K—Ar Geochronology and Evolution of Cenozoic Volcanic Rocks in Eastrn China

Cenozoic volcanic rocks widespread in eastern China constitute an important part of the circum-Pacific volcanic belt.This paper presents more than 150K-Ar dates and a great deal of petrochemical analysis data from the Cenozoic volcanic rocks distributed in Tengchong,China‘s southeast coast,Shandong,Hebei,Nei Monggol and Northeast China.An integrated study shows that ubiquitous but uneven volcanic activities prevailed from the Eogene to the Holocene,characterized as being multi-eqisodic and multicycled.For example,in the Paleocene(67-58Ma),Eocene(57-37.5Ma),Miocene(22-18,16-19Ma),Pliocene(8-3Ma),and Early Pleistocene-Middle Pleistocene(1.2-0.5Ma) there were upsurges of volcanism,while in the Oligocene there was a repose period.In space,the older Eogene volcanic rocks are distributed within the region or in the central part of the NE-NNE-striking fault depression,while the younger Neogene and Quaternary volcanic rocks are distributed in the eastern and western parts.Petrologically,they belong essentially to tholeiite-series and alkali-series basalts,with alkalinity in the rocks increasing from old to youg.The above regularities are controlled by both global plate movement and regional inherent tectonic pattern.     

Experimental Studies of the Solubility of Cassiterite and the Extraction of Tin from Granitic Melts

Experiments indicate that the solubility of cassiterite can be enhanced by increasing either acidity or alkalinity in hydrothermal solutions as a consequence of the duality of tin.The minimum solubility of cassiterite is found in neutral solutions.F-and CL-coordination compounds of Sn can alternate with hydroxyl coordination compounds with changing pH in the solutions.In this case,F^- and Cl^- and OH^- can be substituted with each other.The dissolution reaction of cassiterite is of reducing nature.High temperature and acidic reducing environment are favorable for the dissolution of cassiterite and the trans-port of Sn^2 compounds in fluids or solutions.High-temperature fluoride and chloride fluids can all dissolve,extract and enrich Sn to form F^- and /or Cl-coordination compounds,However,Fplays a more important role than Cl.F-coordination compounds are more stable and efficient than Cl-coordination compounds during the transport an enrichment of Sn in melts or solutions.The solubili-ty of cassiterite and the amount of Sn extracted from granitic melt depend not only on T,P,pH and Eh in the fluids or solutions,but also on the amounts of dissociated F^- and Cl^- in the fluids.     

用β—γ1.46Mev测定含钾样中的铀

在β-γ综合测铀基础上,用大晶体、大道宽,突出~(40)K的11.46MeVγ贡献,使钾的铀当量趋近零值,可以实现含钾样中铀的准确测定。     

韭菜地等地的新生代玄武岩及其超镁铁岩包体的岩石学研究

韭菜地和鸡笼山两地的玄武岩为新生代的火山锥体,主要岩石为碧玄岩和碱性橄榄玄武岩,其中含有较丰富的超镁铁岩包体。玄武质岩石属碱性系列的钾质亚系,SiO_2不饱和,Al_2O_3较低且富含K、Ti和P等不相容元素,具有Al_2O_3/CaO值较高、M值在60—70之间、固结指数近于40、熔融程度低(4％)等特征,表明玄武质岩石是地幔橄榄岩低度熔融的产物。超镁铁岩包体中易熔组分与不饱和型包体组分相近,其矿物化学特征为:橄榄石的Fo值和斜方辉石的En值较低,单斜辉石的Al_2O_3、TiO_2和Na_2O较高,表明包体相对地富集易熔组分,与原始地幔组分相似。估算包体的矿物平衡温度和压力分别为1050℃和21.6×10~3Pa。     

离子色谱法快速测定钙和镁

在Dionex 4000i离子色谱仪上,用5m mol/L HCl/1m mol/L乙二胺为淋洗液,通过DionoxHPIC-CG3柱快速分离和测定钙和镁。钙和镁的保留时间分别为2.59和1.29分,检测限分别为0.02和0.012μg/ml,线性范围从检测限起分别达200和50μg/ml范围。用该法测定了矿泉水中的钙和镁,平均回收率分别为98.8％和104.4％。