象山港潮滩沉积物有机质分布特征及物源影响分析

潮滩是陆海交互影响的重要区域,在陆海物质交换的过程中扮演着重要的角色.象山港位于浙江宁波,是典型的半封闭式港湾,受人类活动影响显著.本文取其重要支港西沪港为研究区,自其潮上带至潮间带采集表层沉积样品,进行总有机碳(Total Organic Carbon,TOC)、总氮(Total Nitrogen,TN)和稳定碳同位...     

广西土壤有机质空间变异特征及其影响因素研究

基于广西第二次土壤普查的270个土壤剖面资料,结合1∶50万数字化土壤类型图、土地利用类型图和气象监测数据等资料,利用地统计学和逐步回归分析等方法对广西表层土壤有机质空间变异特征及其影响因素进行了探究。结果表明：广西表层土壤有机质平均含量为3.11±2.19%,变异系数为70.72%,空间分布呈北高南低的趋势。广西表层土壤有机质空间分布受到自然和人为因素的共同影响,土壤类型、成土母质、海拔、土地利用、气候和坡度6个环境因子对全区土壤有机质含量变异的综合解释能力为47.9%。其中,土壤类型是最重要的影响因素,能独立解释其变异的36.0%,海拔和成土母质分别能独立解释28.5%和15.8%。气温对广西土壤有机质空间分布的影响比降水量更加显著,从而造成了广西土壤有机质整体呈南低北高的趋势。同时,土壤有机质对气温的敏感性在一定程度上受到降雨量的制约。此外,研究区农业耕作管理等因素对土壤有机质的影响也不容忽视。     

1980—2015年风蚀影响下中国北方土壤有机质与养分流失时空特征

中国北方干旱/半干旱区是全球主要的沙尘源区之一,风蚀造成的沙尘排放可导致大量的土壤有机质（SOM）与养分流失,并通过传输与沉降过程对其进行空间再分配,对空气质量、气候变化、植被生长及生物地球化学过程等具有重要影响。本文利用WRF/Chem（Weather Research Forecasting with Chemistry）v3.7.1大气化学传输模型,对1980—2015年间中国北方沙尘排放及其引起的SOM、全氮（TN）与全磷（TP）的时空变化过程进行了精细化模拟,探究了中国北方风蚀引起的SOM、TN与TP养分流失的时空变化特征。结果表明：① 1980—2015年来平均每年约有66.59 Tg的沙尘颗粒排放至大气;② 沙尘排放具有较大的时空差异,沙尘排放源区主要集中在新疆东部、内蒙古西部的巴丹吉林沙漠和腾格里沙漠等地区;③ 每年因沙尘排放引起的SOM、TN和TP流失量分别约为0.07 Tg、0.004 Tg和0.005 Tg;④ 1980—2015年间中国北方沙尘排放及其引起的SOM、TN与TP的流失量具有较强的年际波动,未呈现显著的趋势性变化特征。本研究对于认知风蚀在碳循环与养分循环过程中的作用,以及对深入了解中国北方的土地退化机理具有重要意义。     

苔藓生物结皮层腐殖质组成变化特征研究

腐殖质组成是表征土壤化学性质的主要指标之一,在某种程度对评价风沙土的发育过程具有意义。采集了不同气候区沙地沙漠苔藓生物结皮层样品,采用重铬酸钾容量法和光密度法测定了苔藓结皮层腐殖质组成含量和胡敏酸吸光特性。结果表明：随着干燥指数的增加,苔藓结皮层有机质含量由14.93 g·kg^-1降低到9.89 g·kg^-1,腐殖酸总量由5.1 g·kg^-1降低到2.0 g·kg^-1,胡敏酸含量由2.9 g·kg^-1降低到 0.7 g·kg^-1,富里酸含量由2.2 g·kg^-1降低到1.3 g·kg^-1,胡敏酸与富里酸比值（HA/FA）由1.32降低到0.54,E₄/E₆比值则由4.28增加到5.83。苔藓结皮层腐殖质组成含量及胡敏酸吸光特性具有地带性变化趋势,并影响着生物结皮层及流动风沙土的发育演变过程。     

有机质对海底沉积物中粘土矿物X射线衍射分析结果的影响

X射线衍射法广泛应用于分析粘土矿物的含量和结晶特征,由于粘土矿物易与有机质结合形成有机-粘土复合体,是否去除有机质对分析结果有很大影响,实验结果表明影响最大的是伊-蒙混层矿物(含蒙脱石)和伊利石的含量,为得到可靠实验数据,必须重视对样品的前处理工作,对不同批次样品应该保持一致的处理程序。     

五种双壳贝类贝壳微观结构观察与成分分析

利用扫描电镜技术、X-射线粉末衍射技术和弱酸去钙法,对菲律宾蛤仔、文蛤、厚壳贻贝、泥蚶、缢蛏5种习见海洋经济贝类贝壳的断面微观结构、物相组成、有机基质和蛋白质含量等进行了观察和分析。电镜观察结果显示, 5种贝壳的微观结构主要包含棱柱层和珍珠层;棱柱层晶体结构有斜棱柱层、球棱柱层、棱柱层、均质层和交错板状层5种类型,其中缢蛏只有斜棱柱层,而泥蚶除球棱柱层外,其他4种晶体类型均存在,此复杂结构可能与其贝壳强度大有关;珍珠层晶体结构有珍珠层和肌棱柱层2种类型,其中厚壳贻贝的珍珠层呈典型的“砖-泥”结构,具有明显的层状结构,其余4种贝壳珍珠层均由不规则块状结构组成。X-射线衍射结果显示,菲律宾蛤仔、文蛤、缢蛏和泥蚶4种贝壳都属于文石质壳体,无机相几乎由文石组成,而厚壳贻贝属于混合质壳体,无机相由文石和方解石组成;贝壳化学成分分析显示,5种贝壳有机质含量均为3%左右,而总蛋白含量占有机质的2.98%～7.21%,其中可溶性蛋白是不可溶蛋白含量的5.55～20.31倍。上述结果为贝壳形成机理的研究积累了基础资料。     

Water, organic matter, nitrogen and phosphorus contents in sediment of a large-scale mariculture area in the Zhelin Bay of eastern Guangdong Province, China

The Zhelin Bay is one of the most important bays for large-scale mariculture in Guangdong Province, China. Owing to the increasing human population and the expanding mariculture in the last two decades, the ecological environment has greatly changed with frequent harmful algal blooms. A monthly survey of water content, organic matter （TOM）, and various forms of nitrogen and phosphorous in sediment from July 2002 to July 2003 in the bay was conducted. The results showed that the water content was correlated significantly with TOM and various forms of nitrogen and phosphorus and can be used as proxy for quick and rough estimate of these factors in the future surveys. TOM was also correlated significantly with various forms of nitrogen and phosphorus, indicating that it was one of the key factors affecting the concentrations and distributions of nitrogen and phosphorus in the investigated waters. Average total Kjeldhal nitrogen （TkN） content was（ 1 113.1 ± 382.5）μg/g and average total phosphorus （TP） content was（567.2± 223.3）μg/g, and both were much higher than those of similar estuaries in China and elsewhere. Average nitrogen and phosphorus tended to be higher inside than outside the bay, higher at aquaculture than non-aquaculture areas, and higher at fish-cage culture than oyster culture areas, suggesting that large-scale mariculture inside the bay played an important role in the eutrophication of the Zhelin Bay. Various forms of nitrogen and phosphorus concentrations were higher during the warm season （July--September）, which was due to the increased decomposition and concentration of organic matter resulted from the fast growth and high mortality of the cultured species. Compared with July 2002, TkN and TP contents were much higher in July 2003, in consonance with the eutrophication of the Zhelin Bay. Because exchangeable phosphorus （Ex-P）, iron-bounded phos- phorus （Fe-P） and organic phosphorus （OP） combined accounted for 34.3% of the TP and authigenic phosphorus （Au-P     

Multivariate analysis of fluorescence and source identification of dissolved organic matter in Jiaozhou Bay, China

Hierarchical clustering analysis and principal component analysis (PCA) methods were used to assess the similarities and dissimilarities of the entire Excitation-emission matrix spectroscopy (EEMs) data sets of samples collected from Jiaozhou Bay, China. The results demonstrate that multivariate analysis facilitates the complex data treatment and spectral sorting processes, and also enhances the probability to reveal otherwise hidden information concerning the chemical characteristics of the dissolved organic matter (DOM). The distribution of different water samples as revealed by multivariate results has been used to track the movement of DOM material in the study area, and the interpretation is supported by the results obtained from the numerical simulation model of substance tracing technique, which show that the substance discharged by Haibo River can be distributed in Jiaozhou Bay.     

Application of matter-element model in soil nutrient evaluation of ecological fragile region

On the basis of the soil environment investigation in Da'an City, Jilin Province, China, 40 soil samples from main land use types were obtained and tested by standard method. Soil organic matter (SOM), total N (TN), total P (TP), total K (TK), available N (AN), available P (AP) and available K (AK) were chosen as the evaluation factors. A regional soil nutrient evaluation model was developed based on the matter-element model. The results show that the soil samples with nutrient grade Ⅱ-Ⅴ respectively account for 10%, 30%, 32.5% and 27.5%, and those with grade Ⅳ and Ⅴ account for 60% in all samples. The relationship between soil nutrients and land types indicates that the nutrients of farmland are relatively good, with 41.7% of soil samples with the nutrient grade Ⅳ and Ⅴ. The nutrients of saline-alkali land and sandy land are the worst, with 100% of soil samples with the nutrient grade Ⅳ and Ⅴ. And the ratios of soil samples grade Ⅳ and Ⅴ in grassland and wasteland are respectively 62.5 % and 54.55%. Generally speaking, the soil nutrients status in Da'an City is poor, 60% of soil samples are in poor and extremely poor conditions, indicating that the soil has been severely eroded. Being a relatively superior evaluation method with more accurate resuits and spatial distribution consistency, matter-element analysis is more suitable for regional soil nutrient evaluation than previous models.