河北省青龙县霸王沟侏罗纪叶肢介化石

河北省青龙县木头凳镇兴隆台村霸王沟的侏罗纪地层产翼龙、蝾螈、鱼类、昆虫、叶肢介、双壳类及植物化石,是一个侏罗纪晚期的特异埋藏化石地点。研究者曾认为其相当于中侏罗统道虎沟化石层。经过我们对其中叶肢介的研究,发现霸王沟与这些脊椎动物临近层位的叶肢介与辽宁建昌玲珑塔化石层最常见的柴达木叶肢介(Qaidamestheria)属于一类,壳瓣上都具有较稀疏的微小刻点装饰,而与道虎沟化石层的"真叶肢介"却具有一定差异。霸王沟的叶肢介和脊椎动物组合面貌与玲珑塔化石层相似,属玲珑塔化石层,时代为晚侏罗世最早期,明显晚于道虎沟化石层。道虎沟化石层和玲珑塔化石层的生物组合代表了燕辽生物群早晚两个有明显差异又相互关联的群落。     

贵州晴隆中二叠统大厂层砾岩成因研究

贵州晴隆中二叠统大厂层中—上部产出一套呈囊状、透镜状分布的砾岩层。对大厂层砾岩沉积序列、结构、构造特征和矿物组合进行研究,结果表明:沉积序列为"反粒序",砾岩成分单一,基本为玄武质,是由峨眉山玄武岩直接改造而成,未发育河道相沉积特征;大厂层砾石具特殊的"泥化边"构造,是玄武岩在海水中大量水解的直接证据,填隙物中的青磐岩化矿物组合表明砾岩遭受了低温热液的改造。填隙物具有接近凝灰岩的Zr/Hf(30.7~43.4,均值38.0),揭示玄武岩在改造形成砾石的过程中有火山碎屑(火山灰)参与成岩;砾石和填隙物相对玄武岩贫Na(Na2O)富K(K2O),三者具有相似的稀土配分模式,其中∑REE呈规律性变化(玄武岩最高,砾石次之,填隙物中最低)。沉积背景分析认为,峨眉地幔柱作用使地壳发生了差异抬升,抬升一侧暴露遭受剥蚀形成不整合面,相对沉降一侧继续接受沉积,大厂层正是峨眉山玄武岩前锋带在局限海盆边缘(沉降侧),于茅口灰岩之上继续沉积的产物。大厂层砾岩形成机制是:炽热玄武岩流在海水中急剧爆裂,同时火山碎屑参与沉积,形成的玄武岩前积层(淬碎熔岩角砾)及凝灰岩,沉积在茅口组灰岩之上;在后期的演化过程中,炽热玄武岩冷凝收缩,柱状节理发育,在潮汐流和沿岸流的相互作用下不断磨蚀形成大厂层砾岩。     

鄂尔多斯盆地陇东地区长9油层组古盐度特征及其地质意义

利用黏土矿物X衍射分析和微量元素分析结果,采用Couch公式和Adams公式对鄂尔多斯盆地陇东地区长9油层组沉积期湖盆古盐度进行恢复,确定由于受到成岩作用影响,由Couch公式计算出的古盐度值比实际值低,而由Adams公式计算结果反映的水体古盐度性质更可靠。研究表明:①鄂尔多斯盆地长9油层组沉积期湖盆水体具微咸水-半咸水性质,盐度从北东、北西及西南3个方向往湖盆中央呈逐渐升高,晚期的盐度低于早期盐度,反映湖平面上升的湖进过程。盐度高值区为相对闭塞的湖湾和湖盆中心的半深湖区。平面上,古盐度向河流入注湖盆的河口方向降低。由古盐度变化为古地理恢复提供了依据;②湖泊水体盐度与储层关系密切,较高盐度的水体有利于早成岩阶段绿泥石环边胶结和浊沸石的形成,前者有利于原生粒间孔隙的保存,后者更容易被溶蚀而形成丰富的次生溶孔。     

超级喷发(超级侵入)后成矿作用

本文仿照超级喷发的概念定义了超级侵入,并将超级火山对应于大型岩基.文章聚焦于这样一个科学问题:为什么大规模成矿作用发生在紧接着超级喷发和超级侵入之后？为此,首先探讨了峨嵋山地幔柱系统的活动规律.尽管少数学者对玄武质岩浆大规模喷出之前的千米级地壳隆升提出了质疑,峨嵋山火山岩系第一旋回底部玄武岩直接覆盖在喀斯特之上的新观察支持千米级隆升的认识.这表明,峨嵋山地幔柱快速上涌之初期,岩石圈子系统在相当长一段时间没有作出伸展响应,尽管局部已经发生了地壳岩石的部分熔融.因此,岩浆通道形成之后,首先喷出了巨厚层玄武岩,并且后者裹挟了部分长英质岩浆.此后,岩浆喷发的规模振荡性减小,直至消失和地表沉降.斜长石巨斑玄武岩和苦橄岩中橄榄石斑晶与基质间的不平衡表明这些晶体属于循环晶,暗示岩浆曾经在深部岩浆房滞留了相当长的时间,这将导致岩石圈受热膨胀和再次隆升以及岩浆的冻结.因此,下一阶段岩浆活动的开始要求有一个冻结岩浆房的活化机制.依据野外地质学和岩相学观察,文章详细描述了流体活化机制,并强调了提出这种机制的必要性.虽然多数作者偏好升温活化机制,流体活化机制对长英质和镁铁质岩浆成矿系统都是必需的.进而,结合地幔名义无水矿物的H₂O丰度及其对岩浆产生过程的贡献,提出岩浆产量与减压速率正相关而与流体产量反相关的观点.尽管水流体可以有效降低地幔橄榄岩的固相线温度从而有可能提高岩浆产量,新生代玄武岩中橄榄岩包体依然含有未分解的角闪石和云母且名义无水矿物依然含有较多的H₂O,表明快速减压条件下含水暗色矿物的分解反应和名义无水矿物的脱水作用都是低效的.将这种认识与峨嵋山地幔柱系统的振荡性运动结合在一起,结合成矿作用的基本解是成矿金属从流体中析出的认识,可以得出超大型矿床必然形成于超级喷发和超级侵入之后.攀枝花式铁矿的观察表明,两类代表性矿床都具有铁矿浆侵位发生在成矿系统演化最后阶段的特点.因此得出结论:超大型矿床的形成取决于岩浆通道向流体通道的转换.如果岩浆通道在尚未完全封闭之前被含矿流体所利用,大规模流体快速上升将产生超大型矿床.含矿流体透过残留于通道中的熔体上升,不仅冲刷通道中的残留熔体并使其聚集在火山岩系之下或侵位于其下部形成含矿小岩体,而且持续注入于小岩浆体中的含矿流体可以导致岩浆强烈分异形成层状岩体.当通道中残留熔体被消耗殆尽,沿着通道上升的只有含矿流体.这些含矿流体充填在自生长裂隙中并强烈排气,最终可形成矿浆型富矿体.考虑到通道的规模与关闭速率的关系,推测超级喷发/侵入发生时的岩浆主通道更容易转换为含矿流体通道,因而是圈定找矿靶区的首选目标.该模型似乎与观察结果相吻合,并可与岩浆成矿系统的复杂性、小岩体成大矿理论、透岩浆流体成矿理论和通道成矿假说有机地结合在一起,较合理解释了超级喷发/侵入后成矿作用的地球动力学背景和成矿过程.由于长英质和镁铁质岩浆系统中均可见岩基,我们建议将这类成矿作用统称为岩基后成矿作用.     

新元古代地幔柱事件在Rodinia超大陆西缘的响应:来自马达加斯加的初步证据

对于Rodinia超大陆西缘在裂解过程中是否发育巨长安第斯型陆弧存在较大争议.马达加斯加即位于古地理再造Rodinia的西缘位置,其太古宙结晶基底中出露有大量新元古代侵入体,是澄清这一争议的理想研究区.由于基性岩浆岩组分识别不足等原因,前人曾认为这些侵入岩形成于俯冲带陆弧环境.但笔者在中北部Alaotra湖地区野外考察期间发现了大量辉长质岩石,对其中典型岩体的LA-ICP-MS锆石U-Pb测年表明其结晶于798~778Ma之间(最大误差估计).因此,这些辉长岩体事实上与岛内其他新元古代侵入体构成了双峰式侵入岩套,暗示了可能的陆内伸展环境.在此基础上,笔者重新审视了前人已发表的地球化学数据,发现该双峰式侵入岩套的基性组分显示富钾特征和拉斑演化趋势,局部甚至发育了强烈地钒钛磁铁矿化;酸性组分则显示富铁、偏铝-过铝质和碱钙-钙碱性特征,并具有相对较高的K₂O/Na₂O和Ga/Al比值以及高场强元素含量,属于A型花岗岩(铁质花岗岩).这些特征进一步表明该双峰式侵入岩套形成于陆内伸展环境而非陆弧环境.结合本文的初步研究结果和区域地质演化历史,笔者认为马达加斯加这一双峰式侵入岩套很可能是新元古代地幔柱事件在Rodinia超大陆西缘的响应.     

宁南弧形构造带甘肃大沟—内蒙古乱井中上地壳电性结构

利用大地电磁探测方法在宁南弧形构造带内蒙古乱井—甘肃大沟段进行了中上地壳电性结构特征研究,通过二维反演获得了研究区的电性结构模型,模型清楚揭示出了该区典型的电性结构特征:(1)中上地壳电性结构整体表现为"碎块状"的构造特征,其中走廊构造带总体表现为相对低阻,北祁连碰撞造山带总体表现为相对高阻;(2)海原地震震源区的震源断裂所反映的低阻带构造样式既不像走滑断裂那样陡峭,也不像逆冲断裂那样平缓,而是兼具走滑与逆冲断裂带的双重特征;(3)研究区壳内低阻层呈现不连续分布,总体表现为南深北浅的构造样式,一般都终止于高阻地块边缘或与逆冲推覆构造的滑脱面相交汇处;(4)清水河裂褶带内发育的高阻地块可能为晚古生代或早中生代发育在元古宙基底上的古隆起,为该区燕山期构造运动提供了深部大地电磁资料证据。     

Mineral characteristics and their geological significance of black shales in southeastern Ordos Basin by X-ray diffraction analysis

X-ray diffraction analysis of black shale of Upper Triassic Member Chang 7 of the Yanchang Formation in southeastern Ordos Basin showed that black shales were deposited in brackish, strongly reducing, semi-deep-deep lacustrine facies, and mainly composed of quartz, feldspar, carbonate （dolomite）, clay minerals （illite and il- lite/smectite） and a certain amount of pyrite. The mineral composition characteristics of this set of black shales are similar to those of highly productive shale gas in North America, for example shallow burial, low clay mineral and abundant brittle mineral, so the strata are conducive to the development of cracks and fractures. Thus, this area is favorable for shale oil/gas exploration and development.     

Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS

Inductively coupled plasma mass spectrometry(ICP-MS) has become a powerful tool for providing reliable analytical results in many laboratories around the word. In this study, the mixture of HF and HNO3 acids in high-temperature and high-pressure closed-vessel digestion technique were used to decompose some Chinese reference materials, and thirty seven elements were determined by ICP-MS. Most of the results for Chinese soil reference materials were found to be in reasonable agreement with the reference values, except Cs, Ta, Li, Ge, Zn, Nd, Tb and Ta whose values need to be revised. Their precisions were typically lower than 5% RSD. However, the Precisions of Chinese clay reference materials, especially for GBW03102 and GBW03102a, were significantly different with reference values, probably reflecting the existence of a coarser-grained fraction(70 μm) in samples, and the formation of fluorides in Al-rich samples during sample decomposition by using the mixture of HF and HNO3 acids. Moreover, thirty-seven trace elements covering the mass range from Li to U in four Chinese clay reference materials were firstly provided with good precision and accuracy in this study.     

Paleoclimate and Paleoenvironment of Gonghe Basin, Qinghai-Tibet Plateau, During the Lastdeglacial: Weathering, Erosion and Vegetation Cover Affect Clay Mineral Formation

With the analysis of the sources and formation mechanism of the clay minerals in the sediment core from the Dalianhai lake in the Gonghe Basin,northeastern Tibet-Qinghai Plateau,clay mineral composition proxies,grain-size and carbonate contents have been employed for high-resolution study in order to reconstruct East Asian Summer Monsoon （EASM） over the northeastern Tibet-Qinghai Plateau during the lastdeglacial.The study also extended to establish a relationship between vegetation cover changes and erosion during the last 14.5 ka with pollen record and clay mineral proxies.Smectite/kaolinite and smectite/（illite＋chlorite） ratios allow us to assess hydrolysis conditions in lowlands and/or physical erosion process in highlands of the Gonghe Basin.Before 12.9 Cal ka BP,both mineralogical ratios show low values indicative of strong physical erosion in the basin with a dominant cold and dry phase.After 12.9 Cal ka BP,an increase in both mineralogical ratios indicates enhanced chemical weathering in the basin associated with a warm and humid climate.The beginning of Holocene is characterized by high smectite/（illite＋chlorite） and smectite/kaolinite ratios that is synchronous as with deposition of many peat laminae,implying the best warm and humid conditions specifically between 8.0 to 5.5 Cal ka BP.The time interval after 5.0 Cai ka BP is characterized by a return to high physical erosion and low chemical weathering with dry climate conditions in the basin.Comparing variations of clay mineral assemblages with previous pollen results,we observe a rapid response in terms of chemical weathering and physical erosion intensity to a modification of the vegetation cover in the basin.     

岩石物理化学性质对泰宁丹霞洞穴的形成制约

泰宁丹霞红层由铁钙质混合胶结的较松散固结红色砂砾岩构成,岩石胶结物中CaCO3含量较高,抗压强度极低、孔隙度和含水性均较高。当岩石遇水湿润或浸泡时,或者生物风化过程中受到各种动植物分泌的有机酸作用,岩石胶结物中CaCO3易溶解流失,促使丹霞红层进一步软弱松散。冬季水结冰之后体积会膨胀,所以岩层表面产生片状裂隙。通过裂隙的毛细管效应,孔隙-裂隙水由岩石内部向结冰的表面扩散,在表面张力作用下水呈表面积最小的球状。春季化冻时岩石沿球形片状裂隙自由剥落的片状风化,圆球形洞穴开始形成,随着四季交替,年复一年,间歇性结冰和融化过程,使得洞穴逐渐扩大,形成泰宁丹霞各种形态的洞穴奇观。