Experimental Studies of the Solubility of Cassiterite and the Extraction of Tin from Granitic Melts

Experiments indicate that the solubility of cassiterite can be enhanced by increasing either acidity or alkalinity in hydrothermal solutions as a consequence of the duality of tin.The minimum solubility of cassiterite is found in neutral solutions.F-and CL-coordination compounds of Sn can alternate with hydroxyl coordination compounds with changing pH in the solutions.In this case,F^- and Cl^- and OH^- can be substituted with each other.The dissolution reaction of cassiterite is of reducing nature.High temperature and acidic reducing environment are favorable for the dissolution of cassiterite and the trans-port of Sn^2 compounds in fluids or solutions.High-temperature fluoride and chloride fluids can all dissolve,extract and enrich Sn to form F^- and /or Cl-coordination compounds,However,Fplays a more important role than Cl.F-coordination compounds are more stable and efficient than Cl-coordination compounds during the transport an enrichment of Sn in melts or solutions.The solubili-ty of cassiterite and the amount of Sn extracted from granitic melt depend not only on T,P,pH and Eh in the fluids or solutions,but also on the amounts of dissociated F^- and Cl^- in the fluids.     

徐州石炭-二叠系中首次发现一种特殊形态的地开石

徐州煤田上二叠统石千峰组地层底部粗粒石英砂岩中,发现了晶体沿a轴方向延伸的假六方板条状粘土矿物。扫描电镜观察到清晰的单体形态轮廓,片体长一般约25μm,最长达40μm,宽约4μm,长宽比为6∶1-10∶1板条状片体面对面叠置成“书册”状集合体,聚集在砂岩孔隙中。薄片光性观察、X射线衍射分析、差热分析和红外光谱分析证实为地开石。这种特殊形度的地开石是从孔隙沉淀中直接沉淀的。缓慢地结晶速度是地开石形态变化的主要原因。     

华南花岗岩型铀矿床的形成与活动大陆边缘陆壳演化的关系

我国花岗岩型铀矿床集中产出在华南陆壳成熟度较高的特定部位,其特征是:地壳厚度大(莫霍面深度大干36km);陆壳增生范围宽(1000km以上),地壳铀含量偏高,其中沉积壳层平均铀含量为5.69ppm,花岗岩的平均铀含量为10.5ppm。产铀花岗岩体的源岩物质来自地壳,是陆壳多次增生和重熔分异的产物。对花岗岩型铀矿床的物质成分、元素组合及同位素组成的研究表明,成矿物质主要来自地壳岩石,是华南地壳多次活化改造的结果。     

游离氧化铁形态转化对红粘土工程性质的影响

本文通过模拟环境中的有机质使游离氧化铁形态转化对典型红粘土工程性质的影响试验,系统地测试了游离氧化铁的形态分布与物性指标的关系。试验结果表明,在渍水条件下,游离氧化铁的形态转化对红粘土性质的影响不显著,但在渗水条件下,由于游离氧化铁的流失使得胶结作用减弱,它对红粘土工程性质的影响逐渐明显,其潜在的危害仍然是不容忽视的。     

吉林省浑江市荒沟山区花岗岩成因类型探讨

本文根据吉林省浑江市荒沟山区中生代花岗岩的岩石学、地球化学及同位素地质学研究，论述了该区花岗岩的成因类型，即老秃顶子岩体、梨树沟岩体、草山岩体均为同熔型。     

新疆喀拉通克铜镍硫化矿区二、三号矿床特征及成因

喀拉通克铜镍硫化矿区二、三号矿床的两个岩体为隐伏的中－基性岩体，受北西向断裂的控制，侵位于石炭统南明水组上段之下部地层中，为岩浆熔离型铜镍硫化矿床。矿物成分以磁黄铁矿、镍黄铁矿、黄铜矿为主。有用元素除铜、镍外，尚伴生有金、银、铂、色、钴、硫可综合利用。它国内外同类型矿床相比，具有成岩、成矿时代新，岩体基性程度低、铜大于镍等特点，因而又具有新的地质找矿意义。