气体水合物中大量甲烷释放引起大气圈组分、放射压力和气候的改变

陆坡上水合物矿床中甲烷(CH4)的灾难性释放已显著干扰了古新世／始新世温度最高(PETM)期(约55．5Ma)的全球气候和碳循环。我们调查了所有PETM期古温度和古二氧化碳替代矿物是否与假设考虑大量增加的甲烷散发到大气圈的影响相一致。     

融冰季节北极破碎冰区热通量的初步研究

利用航空遥感数字影像的解析结果和实测气象，海洋和海冰资料，定量研究了夏季融冰期北极破碎冰区的热通量，计算了海洋对大气的热贡献，结果表明，在北极夏季海冰融化时，短波辐射远远大于感热和潜热通量，是表面热通量的决定因素，海洋对大气的热贡献主要由长波辐射决定，在观测期间，海洋对大气的热贡献为38～104Wm^-2，这部分热量的大小与海冰的密集度有关，当海冰密集度小于0.8时，海洋对大气的热贡献随海冰密度度的增大而减小，而当海冰密集度超过0.8以后，该热通量将随海冰密集度的增大而增大。     

Bottom Simulating Reflector and Gas Seepage in Okinawa Trough： Evidence of Gas Hydrate in an Active Back-Arc Basin

To look for gas hydrate, 22 multi-channel and 3 single-channel seismic lines on the East China Sea (ECS) shelf slope and at the bottom of the Okinawa Trough were examined. It was found that there was indeed bottom simulating reflector (BSR) occurrence, but it is very rare. Besides several BSRs, a gas seepage was also found. As shown by the data, both the BSR and gas seepage are all related with local geological structures, such as mud diapir, anticline, and fault-controlled graben-like structure. However, similar structural "anomalies" are quite common in the tectonically very active Okinawa Trough region, but very few of them have developed BSR or gas seepage. The article points out that the main reason is probably the low concentration of organic carbon of the sediment in this area. It was speculated that the rare occurrence of gas hydrates in this region is governed by structure-controlled fluid flow. Numerous faults and fractures form a network of high-permeability channels in the sediment and highly fractured igneous basement to allow fluid circulation and ventilation. Fluid flow in this tectonic environment is driven primarily by thermal buoyancy and takes place on a wide range of spatial scales. The fluid flow may play two roles to facilitate hydrate formation:to help gather enough methane into a small area and to modulate the thermal regime.     

Main Controlling Factors on Hydrocarbon Accumulation and Distribution in Marine Sedimentary Sequences in South China

Multiple source rock assemblages were deposited in the sedimentary provinces in South China in geologic history,and some of them were destructed by and some survived against multiple tectonic movements.Therefore,multiple sources,mixed sources,and uneven distribution of sources occurred in the marine sedimentary basins in South China during the late stage of hydrocarbon pooling.Epidiagenesis of the marine carbonate reservoirs and its modification to reservoir poroperm characteristics determined the formation and the scale of natural gas pools.The exploration practices show that the large to medium gas fields mainly occur in areas with high-quality reservoirs.Detailed study of the paleo-oil accumulations and typical oil and gas reservoirs reveals that the basins experienced multiphase superimposition and modification,leading to the distribution of the Paleozoic paleo-oil accumulations and bitumen in the peripheral areas.The phenomenon that oil and gas production concentrates in the Sichuan basin indicates that the overall sealing conditions of a basin determine the oil/gas potentials and the scale of oil and gas production.This is a critical factor controlling the accumulation and distribution of gas in the marine sequences in South China.The early oil and gas pools in the Yangtze platform left billions of bitumen in the peripheral areas due to the destruction of seals.Since the Himalayan,"late-generation and late-accumulation" gas pools represented by the gas pools in the Sichuan (四川) basin were formed in the marine sedimentary sequences in South China as a result of the change of the sealing conditions.Current gas discoveries appear to be "paleo-generation and paleo-accumulation" gas pools but actually are "late-generation and late-accumulation" gas pools.These patterns of hydrocarbon pooling clearly depict themselves in western Sichuan basin and Weiyuan (威远)gas field.It is revealed that the gas pools in the Sichuan basin were mainly formed as a result of hydrocarbon phase change (thermal cracking of oil to gas),miscible migration,and dynamic equilibration since the Himalayan.A large number of gas pools were formed in the Himalayan and the gas pools in the marine sequences are characterized by late pooling; this kind of gas fields/pools are controlled by:(1) effectiveness of modification and superimposition of the marine basins,(2) effectiveness of the source rocks,(3) effectiveness of the overall preservation conditions,and (4) effectiveness of plays.     

拉拉铜矿黄铁矿微量元素地球化学特征及其成因意义

四川会理拉拉铜矿床是我国著名大型富铜矿床,针对该矿床中黄铁矿的微量元素、稀土元素地球化学分析表明:拉拉铜矿经历了早期火山喷发成岩成矿和晚期变质成岩成矿作用.条带状矿石中的黄铁矿Co/Ni比值集中于4.92～79.2之间,落入火山成因黄铁矿区,稀土元素分布具有Eu正异常和轻稀土富集的特征,反映矿床具有伴随河口群火山喷流沉积成岩过程的同生沉积成矿作用.脉状矿石中的黄铁矿Co/Ni比值集中于1.10～3.45,落在热液成因黄铁矿区,稀土元素较河口群岩石及其他典型块状硫化物矿床矿石稀土元素更加富集轻稀土元素,稀土含量变化范围更大,显著的负Eu异常,则又说明,矿床形成的主要成矿作用是伴随新元古代晋宁运动而发生的大规模的变质作用.     

鄂尔多斯盆地合水地区长8储层特低渗透成因分析与评价

鄂尔多斯盆地合水地区长8储层的物性总体较差,发育粒间孔、溶孔,孔隙结构类型属小孔隙、微细喉道和微喉道型;分析表明其特低渗透成因主要受沉积作用和成岩作用的共同影响,不同沉积微相储层的物性差异较大,柔性组分含量高、粒度细和成分成熟度较低是造成储层特低渗透特征的主要原因;同时成岩压实、胶结作用使得储层的孔隙度减小、渗透性变差,而溶蚀作用和少量成岩微裂缝的产生又在很大程度上改善了储层的特低渗透性能;水下分流河道与河口坝砂体是研究区主要储层的分布相带.     

华北地台中元古代碳酸盐岩中的微生物成因构造及其生烃潜力

华北地台中元古界主要由环潮坪石英砂岩、浅海碳酸盐岩和浅海—泻湖相暗色页岩3种沉积相组合构成,以陆表海浅水碳酸盐岩占主导。碳酸盐岩中除含有丰富的微古植物、宏观藻类和微生物建隆外,还发育大量的微生物成因构造(MISS)和微生物诱发的碳酸盐沉淀(MMCP)。微生物席和MISS构造在高于庄组上部(约1.6 Ga)和雾迷山组下部(约1.45 Ga)碳酸盐岩中尤为发育,表明活跃的微生物活动和高有机质产量。在石化微生物席中,发现有丝状、球状细菌化石和草莓状黄铁矿;围岩中发现有针状文石、花瓣状重晶石、放射状菱铁矿、铁白云石和葡萄状碳酸盐胶结物等多种自生碳酸盐矿物,指示甲烷厌氧氧化(AOM)导致的自生碳酸盐沉淀。中元古代的温暖气候和海洋分层、缺氧、硫化条件有利于微生物的高生产量和高有机质埋藏率。气隆构造和核形石状碳酸盐结核反映浅埋藏条件下活跃的成烷作用和甲烷排放,围岩和MMCP中富沥青质。华北地台中元古界富微生物席碳酸盐岩有良好的生烃潜力,有可能形成重要的烃源岩。据微生物席、MISS构造及MMCP的研究,初步估算华北地台中元古代碳酸盐岩的概略生烃潜力约为10×108t石油当量。     

鄂尔多斯地块早白垩世构造-热事件:杭锦旗玄武岩的Ar-Ar年代学证据

在鄂尔多斯地块北部杭锦旗黑石头沟,于下白垩统砂岩之上发现了一层玄武岩。其SiO2(46.93%)较低而碱含量(K2O+Na2O=6.21%)较高,组合指数σ=8.0,含标准矿物Ne,属于碱性橄榄玄武岩。Ar-Ar激光阶段加热定年结果表明,该玄武岩具有126.2±0.4Ma的Ar-Ar年龄。年龄数据表明杭锦旗黑石头沟玄武岩形成于早白垩世,反映鄂尔多斯地块在早白垩世发生了一次构造-岩浆-热事件,这与华北、乃至整个中国东部在早白垩世发生了较普遍的构造-岩浆-热事件具有一致性。这次构造-岩浆-热事件可能引起深部流体自地下深部上涌及在地块内部运移,为各种成矿元素的迁移、沉淀、富集和成矿创造了合适条件。