贵州省晴隆大厂锑矿锰离子分配特点的初步研究

本文用电子顺磁共振方法详细地分析了贵州省晴隆大厂锑矿田各种矿物锰离子的存在形式,并结合众多的化学分析资料,阐述了矿田中锰离子的分配规律及与锑矿化的关系,指出在大厂矿田的成岩成矿过程中,锰没有象锑那样充分转移富集,其地球化学行为表现为一种“惰性”,各类矿物和岩石中锰的含量均很低,没有锰的载体矿物形成。同时,还进一步论述了对锰离子的研究在解决金属矿床某些问题时具有成因方面和找矿方面的双重意义。     

测机舍电子经纬仪测角系统剖析

本文剖析日本测机舍电子经纬仪测角系统的结构特点,阐述旋转编码度盘DISK和MASK是属增量制式的静态测角方法。本文还论述了磁性液体倾角传感器的原理。     

方解石中Mn~(2+)离子四级EPR晶场参量α_0随温度变化的研究

本文研究表明,对方解石中Mn~(2+)离子的四级EPR晶场参量α_0,虽然其轴向场部分的贡献远小于立方场部分,但二者随温度的变化却差别不大,原因是轴向晶场参量F对键角变化十分敏感。因此,在研究热膨胀系数明显各向异性的晶体中的α_0随温度变化时,不能忽略轴向场部分的贡献,即不能假设α_0≈-α。     

Electronic Structures of Square Planar Coordinated Transition Metal Ions in Compounds with Gillespite Structure

Electronic structures of square planar coordinated transition metal ions in BaCuSi₄O₁₀ and CaCrSi₄O₁₀ are investigated using the ligand-field theory (LFT), angular overlap model (AOM) and iterative extended Hückel molecular orbital theory (IET). The electronic energy levels of the natural mineral dioptase are also investigated, in which the Cu²⁺ ions occupy the sites of pseudo D_4h symmetry. Both LFT and AOM predict that the crystal-field levels of transition metal ions in these compounds follow such an order that E (²B_1g <E(²B_2g <E(²A_1g )<E(²E_g ), and the frequencies of the crystal-field transitions obtained from point charge calculations are in good agreement with those observed. However, the energy-level order cannot be determined unambiguously from the IET calculation because it depends on the values of parameters chosen for the calculation.