我国主要金矿类型中黄铁矿"电子-空穴心"特征及影响因素

通过对我国主要金矿类型中黄铁矿导电类型的分析表明，黄铁矿“电子。空穴心”与金矿床的成因类型具有密切的联系，华北地台太古代变基性火山岩中的金矿床(绿岩带型)、热水淋滤型(卡林型)金矿床，黄铁矿多为单一的“电子心”型导电。大多数产于中生代岩体中的中深脉状金矿、火山次火山岩中的金矿床，黄铁矿为“电子心”、“空穴心”混合型导电，个别的为单一的“空穴心”导电。黄铁矿的“电子．空穴心”受杂质成分As、Co、Nl在成矿背景中的丰度，进入黄铁矿品格中的替代能力的差异、补偿类质同象现象、成矿时温度以及．f(S2)等多种因素的耦合制约。     

山东莒南-日照地区榴辉岩与围岩的接触关系及其地质意义

对山东莒南日照地区榴辉岩与不同围岩的接触关系进行研究发现：包裹榴辉岩的斜长角闪岩有窄的细粒边；榴辉岩在变质地层及超镁铁岩中呈夹层状产出，与超镁铁岩相伴产出的榴辉岩有角闪石化边；变质含霓石花岗岩及闪长玢岩侵入榴辉岩。认为榴辉岩是“就地的”．其原岩类型较复杂。其形成时代可能为新元古代。     

西秦岭三个典型金矿床稳定同位素地球化学特征

据八卦庙金矿、李坝金矿、小沟里金矿稳定同位素研究,金矿床δ34S比正常沉积岩变化范围窄,比岩浆-火山岩型矿床宽,硫源是海水硫酸盐还原硫与深部热液来源硫所组成的混合硫。石英包裹体流体氢、氧同位素分布于岩浆水、大气降水的重叠过渡区,更靠近岩浆水区,岩浆水的同位素特征更明显。八卦庙金矿石英脉3He/4He高于地壳3He/4He值(n×10-8),低于地幔3He/4He值(n×10-5),为壳-幔混合源。上述同位素地球化学证据表明,金成矿与岩浆岩有一定的成因关系。岩浆岩与金矿床空间关系密切,矿区内脉岩发育,脉岩为矿体的上下盘。含矿岩石中发育斑点构造,斑点为黄铁矿、磁黄铁矿、毒砂、绿泥石、石英、绢云母、黑云母、堇青石、红柱石、电气石、碳酸盐等热变质矿物和热液交代矿物,表明花岗岩为成矿提供热动力。据八卦庙金矿、李坝金矿、小沟里金矿稳定同位素地球化学研究,结合成矿地质背景分析和区域成矿地质特征对比,认为凤太、西成、礼岷地区金矿与微细浸染型(卡林型)金矿有明显的差别,该区金矿类似于岩浆热液矿床。     

Hydrothermal Mineralization on the Mesoproterozoic Passive Continental Margins of China： A Case Study of the Langshan-Zha＇ertaishan Belt, Inner Mongolia, China

Most ore-forming characteristics of the Langshan-Zha‘ertaishan hydrothermal exhalation belt, which consists of the Dongshengmiao, Huogeqi, Tanyaokou and Jiashengpan large-superlarge Zn-Pb-Cu-Fe sulfide deposits, are most similar to those of Mesoproterozoic SEDEX-type provinces of the world. The characteristics include: (1) All deposits of this type in the belt occur in third-order fault-basins in the Langshan-Zha‘ertaishan aulacogen along the northern margin of the North China Platform; (2) these deposits with all their orebodies hosted in the Mesoproterozoic impure dolomite-marble and carbonaceous phyllite (or schists) have an apparent stratabound nature; ores display laminated and banded structures, showing clear depositional features; (3) there is some evidence of syn-sedimentary faulting, which to a certain extent accounts for the temporal and spatial distribution and the size of the orebodies in all deposits and the formation of intrabed conglomerates and breccias; (4) they show lateral and vertical zonation of sulfides; (5) The Cu/(Pb Zn Cu) ratio of the large and thick Pb Zn Cu orebodies gradually decreases from bottom to top; and (6) barite is interbedded with pyrites and sometimes with sphalerite. However, some characteristics such as the Co/Ni radio of the pyrites, the volcanism, for example, of the Langshan-Zha‘ertalshan metallogenic belt, are different from those of the typical SEDEX deposits of the world. The meta-basic volcanic rock in Huogeqi, the sodic bimodal volcanic rocks in the Dongshengmiao and potassic bimodal-volcanic rocks with blastoporphyfitic and blasto-glomeroporphyritic texture as well as blasto-amygdaloidal structure in the Tanyaokou deposits have been discovered in the only ore-bearing second formation of the Langshan Group in the past 10 years. The metallogeny of some deposits hosted in the Langshan Group is closely related to syn-sedimentary volcanism based on the following facts: most of the lead isotopes in sphalerite, galena, pyrite, pyrrhotite and chalcopyrite plot on both sides of the line for the mantle or between the lines for the mantle and lower crust in the lead isotope composition diagram; cobalt content of some pyrites samples is much higher than the nickel content (Co/Ni= 11.91-12.19). Some volcanic blocks and debris have been picked out from some pyritic and pyrrhotitic ores. All Zn-Pb-Cu-Fe sulfide orebodies in these deposits occur in the strata overlying metamorphic volcanic rocks in the only ore-bearing second formation. In the Jiashengpan deposit that lacks syn-sedimentary volcanic rocks in the host succession only Pb and Zn ores occur without Cu ore, but in the Dongshengmiao, Tanyaokou and Huogeqi deposits with syn-sedimentary volcanic rocks in the host succession Cu ores occur. This indicates a relatively higher ore-forming temperature. The process of synsedimentary volcanic eruption directly supplied some ore-forming elements, and resulted in secular geothermal anomaly favorable for the circulation of a submarine convective hydrothermal system, which accounts for the precipitation of deep mineralizing fluids exhaling into anoxidic basins along the syn-sedimentary fault system in the Langshan-Zha‘ertai rift. The Dongshengmiao, Tanyaokou, and Huogeqi deposits hosted in the Langshan Group appear to be a transitional type of mineral deposit between SEDEX and VMS-types but with a bias towards SEDEX, while the Jiashengpan deposit hosted in the Zha‘ertai Group is of a characteristic SEDEX type. This evidence, together with other new discoveries of Mesoproterozoic volcanic rocks and the features of lithogeny and metallogeny of the Bayun Obo deposit in the neighborhood emphasize the diversity, complexity and uniqueness of the Mesoproterozoic Langshan-Zha‘ertal-Bayun Obo ore belt.     

赵家堡子金矿床黄铁矿矿物学研究

赵家堡子金矿床金属矿物以黄铁矿为主，黄铁矿分为自形立方体，自形-半自形、半自形-他形立方体和五角十二面体及它们的聚形几种形态。不同形态的黄铁矿与金矿化关系不同，从围岩-矿体黄铁矿的形态特征、热电性、主要成分和微量元素、稀土元素、同位素及包体几方面进行对比研究的结果表明，黄铁矿标型特征不但指示矿床成因，而且是重要的找矿标志。     

西藏桑日县陈坝铜金矿床地质特征及成因探讨

冈底斯成矿带是西藏乃至中国的一条重要的铜多金属成矿带，区内已发现厅宫、驱龙、甲马等大型、特大型斑岩铜矿及克鲁、冲木达等中型以上铜矿；矿床类型有斑岩型、火山热液型、接触交代(夕卡岩)型等。陈坝铜金矿床处于克鲁-冲木达成矿远景区内。矿床成因为夕卡岩型，也有火山热液型。     

松辽盆地敖古拉断裂的封烃泄水作用

敖古拉断裂位于齐家-古龙坳陷生油气区向西运移的指向上，且其走向与油气运移方向垂直。该断裂自基底一直断到第四系，具同生正断特征。通过封堵率计算研究表明，该断裂的侧向封烃能力在姚家组和泉头组地层中为中等，在嫩江组和青山口组地层中较好。通过断面压力计算发现，该断裂垂向封闭性在浅部差，深部好；在断裂走向上断裂中部差，向两端逐渐变好。通过地层水矿化度和变质系数等参数的分布规律及一系列折算水位剖面图的分析发现，该断裂对水是不封闭的，并且是盆地西缘大气渗入水向东流动（向心流）及齐家-古龙坳陷沉积压实水向西流动（离心流）的共同泄水带。所以，该断裂是一条封烃泄水断裂。敖古拉断裂封烃泄水的主要机理是毛细管压力作用。由于敖古拉断裂的封烃泄水作用，使其对齐家-古龙坳陷向西运移的油气起到了一定的屏障作用。     

EPR 9-10°N热液烟囱体的结构特征与生长历史

对Alvin深潜器采集的4个EPR9-10°N热液烟囱体样品进行了结构和矿物地球化学研究,建立了不同烟囱体的形成环境和生长历史. EPR9-10°N热液烟囱体在形态、结构和组成上的差异, 反映了不同的两类热液沉积环境: 类型Ⅰ烟囱体形成于高温、较强酸性、强还原性热液集中流环境, 类型Ⅱ烟囱体则形成于相对低温、较弱酸性、富锌的还原性热液环境. 类型Ⅰ烟囱体的生长始于硬石膏的形成, 在此基础上, Cu-Fe-Zn硫化物在烟囱内各方向上的交代和沉淀过程决定了类型Ⅰ烟囱体的最终结构. 早期、中期、晚期硫化物形成阶段的建立恢复了类型Ⅰ烟囱体形成过程中温度变化和化学反应变化的历史. 与类型Ⅰ烟囱体不同, 类型Ⅱ烟囱体早期黄铁矿淬火结晶和闪锌矿结晶为烟囱体的生长提供了基础.     

藏南定结铁镁质麻粒岩矿物化学、PTt轨迹和折返过程

定结铁镁质麻粒岩出露于藏南拆离系和申扎-定结伸展构造系交汇处的高喜马拉雅岩系糜棱岩化片麻岩内, 以不同规模的透镜状包体沿着糜棱面理分布, 主要岩石类型包括退变石榴石斜长辉石岩、石榴石二辉麻粒岩和辉石斜长角闪岩等. 详细的岩相学分析表明这些铁镁质麻粒岩经历了至少四个阶段的变质演化, 早期形成了石榴石+单斜辉石+石英(榴辉岩)矿物组合(M1)、早期降压分解形成斜长石+单斜辉石后成合晶构成的高压麻粒岩矿物组合(M2)、晚期降压分解形成的斜长石+单斜辉石+紫苏辉石后成合晶构成的麻粒岩相矿物组合(M3)和最后降温水化形成的斜长石+角闪石退变质矿物组合(M4). 详细的矿物电子探针成分分析表明早期石榴石和单斜辉石(M1和M2)矿物成分与B类和C类榴辉岩同类矿物的成分特征相似, M3单斜辉石与麻粒岩相单斜辉石的成分特征一致. 早期残晶矿物组合形成于榴辉岩相(M1), 早期降压分解(M2)反应发生于1.35~1.48 GPa, 625~675℃, 降压分解的M3麻粒岩相变质阶段矿物组合形成于0.7~0.95 GPa, 775~900℃, M4退化变质的斜长石+角闪石矿物组合形成于4.0~7.5 GPa、660~700℃, 记录了俯冲增厚－构造隆升的PTt轨迹. 矿物化学特征和不同阶段变质作用的P-T条件表明早期经历了榴辉岩相变质作用. 折返过程中经历了榴辉岩相构造隆升、榴辉岩-高压麻粒岩相到麻粒岩相均衡隆升和伸展隆升的三阶段折返过程.