Speciation analysis and significance of ecological geochemistry

Different species of one element have different activities, so it has different effects on environment and human health. To analyze qualitatively and quantitatively the speciation of a special element in sample, which is the important basis for appraising the toxicity and studying the rule of transfer and translation of elements. Since the 1970＇s, the scheme of sequential extraction has already been used at many laboratories both at home and abroard, to get the information about heavy metals＇ activity in polluted soils. Because this method has the experimental nature, many schemes of problem has taken place, the absence of consistency of these sequential extraction have been formed. Thus the complexity of the schemes, the lack of selectivity of reagent, the lack of quality control, the result mainly related to the extraction scheme used, and so on. In the face of these problems, the study of experimental methods of sequential extraction on three different soils, sediment in Dongting Lake, soil in Jiangsu Province and loess in Shanxi Province was made. Reference materials of heavy metal speciation following sequential extraction in soil and sediment had been developed. Nowadays two kinds of sequential extraction methods which are widely used are BCR （three steps） and improved Tessier methods （seven steps）. Based on three steps of BCR, water-soluble speciation and the residual speciation were increased in our research. BCR701 was determined eight times at different laboratories using BCR three steps. The results showed that determined data obtained eight times were identical to the standard value, and it is indicated that this method has good reproducibility. The stability and homogeneity experiments indicated that the preparation of three types of candidates accorded with our requirements. Eight laboratories had afforded the determined values of 12 heavy metal elements （Cu, Pb, Zn, Mn, Co, Ni, Cd, Cr, Mo, As, Sb, Hg, Se et al.） using BCR three steps. Also, these three candidates afforded the determined values by seven steps, and 12 laboratories had participated.     

Methylmercury and human biomarkers： Questioning the evidence

Methylmercury （MeHg） is a powerful neurotoxicant in humans. In terms of biomarkers of MeHg exposure, hair and blood have long been used in epidemiological studies as the biomarkers of choice. In fact, total hair mercury （Hg） content as well as organic blood Hg concentrations reflects exposure to organic Hg from food consumption. Extensive studies, establishing a constant and linear relation between MeHg intake versus Hg levels in hair and blood, were conducted by governmental officials to establish guidelines on safe levels of MeHg exposure, which were translated into threshold daily fish consumption rates （usually expressed as μg MeHg per kg bodyweight）. Nowadays, in most epidemiologic studies blood or hair mercury （Hg） level is commonly used as a valid proxy to estimate human exposure to methylmercury （MeHg） through fish consumption without relating this signal to actual fish consumption patterns among populations. Human variability in mercury toxicokinetics was identified and measurement error has been pointed out to be a substantial contributor to observed variability, particularly where dietary information is retrospective and self-reported. However, experimental evidence indicates that significant variability among individuals may exist in the biokinetics of mercury. Also recent findings from previous population-based studies through COMERN initiative also revealed that MeHg metabolic processes might greatly vary across populations. In fact, it is unlikely that the magnitude of the difference measured between observed and expected levels of mercury, given the reported intake, can be entirely explained by laboratory measurement errors or reporting bias.     

Study on Kailyard soil amendment by adding compost of sludge

Mixture of municipal sewage sludge and organic garbage, which was alternatively treated by aerobic and anaerobic composting technologies for 60 days. The characteristics of the compost are as follows： the total nitrogen （TN）, total phosphors （TP） and total potassium （TK） are 1.40%, 0.101% and 1908.32 mg/kg on dry weight basis, the contents of Cu, Ni, Cd, Cr, Pb and Zn are 131.23, 21.49, 1.31, 35.49, 72.50 and 616.76 mg/kg on dry weight basis. A basin-scale experiment was carded out by planting watercress with kailyard soil fertilizing with the compost, the results showed that the municipal sewage sludge and organic garbage compost could promote the production of watercress to different degrees, the crop biomass increased from 74.46% to 312.00% with the amount of compost fertilizing on the kaliyard soil while the amount of compost fertilizing on the kaliyard soil below 150 g per 3.75 kg kaliyard soil and decreased from 312.00% to 102.29% while the amount of compost fertilizing on it over 150 g per 3.75 kg kaliyard soil, so the optimal addition of compost in the watercress and soil was 150 g compost per 3.75 kg kailyard soil. Furthermore,     

Influence of humic acid on bioavailability of heavy metals in sediments

The mimetic ocean environment and chemical method were used to research the bioavailability effect of humic acid on five heavy metals in sediment, including Cd, Cu, Zn, Pb and Ni. The sediment was separated into four containers with artificial seawater, and each of them had different concentrations of humic acid. The values of concentrations covered the whole range found in natural sediment （0.1%-10%）. According to the 48 hours LC50 of clam and distribution coefficient, metals were added in artificial seawater, and their speciation was determined at first and then after two days＇ incubation. It was found the bioavailability of heavy metals was reduced in the presence of humic acid. The obvious negative effect on Zn was observed, but the influence on Cd was not remarkable. In addition, the contents of Pb and Ni increased obviously in organic phase, and they are correlative with the concentrations of humic acid.     

《生物地理学》实践教学改革与大学生创新能力培养

当前,社会对人才创新能力与实践能力的要求越来越高,如何培养高素质创新能力的人才已成为检验高等教育的重要标志。本文探讨了将“自主、探究与合作的学习方式”运用于《生物地理学》实践教学,激发学生的创新思维,学习科学研究的方法,发展综合运用知识的能力,培养创新能力。     

桂北地区早石炭世杜内期的长身贝类的发现及其生物古地理意义

在广西北部兴安县高尚镇金子山剖面下石炭统鹿寨组底部，新发现了长身贝类腕足化石，包括1新种、1个相似种、6个未定种和2个属种未定类型。这些长身贝类以Productellidae和Productidae科的分子为主，另有少量Echinoconchidae和Monticuliferidae科的分子。这些长身贝类全部属于生活在静水环境中的薄壳类型，无一与华南同期地层中已知类型相同。它们之间的差异可能反映了不同沉积环境条件对腕足动物群属种的控制。在鹿寨组底部发现的长身贝类以及近年在桂林南边村和黔南睦化剖面腕足动物群的发现显示出华南台缘斜坡―盆地相区杜内阶中的腕足动物群具有极高的属种分异度，不但有大量见于世界其他地方同期动物群中的分子，也包含有不少原本认为只在维宪阶或更高层位出现的类型或全新的类型，说明华南台缘斜坡―盆地相区不但与世界其他地区的腕足动物群之间存在密切的生物地理区系联系，而且华南台缘斜坡―盆地相区是杜内期腕足动物起源和辐射演化的重要策源地之一。许多属种可能是在这里起源，并迁移扩散到其他地方。     

酶法催化餐饮废油制备生物柴油的研究

以废物资源转化为宗旨,利用固定化脂肪酶催化餐饮废油与乙醇反应制备生物柴油,通过实验获得最佳酯化反应条件:反应温度47℃、有机溶剂为正己烷、醇油比3∶1,5次投加乙醇,酶用量为0.3g,反应时间32h时,生物柴油产率可达81%。     

控制内蒙古二连盆地达尔其油田石油富集度的关键因素——不同油源原油的混合作用

在对3套烃源岩的质量和成熟度描述基础上,通过对原油物理性质、族组成和生物标志化合物参数的研究,在达尔其油田内划分出成熟度有明显差异的低熟油和成熟油。油源对比结果认为它们分别由都红木组一段低熟烃源岩和阿尔善组二段成熟烃源岩所生。推测成熟度参数介于低熟和成熟之间的原油为混源油。通过原油混合试验和油砂连续抽提试验证实了混源油的推测。通过油藏剖面中不同性质油层的分布特征研究,结合断层发育史与油气运移关系分析认为不同油源原油的混合是控制该油田石油富集度较高的关键因素。此外,还分析了控制混源的断层组合特征。     

滇黔桂盆地及其邻区石炭纪至二叠纪层序地层格架及三级海平面变化的全球对比

属于被动大陆边缘裂谷盆地的滇黔桂盆地，自加里东运动之后，泥盆纪开始拉开，整个晚古生代延续发展。受同生断裂的控制，在深水盆地中发育大小不等的孤立碳酸盐台地，因而在滇黔桂盆地及其邻区形成特殊的“台-盆-丘-槽”的古地理格局。对不同古地理背景下的典型剖面进行三级层序划分并对其进行空间追索和对比，在滇黔桂盆地及其邻区的石炭纪和二叠纪地层中可以识别出12个三级层序，相当于晚古生代25个三级沉积层序(2-5Ma；SQ1至SQ25)中的SQ24至SQ25；以地层记录中的的两种相变面和两种穿时性为基本要素，可以建立研究区石炭系和二叠系的层序地层格架；层序地层格架反映了三级层序的基本特征：空间上相序的有序性和时间上环境变化的同步性。研究区的石炭系和二叠系，主要为一套碳酸盐岩地层，其中在连陆台地上发育3套煤系地层，它们分别组成石炭纪三级层序SQ15跨系的三级层序SQ19的HST以及二叠纪吴家坪期的三级层序SQ24；而且在连陆台地边缘和孤立台地上，于阳新世的茅口亚世以及乐平世的长兴期发育海绵生物礁，海绵生物礁分别构成了以下二叠系三级层序即阳新世的SQ22和SQ23以及长兴期的SQ25。3套煤系地层和两套海绵生物礁的发育，使研究区的石炭系和二叠系形成了一个与欧美地区完全不同的层序地层序列。在研究区石炭系和二叠系所识别出的12个三级层序中，石炭纪一二叠纪船山世地层可以划分出6个三级层序。这种划分与Busch等对北美相同层位的划分相似，也就是说该6个三级层序的形成时限大于10Ma；较长的形成时限可能反映了形成在联合古陆汇聚时期即全球构造相对稳定时期三级海平面变化的一个特性。因此，研究区的石炭系和二叠系所识别和划分出的12个三级层序，其数量比Ross和Ross(1985)对欧美地区石炭系和二叠系所划分出的50多个三级层序要少得多。     

我国湿地面积亚洲第一

近期完成的全国首次湿地资源调查显示，我国现有湿地面积3848万hm^2，居亚洲第一位，世界第四位。