青藏高原新生代火车头山碱性及钙碱性两套火山岩的地球化学特征及其物源讨论

藏北羌塘火车头山新生代火山岩可区分为钙碱性及碱性两个不同的系列。钙碱性火山岩主要岩石组合为玄武岩-安山岩-英安岩,其SiO_2介于49%～70%之间,Al_2O_3>10%,Na_2O/K_2O>1;其中玄武岩具平坦型稀土配分型式,LREE/HREE为1.3～1.8,(La/Yb)_N为2.87～4.45,无明显铕异常,δEu为0.96～1.09;该套岩石的Mg~#与SiO_2相关关系以及La/sm-La等亲岩浆元素与超亲岩浆元素协变关系表明,它们应为幔源岩浆经分离结晶演化的产物,其岩石组合类型以及低的Sm/Yb值(Sm/Yb=1.53～5.35)表明它们的原始岩浆应来源于岩石圈地幔尖晶石二辉橄榄岩的局部熔融。本区碱性火山岩为一套典型的钾质岩石系列,主要岩石组合类型为碱玄岩-碱玄质响岩-响岩,其SiO_2介于44%～59%之间,Al_2O_3>14%,Na_2O/K_2O介于0.47～1.51之间;岩石轻稀土强烈富集,LREE/HREE为13.20～15.76,(La/Yb)_N=50.44～91.99;其岩石组合类型以及Mg~#与SiO_2相关关系以及La/Sm-La协变关系同样表明它们为共源岩浆分离结晶演化的产物;然而,其较高的Sm/Yb值(Sm/ Yb=2.63～13.98)表明它们并非地幔橄榄岩直接局部熔融的产物,岩石弱的负Eu异常(δEu=0.77～0.85)以及Th、U的强烈富集和Nb、Ta的相对亏损,又反映了原始岩浆中有显著的地壳物质的贡献;该套钾质碱性系列岩石在La/Co-Th/Co同分母协变图上呈直线型分布,而在La/Co-Sc/Th异分母协变图上呈显著的双曲线分布,从而表明其源区为二源混合型,是青藏高原特殊的壳幔混合层局部熔融的产物,这些特征是新生代青藏高原壳幔层圈物质交换的重要岩石学证据。     

1994年玻利维亚地震破裂过程中的摩擦熔融

１９９４年玻利亚地震的震源参数显示最大地震效率η为０．０３６,最小摩擦应力为５５０ｂａｒ。因此震源过程虽耗散,这与观测到的慢破裂速度相一致。破裂速率仅是局部Ｓ波速度的２０％。在玻利维亚破裂中产生的非辐射能可以与１９８０年圣海伦斯火山喷发的热能相比,或者还大于它,足以融化３１ｃｍ厚的地层。一旦破裂开始,熔融就可能发生,使摩擦力减弱并促使断层滑动。     

川西北塔公石英闪长岩地球化学特征和岩石成因

川西北塔公地区位于青藏高原东部,属于松潘—甘孜造山带的东南部边缘。塔公石英闪长岩侵位于晚三叠世地层中,岩体的K-Ar同位素年龄为134~136Ma,形成于早白垩世。岩石SiO2质量分数为61.37%~62.25%,铝饱和指数为0.93~0.95,全碱质量分数为5.46%~5.77%,里特曼指数为1.62~1.74,样品属于亚碱性准铝质高钾钙碱系列石英闪长岩。岩石Mg#值较高,总体具有高Sr含量、低Nd含量的同位素地球化学特征。N(87Sr)/N(86Sr)值为0.712 589~0.713 009,初始N(87Sr)/N(86Sr)值为0.709 503~0.709 878,N(143 Nd)/N(144 Nd)值为0.512 135~0.512 196,εNd(t)值均为负(-8.6~-7.5),Nd模式年龄为1.33~1.41Ga,Hf模式年龄为1.13~1.37Ga。该岩体是早白垩世期间,川西北地区陆缘-陆内造山环境下由松潘—甘孜造山带古老的下地壳镁铁质物质局部熔融形成的晚碰撞-碰撞后非分异Ⅰ型花岗岩类。     

Mineralogical and Petrological Characteristics of the Neoproterozoic Orthoamphibolite and Orthogneisses in the Mutki Area, the Bitlis Massif, Southeast Turkey

<正>The rocks form as amphibolite±garnet±epidote and orthogneisses in the Pan-African basement of the Bitlis Massif.The petrochemical data of the studied metamorphic rocks suggest different igneous protoliths ranging from calcalkaline basalt to andesite in composition. Petrochemically,the rocks can be classified as group 1(low Zr and La) and group 2(high Zr and La), all showing various enrichments in large ion lithophiles and light rare earth elements,and a depletion in high-field strength elements,suggestive of a destructive plate margin setting.The protoliths of the all samples might have formed mostly by the partial melting of an enriched source,possibly coupled with the fractional crystallization of plagioclase,apatite,and titaniferous magnetite±olivine±clinopyroxene±amphibole in relation with subduction-related magmatism neighboring the Andeantype active margins of Gondwana.The group 2 samples could,however,be generated by a relatively lower degree of the partial melting of an inhomogeneous source with a preponderance of a high-level, fractional crystallization process in comparison to group 1.The protoliths of the samples were metamorphosed up to amphibolite facies conditions,which destroys original igneous texture and mineral assemblages.Geothermobarometric calculations show that the metamorphic rocks are finally equilibrated between 540 and 610℃and～5 kbars,following a clockwise P-T-t path.     

熔融制样波长色散X射线荧光光谱法测定白云石中钙镁硅铁铝

白云石属碳酸盐矿物,应用熔融制样X射线荧光光谱法测定其中主次量组分钙、镁、硅、铁、铝时,由于白云石灼烧减量大,在试料片制备过程中,如果以干基试料制备试料片,除灼烧减量外还有少量其他组分被分解出的大量CO₂带走,导致试料损失,测定结果偏低;如果以灼烧基试料制备试料片,由于灼烧后的试料极易吸收空气中的水分和CO₂,同样使测定结果偏低。基于质量守恒原理,本文直接以灼烧减量测量后的灼烧基试料质量作为试料量(即灼烧减量测定所称量的干基试料量扣除灼烧减量的量),以四硼酸锂为熔剂,5%碘化铵溶液为脱模剂,试料与熔剂的稀释比为1:10,于1050℃熔融15 min以上制备的试料片透彻、玻璃化程度高。以白云石标准物质和标准样品作为标准试料,制作各组分的标准曲线的相关系数在0.9940~0.9994之间;方法检出限为0.011%~0.48%;标准物质和标准样品的测定值与认定值基本一致,各组分的相对标准偏差(RSD,n=11)在0.5%~1.7%之间,方法具有较好的重现性。本方法以1050℃灼烧后的试样作为试料制备XRF分析样片,最大限度地降低了灼烧减量因素(空气中的水分和CO₂)对测定结果的影响,适用于白云石及其煅烧物中钙、镁、硅、铁、铝等组分的同时测定。     

云南普朗超大型斑岩铜矿床含矿斑岩成因及其成矿意义

普朗超大型斑岩铜矿床位于三江特提斯构造域义敦弧南部的中甸弧内,形成于晚三叠世甘孜-理塘大洋板片向西俯冲的消减带上。与成矿作用密切相关的石英闪长岩和石英二长岩具有相似的化学组成,w（SiO₂）>61%,w（Al₂O₃）为11.28%~19.12%,w（MgO）为1.98%~4.04%,Na₂O/K₂O比值介于0.3~2.4（平均0.8）;富集大离子亲石元素（Rb、Sr、Ba）而亏损高场强元素（Nb、Ta、Zr）,具有较高的Sr/Y（27~63）和La/Yb（14~31）比值,较明显的负Eu异常,在Y-Sr/Y和Yb-La/Yb图解中,部分样品落入埃达克岩范围内,另一些样品则落入正常弧钙碱性岩石范围。普朗含矿斑岩部分样品的埃达克岩地球化学属性可能与以下地质-地球化学过程有关：晚三叠世甘孜-理塘大洋板片向西俯冲时发生脱挥发分作用导致上覆地幔楔遭受流体交代,被流体交代的地幔楔随后发生部分熔融形成正常拉斑玄武质-钙碱性岩浆,这种钙碱性岩浆在岩浆房中或侵位过程中发生角闪石、斜长石和磷灰石等矿物的分离结晶作用形成埃达克质石英闪长岩或石英二长岩。普朗含矿斑岩中黑云母和角闪石斑晶的广泛发育表明原始岩浆是富水的,这种富水环境促进角闪石的大量结晶而抑制部分斜长石的结晶,导致残余岩浆的Sr/Y比值增加,从而使部分岩石样品具有埃达克岩的地球化学特征。这种富水的原始岩浆有利于后期岩浆热液体系的形成及铜等金属元素向流体相中分配转移,并最终形成普朗超大型斑岩铜矿床。     

Geochemistry of mafic rocks and melt inclusions and their implications for the heat source of the 14.0°S hydrothermal field,South Mid-Atlantic Ridge

Fresh rocks sampled from the 14.0°S hydrothermal field of the South Atlantic Ridge can be divided into two categories： olivine-gabbro and basalt. The olivine-gabbro is composed mainly of three types of minerals： olivine, clinopyroxene and plagioclase, while a multitude of melt inclusions occur in the plagioclase phenocrysts of the basalts. We analyzed the whole-rock, major and trace elements contents of the basaks, the mineral chemistry of phenocrysts and melt inclusions in the basalts, and the mineral chemistry of olivine-clinopyroxene-plagioclase in the olivine-gabbro, then simulated magma evolution within the crust using the COMAGMAT program. The whole-rock geochemistry shows that all the basalts exhibit typical N-MORB characteristics. In addition, the mineral chemistry characteristics of the olivine-gabbro （low-Fo olivine, low-Mg# clinopyroxene, high-TiO2 clinopyroxene, low-An plagioclase）, show that strong magma differentiation occurred within the crust. Nevertheless, significant discrepancies between those minerals and phenocrysts in the basalts （high-Fo olivine, high-An plagioclase） reflect the heterogeneity of magma differentiation. High Mg# （-~0.72） melt inclusions isobaric partial crystallization simulations suggest that the magma differentiation occurred at the depth shallower than 13.03 km below the seafloor, and both the vertical differentiation column shows distinct discrepancies from that of a steady-state magma chamber. Instead, a series of independent magma intrusions probably occurred within the crust, and their corresponding crystallized bodies, as the primary high-temperature thermal anomalies within the off-axis crust, probably act as the heat source for the development of the 14.0°S hydrothermal system.     

西藏冈底斯南缘中新世含矿斑岩源区组成与成因

青藏高原南部中新世下地壳流动是当前大陆动力学研究的热点,关键科学问题是下地壳的流动方向。LA-ICP-MS定年结果表明冲江斑状黑云母二长花岗岩的形成时代为14.9~14.8 Ma,朱诺斑状花岗岩的形成时代为15.3~14.9 Ma。含矿埃达克质斑岩的特征如下:Si O2含量67.72%~74.49%,K2O含量2.85%~5.98%,Sr含量93~804μg/g,高Sr/Y(16~139)、(La/Yb)N(21~43)比值,Eu/Eu*值为0.6~0.91。冲江岩体锆石εHf(t)值为1.2~5.1,朱诺岩体锆石εHf(t)值为–6.9~–0.1,他们与徐旺春等报道的镁铁质麻粒岩的锆石Hf值(–2.5~4.8)具有很好的叠合性,暗示镁铁质麻粒岩(印度镁铁质下地壳)可以作为他们的岩浆源区。此外,Sr-Nd同位素表现出雅鲁藏布江蛇绿岩和拉萨地块两个端元混合的特征,Pb同位素表现出雅鲁藏布江蛇绿岩和喜马拉雅富集陆壳端元的特征。上述同位素地球化学特征表明,冈底斯中新世埃达克质斑岩的岩浆源区物质组成包括:拉萨陆壳、印度陆壳、雅鲁藏布江蛇绿岩(地幔成分),表现出加厚下地壳部分熔融特征,暗示青藏高原南部由南向北的下地壳流动方向。     

部分熔融程度计算方法简评

介绍和评述了三种计算部分熔融的方法，即批式熔融模式法（CR法）、源岩比值法（SR法）和热动力溶融反演法（DMI法），这三种计算均无须假设源岩的丰度。