Bauxite Deposits in China

Bauxite deposits in China,rangin in age from Late Paleozoic to Cenozoic ,are distributed mainly in Shanxi,Shandong Henan,Guizhou,Guangxi and Yunnan.Based on stratigraphic relations they can be clas-sified as 6 types:inter-system marine,inter-system continental,intra-system marine,intra-system continent-tal,weathering lateritic and weathering accumulation types.But in terms of depositional environments,only four types are distinguished,I.e.the marine deposits,continental deposits,lateritic deposits and weath-ering-accumulation deposits.These deposits have been formed in two steps:firstly,the depression of paraplatform or front basin margins in paleocontinents and secondly,the development of littoral-lagoons on the eroded surface of karstified carbonate bedrocks.The aluminum may have been derived from the carbonate rocks with which the ores are associated,or from adjacent aluminosilicate rocks.     

韭菜地等地的新生代玄武岩及其超镁铁岩包体的岩石学研究

韭菜地和鸡笼山两地的玄武岩为新生代的火山锥体,主要岩石为碧玄岩和碱性橄榄玄武岩,其中含有较丰富的超镁铁岩包体。玄武质岩石属碱性系列的钾质亚系,SiO_2不饱和,Al_2O_3较低且富含K、Ti和P等不相容元素,具有Al_2O_3/CaO值较高、M值在60—70之间、固结指数近于40、熔融程度低(4％)等特征,表明玄武质岩石是地幔橄榄岩低度熔融的产物。超镁铁岩包体中易熔组分与不饱和型包体组分相近,其矿物化学特征为:橄榄石的Fo值和斜方辉石的En值较低,单斜辉石的Al_2O_3、TiO_2和Na_2O较高,表明包体相对地富集易熔组分,与原始地幔组分相似。估算包体的矿物平衡温度和压力分别为1050℃和21.6×10~3Pa。     

铝—铬黑T—OP配合物双波长光度法研究及应用

本文对铝-铬黑T-OP体系进行了研究,发现在pH6时形成紫红色配合物,配合物至少稳定一周。以试剂空白作参比在波长625与688mm处分别出现正负吸收峰,两峰之和在5—80/μg/100ml范围与铝量呈线性关系。铝与铬黑T的组成比为1:3,表观摩尔吸光系数为5.3×10~4。而铁的配合物在628和688mm处吸收值相等,基于此测定铝时可消除铁的干扰。本法重现性好,灵敏度适中,可作为硅酸盐矿物中测定铝的例行方法。     

离子色谱法快速测定钙和镁

在Dionex 4000i离子色谱仪上,用5m mol/L HCl/1m mol/L乙二胺为淋洗液,通过DionoxHPIC-CG3柱快速分离和测定钙和镁。钙和镁的保留时间分别为2.59和1.29分,检测限分别为0.02和0.012μg/ml,线性范围从检测限起分别达200和50μg/ml范围。用该法测定了矿泉水中的钙和镁,平均回收率分别为98.8％和104.4％。