SHRIMP Ion Microprobe Zircon U—Pb Age and Sm—Nd Isotopic Characteristics oof the NE Jiangxi Ophiolite and Its Tectonic Implications

The new SHRIMP zircon U-Pb isotopic study suggests that the crystallization age of a highly fractionated magma in the NE Jiangxi ophiolite suite is 968±23 Ma. Re-calculated Sm-Nd isochron age of 955±44 Ma is within analytical errors. consistent with the zircon U-Pb age. With the exception of two anomalous Sm-Nd data, the remaining 15 analyses so far obtained for the ophiolite gave^εNd (T) values falling into a limited range from +4.3 to +6.7, indicating that the ophiolite was derived from a relatively strongly depleted mantle source. Sm-Nd isotopic systematics in some samples may have been strongly affected by post-magmatic events, such as alteration, deformation and metamorphism, resulting in anomalous^εNd (T) values. Combined with published⁴⁰Ar³⁹Ar age data, it can be concluded that the collision between the Yangtze and South China Blocks occurred during 0.97-0.80 Ga. This work was financially supported by the President Grant of the Chinese Academy of Sciences.     

Partitioning and Hydrolysis of Nb and Ta and Their Implications with Regard to Mineralization

K₂NbOF₅ · H₂O and K₂TaF₇ were prepared through melting Nb₂O₅ and Ta₂O₅ respectively with KHF₂ · 2H₂O, followed by recrystallizing. The hydrolysis properties of K₂NbOF₅ and K₂TaF₇ were determined again by using a rapidly quench vessel. As temperature (from 250 to 550 °C) and pressure (from 500 to 1500 bars) increase, the degree of hydrolysis of both K₂NbOF₅ and K₂TaF₇ will increase. Nb- and Ta-fluorine complex compounds are instable in supercritical aqueous fluids. The degree of hydrolysis of both K₂NbOF₅ and K₂TaF₇ decreases with increasing concentration of HF, independent of the concentration of NaF. The partition coefficients of Nb and Ta between granitic melt and fluid phase are less than 0.15, i.e., most of Nb and Ta are left in granitic melt. The partition coefficient of Ta is more dependent on the concentration of HF than that of Nb. The significance of hydrolysis in Nb- and Ta- mineralization is also discussed in the present paper.     

山东沂水杂岩中变基性岩类的Sm—Nd同位素年龄及其地质意义

在山东太古宙沂水杂岩的变基性岩类中首次获得的Sm-Nd全岩等时线同位素年龄为2997Ma,证实了山东中部的郯庐断裂带中有中太古代麻粒岩相表壳岩存在。沂水杂岩的岩石组合主要有二辉斜长麻粒岩、二辉斜长片麻岩、二辉铁英岩(少量)、二辉斜长角闪岩和紫苏花岗岩类等,它们组成了山东最老的汞丹山地块,其时代大致相当于胶东群,但层位可能更为偏下。沂水杂岩为高角闪岩相至麻粒岩相。变基性岩的原岩相当低钾拉斑玄武岩,稀土配分具有较平坦型和轻稀土富集型两种模式。岩石的ε_(Nd)(t)值为+3.8±0.3,物源来自亏损(上)地幔。它与华北陆台北缘麻粒岩相中部分岩石的岩性十分相似,表明其源区的化学特征相似,但主体的稀土模式有所不同,说明太古宙不同地区相似岩石地球化学的不均匀性。     

九嶷山-铜山岭-都庞岭花岗岩带低钕模式年龄的成因探讨

九嶷山、都庞岭复式岩体分别由志留纪、中三叠世、中一晚侏罗世和志留纪、晚三叠世、中侏罗世花岗岩组成，源岩主要为壳源物质，钕模式年龄值由早至晚顺序降低，并与花岗岩的酸碱度呈负相关。最晚期的晚侏罗世金鸡岭岩体t2DM值仅1480～1410Ma，年龄偏低的原因可能是花岗岩浆源岩有部分来自相对较浅、时代较新的地壳和复式岩体区已固结成岩的早时代花岗岩。中三叠世的铜山岭岩体基性程度高，属壳幔同熔型成因，钕模式年龄1480～1380Ma，低钕模式年龄值的成因和幔源物质的加入有关。     

西南极利文斯顿岛火山岩多种成因过程的地球化学证据

利文斯顿岛火山岩是南极南设得兰岩浆弧的一部分。对岩石的Ｓｒ，Ｎｄ，Ｐｂ同位素组成以及＾８７Ｓｒ／＾８６Ｓｒ与１／Ｓｒ，Ｒｂ，Ｋ和ＳｉＯ２关系的研究表明，利文斯顿岛火山岩具有不同的源区特征。百耳斯半岛和史莱夫角的火山岩，西多斯角的粗玄岩和第三纪的岩云闪长岩显示出同成因的特点、和依诺特角第四纪橄榄玄武岩一样，它们均具有原生地幔的同位素组分，源区岩浆可能直接来自上地幔。     

Geochronology of and Nd—Sr—Pb Isotopic Evidence for Mantle Source in the Ancient Subduction Zone beneath Sanshui Basin,Guangdong Province,China

The available petrochemical data indicate that volcanic rocks in the Sanshui basin of Guangdong Prov-ince are characteristic of the island-arc tholeiite-calc-alkaline series.Their K-Ar ages range from 43 to 64 Ma,corresponding to Early Tertiary.The Nd-Sr-Pb isotopic correlations give two binary mixing trends,indicating a mixed source of Leiqiong depleted mantle,seawater and altered sediments pertaining to subduction.Our studies have confirmed the existence of an ancient subduction zone beneath the South Chi-na continent,which is considered to have resulted from the suturing of various terrains in southern China.     

利用选择性特效树脂富集分离岩石样品中的锶钐和钕

使用目前国际上几种常用的特效树脂:锶树脂(SR)、稀土树脂(RE)和镧系树脂(LN)对岩石样品中Sr、Sm和Nd的分离富集效果进行了试验,结果表明,按厂家提供的流程,SR树脂可回收98%左右的Sr,而且残余的Rb不到2%;RE树脂回收的Sm和Nd只有70%左右;而联合利用RE和LN树脂,并配合SR树脂的使用,可以将Sm和Nd的回收率提高到90%左右;LN树脂可以很好地分离Sm和Nd,并且回收的Nd可占总样量的85%左右.     

饮水氟化安全性与有效性的争论

关于饮水氟化在学术界存在着两个对立的观点，一是支持，一是反对。支持饮水氟化者认为它不仅可有效的减少龋齿的发病率，还是最经济的预防龋齿的措施，适当地实施这一措施不会产生氟斑牙等氟中毒现象；反对饮水氟化者认为人体氟来源是多样的，过量氟对人体具有毒性，饮水氟化具有氟中毒的潜在危险。国内外大量的研究与观察已经证明，存在着一个既不造成氟斑牙流行又最大限度地发挥氟的防龋作用的饮水氟浓度。由于人种、地域、气候和饮食生活习惯的不同，在不同地区不同季节的饮用水氟含量应不同。目前，全国性的饮水氟含量与居民口腔健康的相关性的研究还基本处于空白阶段。因此在全国范围内进行这方面的研究是我国各城市饮水氟化防龋研究的基础。