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31.
Yoko Shimamoto Yoshio Takahashi 《中国地球化学学报》2006,25(B08):114-114
Although inorganic species are predominant in natural systems, but there are many kinds of organoarsenic species such as methylated and phenylated arsenic compounds. Phenylarsonic acid (PA) is a degradation product of organoarsenics used for chemical warfare agents, which has been detected in well water at the disposal site of the agents in Japan. There are few reports studying behavior of PA in soil. In this study, PA was adsorbed onto ferrihydrite and its chemical forms were determined using high performance liquid chromatography connected to inductivity-coupled plasma mass spectrometry (HPLC-ICP-MS). 100 mg/kg of PA was mixed with 0.03 g of 2-line ferrihydrite. For each suspension, pH was adjusted by HNO3 or NaOH. Each sample was incubated for more than 19 hours and the final pH was measured. After filtration, the chemical form of arsenic in the filtrate was measured using HPLC-ICP-MS. In addition, ferrihydrite separated by filtration was dissolved by 3 ml of 0.5 M HCI and the arsenic species in the solution was detected by HPLC-ICP-MS (column: Tosoh TSKgel SuperlC-AP, eluent: 0.01 M HNO3). It was verified that PA is not degraded by heating in 0.5 M HCl solution. At pH 3.1, any arsenic compounds were not detected from the solution, because almost all arsenic species were adsorbed onto ferrihydrite at lower pH. At pH= 12, however, 7%-10% of inorganic arsenic was detected in the solution. In solid phase, there are some problems to determine the precise ratio of inorganic and organic species. When the solution includes Fe ion at 0.01 M level, the retention time of arsenic species drifted compared to those in standard solution, which makes it difficult to determine precisely the arsenic species adsorbed on ferrihydrite. Therefore, more study is needed to determine the ratio of inorganic and organic species in the system. 相似文献
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Rajasekhar Balasubramanian Chanbasha Basheer Kang Lisa Siao Wei See 《中国地球化学学报》2006,25(B08):183-183
Microorganic pollutants such as polycylic aromatic hydrocarbons (PAHs), organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs) and total petroleum hydrocarbons (TPHs) are known to be present in urban ambient air. These organic compounds are prone to atmospheric transport and deposition over long distances, thus enabling them to accumulate even in regions remote from their sources. Deposition from the atmosphere can be via direct deposition and exchange with crops that may be directly or indirectly ingested by humans. It can also take place via wet and dry deposition and air-water exchange. Following their deposition, these microorganic pollutants tend to accumulate in soils, sediments and in human and ecological food chains. There are many reports in the literature on the atmospheric concentrations of microorganic pollutants, but there are few reports and data in Asia. This study was performed in Singapore to determine the relative amounts of persistent organic pollutants and TPHs in ambient aerosols. One of the important sources of these organic compounds in Southeast Asia is thought to be biomass burning (vegetation fires). Hence, air sampling was conducted during both smoke haze and non-haze periods. The data obtained from this study will be presented and discussed. 相似文献
34.
Sivaji Patra Congqiang LIU Siliang LI Fushun WANG Baoli WANG 《中国地球化学学报》2006,25(B08):269-270
Geochemical cycling has received wide attention due to the need to understand the pathways of pollutants through our present environment. In this regard the Yangtze River plays a significant role in putting those pollutants into the East China SeafWorld Oceans. The Yangtze River is of high sedimentation rate and water discharge. The watershed covers variable climate regions from temperate to subtropical and from semiarid to humid. Twenty three (23) sampling locations at the estuary have been selected for understanding the dynamic relationships. The elements (Cl^-, SO4^2-, Na^+, K^+, and Ca^2+) show conservative behavior during mixing of fresh water with saline water whereas Mg^2+, Mn^2+ show a non-conservative pattern . The relationships between Na^+/SO4^2- and Cl^-/SO4^2- molar ratios show a mixing of more than two water sources. 相似文献
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平落坝储层有机包裹体特征与气藏形成过程研究 总被引:4,自引:0,他引:4
通过储集层成岩作用与有机包裹体的研究认为,研究区储集层有机包裹体主要通过交代和重结晶作用而形成,有各种相态形式,主要分布在石英颗粒内溶蚀缝或孔隙中,构造裂缝中基本未见有机包裹体。上三叠统储集层包裹体丰度明显高于侏罗系沙溪庙组。香二气藏砂岩有机包裹体均一温度主峰在 10 0~ 110℃;沙溪庙气藏砂岩有机包裹体均一温度主峰在 90~ 10 0℃。香二气藏形成时间早,经历了印支期少量注入到印支期末-喜山早期大量注入,再到喜山晚期调整、部分注入的过程。沙溪庙气藏天然气注入则主要发生于喜山运动期。 相似文献
38.
兖州矿区煤中某些微量元素的赋存状态研究 总被引:6,自引:8,他引:6
微量元素的赋存状态决定其在煤的加工利用过程中释放的难易程度和毒性,弄清其在煤中的赋存状态,对准确评价元素的工艺性能、环境影响、作为副产品的可能性以及在地质意义上都是十分重要的。分析了微量元素在煤中的有机亲合性,采用数理统计方法,求得了微量元素与煤中有机显微组分、三态硫、灰分之间的相关性,并在浮沉实验的基础上,分析了微量元素的存在状态,通过研究向知,Ge、Ga、U、V、Cu、Th、Pb和Zn主要以无机态存在于煤中,F和Cl可能以有机态存在为主,As无机态和有机态存在的机率相似。 相似文献
39.
武汉市区第四系含水层地下水有机污染敏感性研究 总被引:14,自引:0,他引:14
在详细调查武汉市水文地质条件和地下水污染现状的基础上,获得了高精度的武汉市水环境中微量有机污染物的组成数据。所检测出的有机组分达30余种,以苯及相关苯系物为主,污染程度较高的地下水主要分布在人口密集区和工业,商业区,应用改进的DRASTIC模型-地下水污染敏感性评价模型,在GIS平台上,编制了武汉市区地下水污染敏感性分区图。根据其评价结果,建议集中对那些敏感性相对较高的区域采取有效的环保措施,开发利用时应作出风险评价。 相似文献
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