土元素Ｇｄ,Ｔｂ,Ｄｙ,Ｈｏ,Ｅｒ,Ｔｍ,Ｙｂ则逐步降低。这反映了矿物晶内的元素的迁移以及外来流体的参与在一定的程度上制约一岩相     

一种深绿色翡翠仿制品的宝石矿物学特征

采用常规宝石学仪器、红外光谱、拉曼光谱、X射线粉晶衍射、X射线荧光光谱和紫外-可见吸收光谱等方法,对一种类似于翡翠的深绿色玉石品种进行了常规宝石学、谱学特征、矿物成分及化学成分的研究。结果显示,该样品的折射率为1.52～1.54(点测),密度约为2.65 g/cm³,其主要矿物组成为石英、钠长石和铬白云母,另含有微量金红石、榍石和磁铁矿。石英的特征红外吸收峰为799和780 cm^-1,钠长石的最强吸收区位于1200～900 cm^-1;钠长石的特征拉曼位移为479、507 cm^-1,石英的最强拉曼位移为463 cm^-1,白云母的主要拉曼位移为263、701 cm^-1。紫外-可见吸收光谱测试表明样品的致色元素为铬。根据岩石分类和命名方案,样品定名为铬白云母钠长石石英岩。