壳聚糖及其衍生物在水处理中的应用

壳聚糖(Chitosan)是甲壳素(Chitin)的脱乙酰化产物,本身为线型分子,分子链中含有反应性基团羟基(-OH)和氨基(-NH2)。在酸性溶液中,由于-OH和-NH2的存在,壳聚糖可形成高电荷密度的阳离子聚电解质,能够凝聚溶液中带负电的悬浊液、有机物     

海山富钴结壳标准物质研制

报道了我国与俄罗斯合作研制的三个海山富钴结壳标准物质GSMC-1,2,3.这三个标准物质的原样分别取自西太平洋麦哲伦海山和中太平洋海山.样品经风干、选配、球磨制备成均匀的粉体样品,其均匀性采用高精度的X-射线荧光光谱法检验.样品的化学组分采用国内外多实验室协同分析方式定值,有八个国内实验室和八个国外实验室参加了合作分析.测试组分均为57个,其中GSMC-1,2有43个组分定为保证值,10个组分作为参考值;GSMC-3有45个组分定为保证值,8个组分作为参考值.经2a多的试用,三个标准物质已于2005年被国家计量部门批准为国家一级标准物质,其编号分别为GBW07337,GBW07338和GBW07339.     

Mineral provinces and matter provenance of the surficial sediments in the western Philippine Sea: implication for modern sedimentation in West Pacific marginal basin

The characteristics and distribution patterns of detrital minerals (0.063~0.125 mm) in marine sediments provide a significant indicator for the identification of the origin of sediment.The detrital mineral composition of 219 surface sediment samples was analysed to identify the distribution of sediments within the western Philippine Sea. The area can be divided into three mineral provinces: (I) province east of the Philippine Trench, the detrital minerals in this province are mainly composed of calcareous or siliceous organisms, with the addition of volcanogenic minerals from an adjacent island arc; (II) middle mineral province, clastic minerals including feldspar, quartz and colorless volcanic glass, sourced from seamounts with intermediate-acid volcanic rock, or erupting intermediate-acid volcano; (III) province west of the Palau—Kyūshū Ridge, the matter provenance within this province is complex; the small quantity of feldspar and quartz may be sourced from seamounts or erupting volcano with intermediate-acid composition, with a component of volcanic scoria sourced from a volcano erupting on the Palau—Kyūshū Ridge. it is suggested that, (1) Biogenic debris of the study area is closely related to water depth, with the amount of biogenic debris controlled by carbonate lysocline. (2) Volcaniclastic matter derived from the adjacent island arc can be entrained by oceanic currents and transported towards the abyssal basin over a short distance. The weathering products of volcanic rocks of the submarine plateau (e.g.,Benham Plateau) and adjacent ridges provide an important source of detrital sedimentation, and the influence scope of them is constrained by the intensity of submarine weathering. (3) Terrigenous sediments from the continent of Asia and the adjacent Philippine island arc have little influence on the sedimentation of this study area, and the felsic mineral component is probably sourced from volcanic seamounts of intermediate-acid composition.     

辽宁省海岸带水资源可持续发展模糊迭代分区研究

给出一种模糊聚类循环迭代模型以及通过模糊二元对比赋权与迭代赋权相融合的组合赋权方法,采用交叉循环迭代的方法确定聚类中心矩阵,通过判断聚类准则函数获得最终聚类矩阵.该模型兼顾了主观决策与客观决策,使聚类分析具有很大的柔性,最后将模型应用到辽宁省海岸带30个县(市)区的水资源可持续发展分区研究中,按照水资源可持续发展评价的9个指标分为4个类别,结果表明,模型聚类分区结果比较合理.     

不同过滤条件下黄色物质的吸收光谱演化特征分析

在实验室对青岛近岸现场水样进行处理、分析,获得了原始状态下水样和被过滤（0.22μm,0.45μm）黄色物质水样的吸收光谱数据,除进一步验证了黄色物质光谱分布模式外,还测得黄色物质光吸收随滤膜孔径的变化。30个现场样品在波长380nm处吸收系数统计平均值^—Ay（380）分析表明,当使用0.45μm过滤器对水样进行处理,所获得的^—Ay（380）值要比未经过处理的现场水样所测得的^—Ay（380）值高约2.1％;而用0.22μm过滤器对现场水样进行处理,所获得的^—Ay（380）值要比未经过处理的现场样品所测得的^—Ay（380）值高约12．6％,要比用0．45μm过滤器处理的现场样品所测得的^—Ay（380）值高约10.3％,这些数据的获得为现有已获黄色物质数据的“归一化”和统一评判以及未来黄色物质测量数据的准确性判断与比较提供了参考。     

楚科奇海表层沉积物的生源组分及其对碳埋藏的指示意义

工业革命以来大气中CO₂浓度由280 ppm剧增至375 ppm,是导致全球气候变暖的主要原因[1]。海洋作为大气CO₂的“汇”之一,每年可吸收人类释放CO₂气体总量的30%,对全球碳循环的收支平衡有重要作用[2]。两极地区是CO₂的主要汇区,也是全球变化的重要反馈窗口。因此,了解碳在北冰洋的生物地球化学循环过程是十分必要的[3-4]。海洋中的生源沉积物主要来自于海洋上层浮游生物碎屑的沉降,主要由蛋白石(以生物硅代替,BSi)、碳酸钙(CaCO₃)和有机质(通常用有机碳替代,TOC)组成[5]。     

河口物质和水体长期输运分离的理论分析和观测验证Ⅰ.物质和水体长期输运分离的理论分析

基于单宽断面潮周期平均水体和物质对流输运通量,定义了二维水体和物质长期输运速度,它们分别描述单宽断面水体和物质长期输运的方向及快慢。通过二维水体和物质长期输运速度的对比分析,提出了物质和水体长期输运分离概念:受物质浓度影响,在物质和水体瞬时运动速度相同的情况下,物质和水体潮周期平均对流输运的方向和快慢可能存在差异。本文将二维物质长期输运速度分解为二维水体长期输运速度、二维潮泵输运速度和垂向切变输运速度,它们分别描述余流输运、潮泵输运和垂向切变输运,后两种输运造成单宽断面物质和水体长期输运分离。本文的分析表明,河口受地形、径流、潮流、密度梯度影响,存在有利于物质和水体长期输运分离的自然条件。     

Low-temperature alteration of oceanic island basalts and their contribution to transition metal circulation of the ocean

The major elements, rare earth elements （REE） and trace elements of four basalt samples from central and western Pacific ferro- manganese crust provinces have been analyzed using chemical methods and ICP - MS, respectively. The results indicate that the samples have been extensively altered and that the contents of their major elements have changed significantly. However, the similarity of REE partition patterns and trace element contents of basalt samples to those of fresh oceanic island basalts （OIB） indicate that the basalt samples originated as OIB. Because of low-temperature alteration, the contents of A1203 , Fe203 , MnO, K20 and P205 increased, while MgO and FeO decreased. Active components, such as magnesium and iron, were leached from OIB resulting in the relative enrichment of SiO2. The leaching of active components can cause the relative enrichment of REE, while the precipitation of LREE-rich ferromanganese oxides in vesicles and fissures not only causes an increase of REE contents, but also induces ＂fractionation＂ of LREE and HREE. Based on the enrichment mechanism of REE contents, the theoretical quantities of precipitated ferromanganese oxides and the depleted quantities of active components are calculated ： the depleted quantities of active components for the unit mass of fresh basalts vary in the range of 0.15 ～ 0. 657, and the precipitated quantities of ferromanganese oxides for the unit mass of fresh basahs vary in the range of 0. 006 ～ 0. 042. Of the major elements, the two most depleted are iron, and magnesium, with 18.28% ～ 70.95% of iron and 44.50% ～ 93.94% of magnesium in the fresh basalts was leached out. Theoretical calculation and geochemistry results both indicate that low-temperature alteration of basalts can supply abundant amount of metals to seawater, and may play an important role in ocean metal circulation.     

Natural thermoluminescence of fossil foraminiferals as a potential proxy for deep-sea temperature changes

Foraminiferal shells from two piston cores separately located at the Ninetyeast Ridge and the Bengal Fan of the Indian Ocean were selected and purified for measurements of natural thermoluminescence （NTL） intensity by a high precision thermoluminescence meter （RGD-3）. Variations of the NTL intensity along the two core sequences both spanning the last two glacial--interglacial cycles displayed a strong, identical signal of the global ice volume cycles, which matched well with their corresponding oxygen isotope data. As higher NTL intensity occurred within interglacial periods and changes in an NTL signal were most likely influenced by the temperature of ambient seawater in which the planktonic foraminiferal shells long existed, the NTL signal could be considered as a potential proxy for orbital scale temperature changes of bottom seawater in the tropical Indian Ocean.     

Wind impact on pollutant transport in a shallow estuary

A three-dimensional numerical model, EFDC （ environmental fluid dynamics code） is applied to the Pamlico River Estuary （PRE） in eastern North Carolina of the United States to examine the wind impact on pollutant age distributions and residence time. A series of model experiments representing base case, remote-wind-induced water level set-up and local winds cases are conducted. Model results indicate that the pollutant mean age and the system residence time are functions of gravitational circulation in the PRE. The system responses to remote-wind-induced water level set-up are different in different portions of the PRE. Under such condition, dissolved substances in the upstream portion of the PRE have a younger age and shorter residence time （compared with the base case） , by contrast, they have a older age and longer residence time in the downstream portion of the PRE. Upriver and downriver local winds appear to have opposite impacts on pollutant age distributions. The substances are retained much longer within the PRE under upriver wind than those under downriver wind. The model results also suggest that across - river winds may lead to longer residence time through enhanced turbulence mixing, which slows down the gravitational circulation in the PRE.