辽东中生代晚期和古近纪玄武岩及深源捕虏晶--对岩石圈地幔性质的制约

辽东地区玄武岩的K-Ar定年结果表明,曲家屯玄武岩形成于晚白垩世,K-Ar年龄为81．58±2．46Ma;乱石山子玄武岩形成于古近纪,K-Ar年龄为58．36±1．64Ma。本区玄武岩含有丰富的橄榄石、单斜辉石和角闪石捕虏晶。乱石山子玄武岩中橄榄石捕虏晶的Mg^#值（79．5-88．5之间,平均值为84）较曲家屯玄武岩中橄榄石捕虏晶Mg^#值（77．0～79．8之间,平均值为78．4）偏高;单斜辉石捕虏晶为透辉石,其从核部到边部的Mg^#等变化趋势与橄榄石类似;斜方辉石捕虏晶为占铜辉石,其Mg^#值介于85．2-87．6之间,平均值为86．4。捕虏晶发育的环状裂隙、扭折带、矿物成分环带以及捕虏晶与主岩Mg^#值之间的不平衡均暗示它们为玄武质岩浆上升捕获的早期岩浆晶出矿物的堆晶体。玄武岩的岩石地球化学分析结果表明：（1）它们属于碱性系列,为碱性玄武岩,曲家屯玄武岩较乱石山子玄武岩贫硅、镁,富钙、铝,它们均具有原始岩浆的特征;（2）二者具有相似的稀土元素配分模式,但曲家屯玄武岩轻稀土元素总量更高,且轻重稀土元素分离程度高;（3）二者具有相似的Sr-Nd同位素组成,Isr和εNd（t）值分别介于0．7039～0．7045和＋1．60～＋3．69,反映了亏损的岩石圈地幔特征。     

东秦岭造山带"两阶段双带"区域成矿模式

东秦岭造山带总体上可划分为中元古代-古生代主要与裂谷、坳陷槽有关的海盆同生沉积成矿以及中生代与大规模陆内俯冲造山体制有关的后生热液成矿两大阶段,且中生代所形成的浅成和中深成两类热液矿床在横向上分带并呈相邻平行展布,成对共生,构成双成矿带,其形成机制是扬子地块及华北地块分别往秦岭发生陆内俯冲,使与挤压、转换挤压-变质变形、深成侵入-深源流体成矿系统有关的中深成热液型矿床形成于仰冲板片前缘的推覆-隆升带中;而使与伸展-高地热场(火山、浅成侵入)-地热流体成矿系统有关的浅成热液型矿床形成于推覆-隆升带后侧的同碰撞伸展带中.     

玄武岩中普通辉石,石榴石巨晶的研究：Ⅰ.REE演化

辽宁宽甸、河北汉诺坝和福建明溪碱性玄武岩中的普通辉石和石榴石巨晶MgO、FeO、CaO含量的变化呈现了矿物的结晶分异趋势。从高温到低温晶出辉石的REE分馏程度不断增高,石榴石REE分馏程度不断降低,即两种巨晶中的LREE不断增加,而HREE逐渐减少,矿物的稀土模式曲线出现交叉现象。 用宽甸和汉诺坝任一层玄武岩作为液相与巨晶所计算的REE分配系数D_(矿物)~(REE)-玄武岩值,均与实验值相近,因而它不能旁证载体玄武岩就是巨晶的母岩浆。辉石晶出后残余岩浆比例Ⅰ值计算表明,母岩浆体可能是一个相对体积不太大的、主元素和REE成分不断变化的相对独立的地质体。     

五大连池等地钾质碱性玄武岩、幔源包体的微量元素特征及成因信息

黑龙江省五大连池、科洛、二克山火山岩的成因,是一个重要而又复杂的问题.作者根据岩相学、地球化学、模式计算等一系列工作,认为这组钾质玄武岩是含金云母的尖晶石二辉橄榄岩低度局部熔融的产物。岩浆在上升过程中,经历了结晶分异和同化混染,从而形成一套具成因联系的新生代大陆板内钾质碱性玄武岩。本文试从微量元素方面对此结论提供证据,并显示钾质熔岩及幔源包体的微量元素特征,由此说明地幔交代作用在钾质系列岩浆形成过程中的重要性。     

内官—香泉盆地地下水资源及其开发利用状况探讨

在计算内官-香泉盆地地下水资源量以及多年地下水超采量的基础上,进一步推算了盆地年均地下水超采系数和年均泉水流量衰减率,从理论上证明内官-香泉盆地是中型地下水严重超采区,盆地地下水超采量的年际变化呈明显递增趋势。由于长期持续、过量开采地下水,导致本区域环境地质灾害日趋严重。     

藏北双湖山字形山玄武岩锆石U-Pb年龄、地球化学特征及其地质意义

次对藏北双湖山字形山玄武岩进行了同位素年代学和岩石地球化学研究。锆石LA ICP MS U Pb测年结果表明,玄武岩形成时代为中三叠世Ladinian期((2358±27) Ma)。主量元素SiO2质量分数为4284%~5222%,TiO2为161%~269%,FeOT/MgO为152~194,属亚碱性系列拉斑玄武岩。稀土元素∑REE含量为11409×10-6~20847×10-6,(La/Yb)N为490~650,相对富集LREE。微量元素配分模式曲线与OIB型玄武岩相似。岩石成因研究表明岩浆在演化过程中主要受分离结晶作用控制,La/Nb、La/Ta、Zr/Ba等不相容元素比值与Ti含量表明,山字形山玄武岩可能是软流圈地幔与岩石圈地幔相互作用的产物。玄武岩较高的Zr含量与Zr/Y比值显示其处于板内伸展构造背景。结合区域地质资料推测,中三叠世玄武质岩浆是南、北羌塘地块碰撞造山过程中板片断离、软流圈物质上涌熔融的产物,而晚三叠世偏铝质-过铝质岩浆岩及高压变质岩折返剥露为造山带垮塌引起的伸展作用的结果。     

玄武岩及其有关的非金属矿床

玄武岩及其有关的非金属矿床是重要的矿床系列之一,玄武岩本身就是有用的非金属矿产,与其有关的非金属矿产有宝玉石、硅藻土、坡缕石粘土等.根据成矿作用分为五种成因类型.本文系统总结了玄武岩及其有关的非金属矿床的特点.     

阿尔泰南缘中泥盆统北塔山组火山岩的矿物学研究

阿尔泰山南缘中泥盆统北塔山组火山岩极为发育。本文对富辉橄玄岩和玄武岩中的单斜辉石和橄榄石斑晶进行了矿物化学分析,并结合矿物的地质温压计和岩浆结晶模拟,约束了两种岩石中矿物的形成过程,推测了原始岩浆的演化过程。提出富辉橄玄岩和玄武岩的原始岩浆属于拉斑玄武系列,富辉橄玄岩中的高压单斜辉石来源于深部（40～50 km）,其结晶早于橄榄石;玄武岩中单斜辉石大多属于岩浆房结晶产物（30～40km）,其结晶晚于橄榄石;两种岩石中橄榄石均属于岩浆房结晶产物（30～40 km）。     

Trace Element Geochemistry of Tertiary Continental Alkali Basalts from the Liuhe—Yizheng Area,Jiangsu Province,China

Reported in this paper are the chemical compositions and trace element (REE,Ba,Rb,Sr,Nb,Zr,Ni,Cr,V,Ga,Y,Sc,Zn,Cu,etc)abundances of Tertiary continental alkali basalts from the Liube-yizheng area,Jiangsu Province,China.The olivine basalt,alkali olivine basalt and basanite are all derived from evolved melts which were once af-fected by different degrees of fractional crystallization of olivine and clinopyroxene(1:2)under high pres-sures.The initial melts were derived from the garnet lherzolite-type mantle source through low-degree par-tial melting.The mantle source has been affected by recent mantle-enrichment events(e.g.mantle metasomatism),resulting in incompatible trace element enrichment and long-term depletion of radiogenic isotopic compositions of Sr and Nd.     

Interactions between basalts and oil source rocks in rift basins： CO2 generation

Basalts interbedded with oil source rocks are discovered frequently in rift basins of eastern China, where CO2 is found in reservoirs around or within basalts, for example in the Binnan reservoir of the Dongying Depression. In the reservoirs, CO2 with heavy carbon isotopic composition (δ13C>-10‰ PDB) is in most cases accounts for 40% of the total gas reserve, and is believed to have resulted from degassing of basaltic magma from the mantle. In their investigations of the Binnan reservoir, the authors suggested that the CO2 would result from interactions between the source rocks and basalts. As the source rocks around basalts are rich in carbonate minerals, volcanic minerals, transition metals and organic matter, during their burial history some of the transition metals were catalyzed on the thermal degradation of organic matter into hydrocarbons and on the decomposition of carbonate minerals into CO2, which was reproduced in thermal simulations of the source rocks with the transition metals (Ni and Co). This kind of CO2 accounts for 55%-85% of the total gas reserve generated in the process of thermal simulation, and its δ13C values range from -11‰- -7.2‰ PDB, which are very similar to those of CO2 found in the Binnan reservoir. The co-generation of CO2 and hydrocarbon gases makes it possible their accumulation together in one trap. In other words, if the CO2 resulted directly from degassing of basaltic magma or was derived from the mantle, it could not be accumulated with hydrocarbon gases because it came into the basin much earlier than hydrocarbon generation and much earlier than trap formation. Therefore, the source rocks around basalts generated hydrocarbons and CO2 simultaneously through catalysis of Co and Ni transition metals, which is useful for the explanation of co-accumulation of hydrocarbon gases and CO2 in rift basins in eastern China.