石墨炉原子吸收法测定钛铁矿中的微量镉

研究了石墨炉原子吸收测定钛铁矿中微量元素 Cd 的方法,探索了在高含量的 Fe,Ti 基体干扰下以NH4H2PO4-H2NCSNH2-EDTA为混合基体改进剂的最佳仪器工作条件。在取样0．2000g,定容25 mL的条件下,方法检出限为0．006μg/g,用国家标准物质验证,其准确度（犚犈％）＜10％,12次测定精密度（犚犛犇％）＜10％,加标回收率90％～110％之间,符合国家相关要求。     

攀枝花中坝乡天宝山石墨矿床地质特征及找矿标志

天宝山石墨矿赋存于前震旦系康定群冷竹关组片岩建造中,呈似层状产出。根据岩性、碳质来源及矿床成因等地质特征,天宝山石墨矿属于沉积变质型矿床。天宝山石墨矿床找矿标志矿主要有地层时代标志(前震旦系康定群冷竹关组变质岩层)、岩性标志(云母石英片岩)、岩浆岩标志(石英闪长岩)和物探异常标志(低电阻、高极化率)。在调查区共圈定石墨矿体3条,其中KT1矿体走向最大长度约1.92km,矿体最大出露厚度约12m,矿石品位3%～14.95%。通过地质和物探工作,发现天宝山石墨矿成矿规模大,具有较大的社会经济价值。     

石墨炉原子吸收法测定化探水样中的铅、铬、钴、镍

在黄土覆盖，干旱半干旱自然景观区采用水化学测量进行普查找矿有重要的指示意义，但化探水样中Pb、Cr、Co、Ni的测定报道不多。对于水样中痕量元素用火焰原子吸收虽有介绍^[1，2]，但用石墨炉原子吸收法较为理想^[8，4]。为提高分析的质量，普遍使用基体改进剂。我们采用HNO8-H2O2消化水样，加入钯盐作基体改进剂，以石墨炉原子吸收光谱法对化探水样中的铅、铬、钴、镍进行测定，简化了分析操作，提高了结果的可靠性。     

无固相冲洗液在变质岩系复杂地层绳索取心钻进中的应用

辽宁省北镇市杜屯地区超大型石墨矿处于变质岩系中,在勘查过程中分析了该区变质岩系复杂地层的成因及特点,采用了绳索取心与无固相冲洗液钻进工艺,并分析了冲洗液对石墨岩矿层稳定性的影响,对冲洗液体系进行了优化,分析了冲洗液的护壁作用机理。同时对钻进过程中的技术应对措施进行了优化,解决了绳索取心钻进过程中钻杆结泥皮及技术套管的使用等问题,顺利地完成了矿床的勘探工作,取得了良好的技术经济成果。     

Dechlorination of trichloroethylene in solution over supported nano zero valent Fe and Cu/Fe bimetal on exfoliated graphite

Degradation of organic halides by reductive dehalogenation promoted by zerovalent metals is a very active research area. The use of nano-sized particles of zero valent iron （ZVI） or bimetallic combinations of ZVI currently attracts the most attention due to their high surface areas and high reactive activity. The introduction of second catalytic metals, such as Pd, Pt, Cu, or Ni, results in an even higher dehalogenation rate. The supported zero-valent iron materials have higher activity and greater flexibility for environmental remediation applications than other forms of ZVI. Nano ZVI supported on micro-scale exfoliated graphite was prepared by using KBH4 as the reducing agent in the H2O/ethanol solution of Fe^2＋ in the laboratory. Then the ethanol solution of Cu^2＋ was added to the fleshly prepared wet supported nano ZVI. The Fe/Cu bimetallic particles supported on the graphite were obtained because of the reduction and deposition of Cu on the Fe surface. The TEM image showed that iron particles were highly dispersed on the surface of graphite. In this study, supported zero valent Cu/Fe bimetallic nanoparticles were used for the dehalogenation of trichloroethylene （TCE） in batch experiments. The dechlorination rate of supported zero valent Fe/Cu bimetallic nanoparticles was greater than the supported nano ZVI. Supported Cu/Fe bimetal with 4 wt% Cu had the fastest dehalogenation rate than that with different content of Cu. When the nana FeO dosage was 5 g/L in the dehalogention system, 8 mg/L of TCE was completely dechlorinated within 4 hours. Increasing or decreasing the FeO dosage, the dechlorination rate could be worse. When the concentration of Fe^2＋ was 0.05 mol/L during the preparation by KBH4 reduction, the nano Cu/Fe particles exhibited the spheral shape with 50-80 nm in size. When the concentration of Fe^2＋ was higher （0.2 mol/L）, the nano particles were the palpus structure and had the poor dehalogenation effect on the TCE.     

康滇地轴巨粒晶质铀矿的发现及其地质意义

康滇地轴米易海塔地区富晶质铀矿石英脉产于晚元古代受混合岩化作用影响的五马箐组黑云斜长片岩中,受韧-脆性断裂构造裂隙带控制。晶质铀矿呈黑色,半金属光泽;晶形完好,以立方体与八面体聚形及菱形十二面体为主,少量呈立方体;粒径大多0.5cm左右,最大可达1cm以上。共生矿物组合为石英-晶质铀矿-榍石-辉钼矿组合。研究认为,晶质铀矿形成于温度压力较高及深度较大的地质环境,是高温偏酸性流体在温度缓慢下降的强还原条件下结晶而成的。康滇地轴具有形成高强度铀矿化的地质背景和成矿条件,在康滇地轴混合岩地区最有前景的铀矿类型应为受韧-脆性构造控制的中高温热液脉型矿化。     

全热解石墨管石墨炉原子吸收法测定痕量锶

研究了热解涂层和全热解石墨管中Sr的原子吸收信号形状和原子化行为,讨论了CaCl_2、FeCl_3和HClO_4,抑制Sr吸收信号的原因。采用EDTA铵盐作基体改进剂,全热解石墨管石墨炉原子吸收法直接测定河泥中痕量Sr,方法的特征量为6.9pg/0.0044A。     

赣南6722铀矿床钛铀矿—晶质铀矿—铀石—沥青铀矿显微共生组合的厘定及成因意义

通过235U诱发裂变径迹及电子探针测试综合研究,在6722铀矿床的含矿隐爆角砾岩胶结物中首次发现钛铀矿—晶质铀矿—铀石—沥青铀矿显微共生组合。这样一种在1 cm2(光薄片)范围内分布,而且不存在任何脉状相互穿插现象的钛铀矿—晶质铀矿—铀石—沥青铀矿显微共生组合表明其形成于同一成矿物理化学体系中。根据UO2—TiO 2—H2O体系稳定场,确定6722铀矿床中钛铀矿—晶质铀矿—铀石—沥青铀矿显微共生组合形成温度范围为250~350℃,属中—高温热液成因。