Screening Effect of the Diffusive Boundary Layer in Sediments of Lake Aha in the Suburbs of Guiyang City,Guizhou Province

The redox cycle of iron and manganese is a major geochemica process at the boundary layers of lake sediments.Lake Aha,which lies in the suburbs of Guiyang City,Guizhou Province,China,is a medium-sized artificial reservoir with seasonally anoxic hypolimnion,Long-term sedimentary accumulation of iron and manganese resulted in their enrichment in the upper sediments,In the anoxic season,Fe^2 and Mn^2 ,formed by diological oxidation,would diffuse up to overlying waters from sediments.However,the concentration of oxidation,would diffuse up to overlying waters from sediments,However,the concentration of Fe^2 increased later and decreased earlier than that of Mn^2 .Generally,sulfate reduction occurred at 6 cm below the sediment-water interface.Whereas,in the anoxic season.the reduction reached upper sediments,inhibiting the release of Fe^2 ,The Fe concentration of anoxic water is quickly decreased from high to low as a result of reduction of the suplhur system.     

关于风化作用涵义的探讨

风化作用是指受太阳能，大气，大气水影响的地球物理，地球化学，生物化学的综合作用，使一部分物质溶解淋失，另一部分物理残留，低价元素矿物氧化成高价元素矿物，形成氧化带（风化带），过去只知道范围只包括“暴露在地表面”这一部分，没有包括地表面以下的“氧化改造带”由于两者都是大气水（天水）组成。其物，化性质相同，都含游离ＣＯ２，Ｏ２气体，从地球化学的意义来说，实际是在酸性条件下氧化作用，这种大气水中除了含有     

生物兼容水基磁流体的制备和性质

用天冬氨酸和谷氨酸化学吸附在纳米四氧化三铁粒子表面，制备得到强生物亲合性的水基磁流体。这种磁流体在磁性药物载体、磁共振造影剂和磁高热治疗肿瘤等领域有良好的应用前景。用体系的电导和旋光度参数表征了两种氨基酸化学吸附在磁粒子表面的过程，研究了酸度、氧化钠浓度、天冬氨酸和谷氨酸的吸附等因素对磁流体的磁性和稳定性的影响。磁测量表明，该磁流体对空气较敏感，60天后饱和磁化强度衰减17％；若保存在磨口瓶中，60天后饱和磁化强度基本不变，可应用于生物医药中。     

中国稻田甲烷产生和排放研究 Ⅰ.产生和排放机理及其影响因子

综合论述了近 2 0年来中国稻田甲烷排放的研究状况 ,包括中国稻田甲烷排放通量的观测 ,稻田甲烷生成的生物学机理及产生、转化、传输的机理研究 ,稻田甲烷排放的影响因子 ,主要介绍了稻田甲烷产生和氧化过程、影响甲烷排放的因子     

电吸附找矿方法

电吸附找矿方法是找隐伏矿的新方法。它是指通过物理化学手段来发现后生地球化学异常的找矿方法。它是建立在异常元素地球化学理论和野外地电提取法的理论基础之上。利用电吸附找矿方法在一些已知矿床进行找矿效果试验,获得了很好的效果,说明了该方法找矿的有效性。     

二连盆地可地浸砂岩型铀成矿的再认识

笔者从铀成矿条件入手 ,分析了二连盆地在基底演化期、含矿建造形成期以及后生改造成矿期各阶段对可地浸砂岩型铀矿的控制作用 ,认为二连盆地在含矿建造形成期是由众多分割性强的 ,构造演化和沉积变迁自成体系 ,并具有多物源、近物源特点的小凹陷所组成。同时 ,综合其他控制砂岩型铀矿的因素 ,确定了二连盆地是以发育潜水 层间氧化带砂岩型铀矿为其主要成矿类型 ,且矿床规模以中、小型为主 ,具有成群成带产出的特点。     

沸石在水环境治理中的应用现状与前景

文章叙述了沸石的基本结构以及吸附、离子交换特性，总结了近年来国内外有关沸石在水环境保护方面的研究与应用成果，提出了沸石在今后的水环境保护和改善方面将具有广泛的应用前景。     

重金属迁移转化模型研究

大量重金属污染物迁移转化的现象和研究成果都表明重金属以泥沙颗粒为载体迁移转化,描述重金属在天然水体中的迁移转化必须紧紧抓住泥沙颗粒运动及重金属与泥沙之间的转化关系进行.为此在对现有的重金属迁移转化数学模型进行概括分类的基础上,根据水沙运动与污染物相互作用关系,分析了泥沙颗粒运动及重金属吸附解吸不平衡过程,并结合水沙数学模型,建立了重金属迁移转化的耦合模型.同时在模型合理性分析的基础上,对模型进行了计算分析,分析表明模型能够合理地反映重金属污染物在水体中的迁移转化过程.     

Sorption Characteristics of Rare Earth Element Eu^3＋ onto Silica-Water Interfaces Studied by Fluorescence Spectroscopy

The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ～1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=～5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献   

Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.