再论元古界铁氧化物（Cu—U—Au—REE）矿床之热液成因

元古界铁氧化物Ｃｕ－Ｕ－Ａｕ－ＲＥＥ矿床的构造背景和矿物成分的多变性以及独特的形成深度，导致对其成因模式有不同的认识。本文研究表明，属该矿床类型的南澳大利亚ＥｍｍｉｅＢｌｕｆｆ铁氧化物矿床明显为热液成因，宏观、微观上均表面出叠加关系。其形成主要分两阶段，第一阶段形成富磁铁矿矿石，与源于中元古化长英质主要侵入事件的高温流体有关，随后的富赤铁矿矿化则与低温流体有关。全岩稳定同位素分析结果支持这一观点。     

含金热液隐爆角砾岩的特征及研究意义

含金热液隐爆角砾岩可划分为岩浆热液隐爆角砾岩、岩浆－天水混合热液隐爆角砾岩和天水热液隐爆角砾岩。隐爆角砾岩最重要的特征为：形似厚板状、筒状，角砾岩中含有大量岩粉，矿物的快速沉淀。热液体系的减压扩容、流体的沸腾和去气（ＣＯ２）作用引起了隐爆角砾岩化。金常富集在隐爆中心附近。对隐爆角砾岩的研究将有助于判断金矿体的剥蚀程度、矿头和矿尾的位置，有助于布置勘探工程，有助于对金沉淀机制的研究和深部预测。     

混合岩化作用中交代岩和铁矿形成的实验研究

通过黑龙江西麻山、天宝山和河南桐柏山混合岩化交代铁矿床的野外地质工作,并进行了高温高压下系统的模拟实验。实验结果证明了在380～650℃的温度和300×10~5～700×10~5Pa的压力下,含K、Na卤化物的弱酸性混合岩化的热液,与太古代的变质岩经历了120个小时的持续交代作用,形成了与这些矿区基本相一致的交代岩和铁矿,揭示了混合岩化作用中形成了交代岩和铁矿的物理化学条件。     

独山锑矿稳定同位素地球化学研究

通过氧、硫、氢、碳、铅等稳定同位素和矿物包裹体地球化学的研究;指出独山锑矿成矿温度低(1OO～200℃).成矿流体主要为大气降水,成矿物质主要来自地层;成矿作用以构造裂隙充填型为主;系大气降水低温热液型矿床.该类矿化是地洼区构造活化成矿的一种典型成因类型.     

地球化学异常的运移和动力学分散—特罗多斯蛇绿岩中的热液运移

塞浦路斯特罗多斯蛇绿岩的~(87)Sr/~(86)Sr分析限制了流体-固体交换作用和由时间积分的流体流量,剖面上部约1km(包括枕状熔岩和最上部的席状岩墙)的~(87)Sr/~(86)Sr值介于特罗多斯新鲜火山玻璃(约0.7035)与白垩纪海水(约0.7075)之间。然而,下伏席状岩墙和最上部的深成岩体岩石的~(87)Sr/~(86)Sr比值分布范围相当窄(约0.7052 2σ),这些岩石包括一直被认为流体集中上涌带的石英绿泥石岩和绿帘岩。     

阿尔泰高山区金矿带的确定和意义

根据地质、地球化学和资源总量预测等方法的综合研究表明,在阿尔泰高山区红山咀断裂以北宽20～30km,东西长约150km地带为一重要金成矿带。金矿赋存于晚古生代陆相酸—中酸性火山岩地层中,空间上受冰长石-黄铁绢英岩化蚀变带严格控制,是以毒砂、辉锑矿等金属硫化物为主要载体的层控浅成低温热液溶滤型金矿,也是一种新的重要的金矿工业类型。     

Rare-earth element mobility during ore-forming hydrothermal alteration: A case study of Dongping gold deposit Hebei Province,China

REE mobility during hydrothermal ore-forming processes has been extensively investigated in recent years and the potential of REE to provide information about ore forming processes has commonly been recognized.The Dongping gold deposit,which is located in northwestern Hebei Province,China,occurring in the inner contact zone of the Shuiquangou syenite complex,is spatially,and probably genetically,related to the syenite,the deposit was formed under the moderate to high temperature(220℃ to 320℃),weakly acidic to weakly alkaline,rather high fo2(lgfo2=-30～-34)environment.The REE study of the host rocks,altered wall rocks,ores and gangue minerals from the deposit suggests that the REEs have been mobilized and differentiated during K-feldspathization and silicification.The extremely altered syenite enveloping auriferous quartz vein shows positive Ce anomaly and larger LREE/HREE ratio than that of the unaltered syenite.The REE concentrations and patterns of the ores are determined by the ore types and mineral assemblages,LREE/HREE ratios in the gangue quartz and hydrothermal Kfeldspars are relatively low.The most significant observation is that the gangue quartz shows significant positive Eu anomaly,whereas the hydrothermal K-feldspars show less significant or no positive Eu anomaly at all relative to the primary feldspar in the unaltered syenite. It is evident that the REEs are mobile during K-feldspathization and silicification in the ore forming process.Weak to moderate K-feldspathization caused REE mobility without apparent differentiation with the exception of extreme K-feldspathization and silicification which resulted in significant depletion of HREE and Eu and relative enrichment of Ce.The REE,Y,U,Th and Au contents of the syenite decrease as the degrees of K-feldspathization and silicification of the rocks increase towards the auriferous quartz veins.As the ores were deposited under a rather oxidized environment,Ce^4 predominated over Ce^3 .The precipitation of the former in the form of CeO2 or absorpted onto the secondary mineral assemblage resulted in the inconsistent removal of the REE and the relative Ce enrichment in the strongly altered rocks.in contrast,Eu was present mainly in a low valence state (Eu^2 ).The geochemical differences from the other REE^3 and much less sites in the secondary minerals to accommodate the Eu released form the original minerals resulted in the enrichment of Eu in the fluids.The mobility and differentiation of REE and the coherent mobilities of Y,U,Th and Au also support the argument that the syenite is one of the source rocks for gold mineralization.The REE contents and patterns of the altered rocks enveloping the auriferous quartz vein could be used as a guide for locating ore veins in mineral exploration.     

山西义兴寨金矿床金矿物颗粒的产出及其成矿动力学意义

山西义兴寨金矿床的金主要呈包体金和裂隙金两种产出状态.文章根据成矿地球化学动力学理论,论证了金元素在含矿断裂发生脆性破裂和脆-韧性扩张活动中析出的化学反应类型,以及受反应动力学条件的制约,形成矿石中金不同产出状态的规律.指出热液矿床中普遍存在的包体金为热液成矿早期阶段断裂发生脆性破裂和成矿流体沸腾,导致快速反应结晶的产物;而裂隙金和晶隙金为成矿晚期金等矿质在流体中残余富集,同时成矿断裂再次发生脉动破裂,即成矿热力学演化与有利的构造动力学因素耦合作用的结果.得出金矿物颗粒的产出状态具有成矿动力学意义的结论.