浅议痕量分析中的污染源

关于痕量分析的污染问题已有许多文献作为全面阐述，本文主要介绍笔者在分析测试和方法研究中遇到的一些现象与解决的途径。     

β-环糊精-1，2，5，8-四羟基蒽醌包结物荧光法测定铍

本文对1，2，5，8-四羟基蒽醌(THA)与镀形成配合物和THA进入β-环期精(β-CD)的内空腔与镀形成包结物这两种测定镀的荧光分析方法进行了比较，试验表明，后者的灵敏度和重现性有显着提高．选择性明显改善。详细研究了方法的测定条件．并应用于矿样中痕量镀的测定，结果符合质量要求。     

武夷山脉中段晚太古代宇宙尘特征

武夷山脉中段晚太古代宇宙尘赋存于上太古界天井坪组。粒度一般为0．15-0.2mm，最大0.32mm，最小0.042mm,形态呈单球体、不规则形或碎片状，以前者为主。在扫描电镜下表面具烧蚀、蜂巢状气印、气孔状、刺(瘤)突趁、晶洞及偏心双层等结构。宇宙尘由内核和熔壳组成；内核是自然铁(a-Fe)，含Fe、Cr、Ni、Co等元素；熔壳是磁铁矿或方铁矿，除Fe外尚含Si、Al、Cr、Mn、S等元素：根据其结构、构造组成和物质成分的综合分析结果，并与国内文献资料进行对比，本区宇宙尘可能是铁陨石在大气中的消融物或在太空中的碎裂物。     

The Geologic Time Scale and the Italian stratigraphic record

The construction of the Geologic Time Scale (GTS) is a titanic scientific challenge that has been under way for two centuries and will require much dedicated effort in the future. Italy preserves a paramount stratigraphic record of Mesozoic and Cenozoic marine sediments that have been significant in the development of the modern GTS. The Italian stratigraphic record has been histori-cally important in introducing and defining the standard Chronostratigraphic Units (CUs) of the Neogene and Quaternary. Pelagic successions from Northern Apen-nines and Southern Alps have been used in the seventies for integrating the late Cretaceous-Paleogene Geomag-netic Polarity Time Scale (GPTS) with planktonic microfossil biostratieraohv and standard CUs. This was a major contribution to the construction of a new gener-ation of GTS based on integrated magnetobiochronol-ogy. The middle Miocene to early Pleistocene marinerecord from Sicily and southern Italy has been funda-mental for establishing the recently developed Astro-nomical Time Scale (ATS). In prospect, there are many potentials still to be exploited in the Italian marine stratigraphic record for implementing the GTS by defin-ing GSSPs of various CUs, improving magneto-biochronology and extending downwards the ATS.     

Sedimentary characteristics of tide-dominated estuary in Donghetang Formation（Upper Devonian）, central Tarim Basin

The Donghetang Formation （Upper Devonian） in central Tarim Basin has been thought an important oil and gas reservoir since the abundant oil and gas resources were found in the wells W16, W20, W34, and other fields. However, the sedimentary environment of the Donghetang Formation has been disputed because it suffered from both tidal and fluvial actions and there were not rich fossils in the sandstone. After the authors analyzed sedimentary features by means of drill cores, well logging data, paleosols, and with SEM obseruations, three kinds of sedimentary environments were distinguished： alluvial fan, tide-dominated estuary, and shelf. Particularly, the sedimentary features of tide-dominated estuary were studied in detail. Besides, the authors discussed sedimentary characteristics of the Donghetang Formation which was divided into two fourth-order sequences and five system tracts. At the same time, according to the forming process of five system tracts, the whole vertical evolution and lateral transition of tide-dominated estuary were illustrated clearly. Finally, the reservoir quality was evaluated based on porosity and permeability.     

比值分析及其在伴生元素评价中的应用

比值分析是利用伴生元素含量(x)与主元素含量(c)在矿石中的比值(α=x_0/c_0),在矿物中的比值(b=x_i/c_i)以及两者的比值(称比值系数k=b/α),对伴生元素赋存规律进行分析研究的方法。b值和矿石中仅有一种矿物含某种伴生元素的a值,可确切了解伴生元素自身变化、富集规律及其在载体矿物中分布的均匀程度;矿石中与各矿物相关联的k值具有如下关系:k_1+k_2+…=1,据此可确定伴生元素在各有关矿物中的分配情况和判断赋存有该种伴生元素的矿物是否全部查明。