高温焙烧对白云母晶体结构和物性影响研究

通过X射线荧光光谱仪、X射线粉晶衍射分析、热重分析、扫描电镜等表征手段,研究焙烧温度对白云母晶体结构特征、物性变化的影响.结果表明:白云母在25～1 200℃温度范围的加热过程变化主要分为三个阶段:25～500℃,该焙烧温度段对白云母的晶体结构、光学性质、表面形貌影响甚小;600～1 000℃,白云母虽保持片层状晶体结...     

锡石的晶体结构和形态的关系

本文对不同成因类型的锡石晶体形态进行了研究,并从PBC(周期性键链)理论出发,讨论了锡石晶体形态与晶体结构的关系。笔者认为,锡石晶体具有三种F面,即s{111}、e{101}、m{110},与Hartman对同样结构类型的金红石晶面性质划分有所差异。据锡石晶面结构性质所推导的理想晶体形态图,与晶体测量所得到的天然晶体形态图总体上相吻合。     

Bond—Valence Sum and Distortion of Coordination Polyhedra

By using the Lagrange‘s intermediate value theorem,it is derived mathematically that the structur-al distortion of a coordination polyhedron may lead to an increase in bond-valence sum of the cen-tral atom of ion .The applicabilities of the bond-valence model are discussed in the following two cases:the modeling of crystal structure ,and the indication of distortion degree of a coordination polyhedron.Also it is shown that a distorted polyhedron should be in favor of a longer average bond length or a smaller coordination number.     

衍射指标h和k的互换问题

通过衍射线指标和面网指标的联系讨论了晶体的对称性对衍射指标h和k互换的影响。在下列情况下衍射指标h和k是不能互换的:在低级晶族;在四方晶系C_(4h)—4/m劳厄点群,六方品系C_(6h)—6/m劳厄点群和立方晶系T_h—m3劳厄点群对于hko和kkl型衍射;在三方晶系选取六方晶胞的情况下,在C_(3i)—3劳厄点群对于hol,okl,hko和hkl型衍射,在D_(3d)—3m劳厄点群对于holokl和hkl型衍射,以及在菱面体点阵除非h和k都是三的倍数。     

电解二氧化锰制备条件与晶体结构及电气性能的关系.不同电解液体系的影响

在MnSO-4-H-2SO-4和MnCl-2-HCl电解液体系中分别制备出电解二氧化锰(EMD),并在该二电解液中制备出掺杂MnO-2样品,而后用X射线衍射确定其晶型为MnO-2-γ,用扫描电镜观察其表面形貌,用XPS研究掺钛EMD表层物种;用模拟电池在实验室中快速检测掺杂样品的电性能,进而探讨了不同电解液体系中制备所得MnO-2与其晶体结构及电气性能的关系.     

晶体结构图实用微机程序

本文介绍的是用于矿物学教育与研究的若干实用程序。其主要内容包括晶体结构图绘制、粉末X光衍射线位置和强度的计算、最小二乘法的空间格子常数计算以及晶形外形图绘制。该程序使用16位NEC PC9801微机和BASIC语言,数据输入、绘图以及计算皆可由菜单指定,稍具备晶体学知识的人都会利用。     

Effect of Overpressure on Rock Frame and Its Implications for Overpressure Evolution

Overpressure is a hot topic in the study of sedimentary basins. It is important in generation,maturation migration,and accumulation of hydrocarbon,but the effects of overpressure on rock frame have not been investigated. In this study,experiments were carried out to study the effects of overpressure on rock frame structures using five core samples from the Junggar basin,Northwest China. The deformations and velocities for the samples were measured at different effective pressures related to non-equilibrium compaction and fluid expansion overpressure mechanisms. The results show that the effect of overpressure on rock frames gradually increases when the effective pressure drops down to a certain value (called critical pressure). Moreover,non-equilibrium compaction mechanism has more effects on rock frames than fluid expansion mechanism under the same effective pressure. Furthermore to study rock frame structural changes,we use Kuster and Toks?z's expressions to simulate the effective aspect ratios of inclusions α (penny shapes) for different effective pressures. The results show that the α decreases dramatically when the effective pressure decreases from the critical pressure. Changes of α can be interpreted as responses to the rock frame changes when grains conform one another by rotating and self-adjusting. However,different mechanisms of overpressure have different effects on rock frames. The rock frame can be affected more easily by overpressure in shallow regions generated by non-equilibrium compaction mechanism. Once this kind of rock frames are preserved after overpressure releases to a normal hydrostatic pressure,they can be identified by their specific rock frame characters. This method provides a new way to study overpressure release and fluid migration and accumulation.     

草莓红绿柱石的晶体结构及其对形态的影响

草莓红绿柱石(Pezzottaite)是一种含高锂-铯新发现的属三方晶系的新矿物种,理想化学式为Cs(Be2 Li1)3Al2Si6O18.结构与绿柱石相似,属于复杂的环状硅酸盐矿物.空间群为R 3c[1-2].     

不同水域鲤鱼耳石CaCO3晶体结构特征与环境响应初探

鲤鱼耳石共有三对:矢耳石、微耳石、星耳石;分别存在于球状囊、椭圆囊、平状囊(听壶)中,具有重要的感应平衡、运动、重力和声音的作用.