壳聚糖/蒙脱土插层复合物对活性红染料的吸附热力学研究

采用溶液插层法,利用壳聚糖和蒙脱土制备了壳聚糖/蒙脱土插层复合物,使用红外光谱和X-射线衍射分析对其结构进行了表征;以此复合物为活性红染料RR136的吸附剂,考察了复合物中壳聚糖与蒙脱土的摩尔比、染料溶液pH值和浓度、吸附温度及吸附剂用量等因素对吸附性能的影响。结果表明,吸附反应的最佳条件是以壳聚糖与蒙脱土摩尔比为5∶1的插层复合物为吸附剂,反应温度20℃,RR136溶液pH为3。壳聚糖/蒙脱土插层复合物对活性红染料的吸附更符合Langmuir模型,吸附热力学参数ΔGo、ΔHo和ΔSo值分别为-3.338kJ·mol-1(30℃),-37.98kJ·mol-1和-114.77J·mol-1·K-1,表明壳聚糖/蒙脱土插层复合物对活性红染料的吸附是自发的、以物理吸附为主的放热反应。     

水氯镁石脱水反应的热力学计算

水氯镁石脱水制备无水氯化镁是一个多反应的复杂过程,文中对水氯镁石脱水制备无水氯化镁过程中可能存在的化学反应的热力学各函数进行了计算,对脱水反应机理进行探讨,并为生产提供理论依据     

铈异常及海水中铈的热力学

海相碳酸盐岩的铈异常可作为古海洋水氧化还原条件的一种指示剂。安哥拉海盐和巴西海盆(南大西洋)底部洋水在白垩纪时是还原环境,大约在54～58MaBP时,南大西洋变为类似于现在海水的氧化还原环境。本文提出了一个新的比较完善的铈氧化还原热力学公式,解释了长期悬而未决的海水和河水中铈地球化学异常的问题,如大西洋表层海水为何具有铈正异常等。查明于54～58MaBP非洲板块和南美板块彻底分离,统一的南、北大西洋开始形成。论证了阿尔卑斯运动和喜马拉雅运动是同步的。     

大气热力学的若干新发展

对自20世纪80年代以来的大气热力学发展进行了综合评述, 阐述了如城市热岛效应、全球增暖等非传统大气热力学问题; 基于大气非平衡态热力学的非线性理论, 提出应发展突显热力学作用的数值模式, 并阐述其必要性和可能性。     

海冰对北极海冰边缘区大洋光学观测的影响评估

Diffuse attenuation coefficient(DAC) of sea water is an important parameter in ocean thermodynamics and biology, reflecting the absorption capability of sea water in different layers. In the Arctic Ocean, however, sea ice affects the radiance/irradiance measurements of upper ocean, which results in obvious errors in the DAC calculation. To better understand the impacts of sea ice on the ocean optics observations, a series of in situ experiments were carried out in the summer of 2009 in the southern Beaufort Sea. Observational results show that the profiles of spectral diffuse attenuation coefficients of seawater near ice cover within upper surface of 50 m were not contaminated by the sea ice with a solar zenith angle of 55°, relative azimuth angle of 110°≤φ≤115° and horizontal distance between the sensors and ice edge of greater than 25 m. Based on geometric optics theory, the impact of ice cover could be avoided by adjusting the relative solar azimuth angle in a particular distance between the instrument and ice. Under an overcast sky, ice cover being 25 m away from sensors did not affect the profiles of spectral DACs within the upper 50 m either. Moreover, reliable spectral DACs of seawater could be obtained with sensors completely covered by sea ice.     

Corrections to Solar Thermal Structure when a Turbulent Magnetic Field is Included

Correction of non-ideal effect due to a magnetic fluctuating tensor is derived from the ideal MHD equations. The inclusion of a magnetic turbulent field leads to modifications of the hydrostatic equilibrium equation and thermodynamical variables such as the temperature T, the adiabatic exponent γ, the adiabatic temperature gradient △↓ad and the temperature gradient △↓. In particular, the modifications in the adiabatic and radiative temperature gradients will result in a change in the Schwarzchild criterion, hence in the location of the base of the convective zone. Incorporating the modifications, we construct a modified thermodynamical equilibrium structure of the Sun.     

湍流压对中小质量恒星后期演化的影响：（Ⅰ）湍流压,物态方程及热…

本以恒星结构演化理论中常用的混合程对流理论为基础，给出了湍流压以及考虑湍流压情况下恒星内部物态方程和各热力学量的表达式。在此基础上研究了质量为２．８Ｍ和７Ｍ的恒星由主序演化到红巨星和ＡＧＢ星阶段其湍流压的大小。结果证明，在红巨星和ＡＧＢ阶段，靠近恒星表面区域内湍流压可以达到总压强的３０％。     

梅山铁矿形成物理化学条件的热力学分析

Using thermodynamic data, the authors have calculated the equilibrium constants (at high temperatures and pressures) for 47 reactions among 18 kinds of minerals present in the Meishan iron deposit, and constructed equilibrium diagrams of the mineral paragenesis.On this basis, they have discussed the physicochemical conditions of formation of the depo.sit and the relations between mineralization and wall-rock alteration.