A Closure Study of Aerosol Hygroscopic Growth Factor during the 2006 Pearl River Delta Campaign

Measurements of aerosol physical, chemical and optical parameters were carried out in Guangzhou, China from 1 July to 31 July 2006 during the Pearl River Delta Campaign. The dry aerosol scattering coefficient was measured using an integrating nephelometer and the aerosol scattering coefficient for wet conditions was determined by subtracting the sum of the aerosol absorption coefficient, gas scattering coefficient and gas absorption coefficient from the atmospheric extinction coefficient. Following this, the aerosol hygroscopic growth factor, f(RH), was calculated as the ratio of wet and dry aerosol scattering coefficients. Measurements of size-resolved chemical composition, relative humidity (RH), and published functional relationships between particle chemical composition and water uptake were likewise used to find the aerosol scattering coefficients in wet and dry conditions using Mie theory for internally- or externally-mixed particle species [(NH₄)₂SO₄, NH₄NO₃, NaCl, POM, EC and residue]. Closure was obtained by comparing the measured f(RH) values from the nephelometer and other in situ optical instruments with those computed from chemical composition and thermodynamics. Results show that the model can represent the observed f(RH) and is appropriate for use as a component in other higher-order models.     

内蒙古额仁陶勒盖银矿床石英的矿物标型特征研究

对额仁陶勒盖银矿床中石英的稀土元素，包裹体测温、包裹体成分、同位素、化学成分及红外光主普学特征等进行了研究，认为额仁陶勒盖银矿床属于浅成中温热液成因，早期成矿流体为岩浆热液，晚期成矿流体天水臧主导地位，矿床形成于弱碱性条件下及还原环境中。石英的红外光谱学特征、石英的化学成分及形态是该银矿床重要的找矿矿物学标志。     

Study on the geochemical characteristics of arc-volcanic rocks in the Chiang Rai-Lampang belt of northern Thailand

On the basis of the petrographic characteristics, rock assemblages, petrochemistry, REEs, trace elements and geotectonic settings, the authors described the characteristics of continental marginal arc-volcanic rocks in the Late Permian-Early Triassic (P2-T1) volcanic rocks distributed on the eastern side of the ocean-ridge/oceanic island basalts in the Chiang Mai belt. The volcanic rock assemblage is basaltic andesite-andesite-rhyolite. The volcanic series is dominated by the calc-alkaline series, with the tholeitic series coming next. The chemical composition of the volcanic rocks is characterized by high Al2O3; the REE distribution patterns are of the LREE-enrichment rightward incline type; the large cation elements are highly enriched, and the volcanic rocks are generally enriched in U and Th and depleted in Ti, Cr and P. The petrochemical plot falls within the field of island-arc volcanic rocks, in consistency with the projected points of continental marginal arc-volcanic rocks in the Lancangjiang belt. These continental mar-ginal arc-volcanic rocks, together with ocean-ridge/oceanic island-type volcanic rocks in the Chiang Mai belt, con-stitute the ocean-ridge volcanic rock-arc magmatic rock belts distributed in pairs, indicative of eastward subduction of the oceanic crust in the Chiang Mai belt. This result is of great importance in exploring the evolution of the pa-leo-Tethys in the Chiang Mai belt.     

2004年北京秋季大气颗粒物的化学组分和来源特征

2004年9月在北京城区进行了大气颗粒物采样,样品用PIXE方法进行了分析,得到了20种元素的浓度及其谱分布。并对北京颗粒物的谱分布、富集因子和来源进行了分析研究。发现K元素浓度分布呈细粒态单峰谱分布,细粒态K富集因子较高,表明了生物质燃烧的主要贡献。因子分析结果还表明,土壤尘、生物质燃烧、煤烟尘、工业源和汽车尾气排放源对秋季北京局地排放源有明显贡献。     

青龙山超高压变质榴辉岩绿帘石化学成分与流体包裹体特征

青龙山超高压变质榴辉岩中的绿帘石经历了四个演化阶段：早期绿帘角闪岩相进变质阶段形成的绿帘石，其化学成分以含铁高为特征，Fe2O3为14．796～17．84％，XFe=0．413～0．486，而CaO和Al2O3含量较低；柯石英榴辉岩相变质阶段和石英榴辉岩相变质阶段形成的绿帘石，其化学成分呈现连续变化，核部相对富Fe2O3，为11．933～12．993％，XFe=0．322-0．358，而CaO和Al2O3含量低，主要形成于柯石英榴辉岩相变质阶段；边部Fe2O3的含量低，为9．628-10．138％，XFe=0．275～0．286，而CaO和Al2O3的含量高，主要形成于石英榴辉岩相退变质阶段；晚期退变质角闪岩相阶段形成的绿帘石，其化学成分与绿帘角闪岩相变质阶段相似，也以富含Fe2O3为特征，XFe=0．433。绿帘石化学成分的变化反映了苏鲁超高压变质带快速俯冲快速折返的过程。绿帘石中存在三种不同盐度的含Mg^2＋、Fe^2＋等金属阳离子的NaCl水溶液包裹体，高盐度（22．5wt％NaCl至略大于23．2wt％NaCl）的水溶液包裹体形成于柯石英榴辉岩相变质阶段，中高盐度（12．6-16．0wt％NaCl）的水溶液包裹体形成于石英榴辉岩相变质阶段，而中等盐度（6．4-11．7wt％NaCl）的溶液包裹体形成于角闪岩相退变质阶段。绿帘石中流体包裹体的研究证实超高压变质作用及后期的折返过程中并不存在大规模的流体作用，变质流体的活动限于矿物晶体颗粒范围。     

内蒙白云鄂博矿区H9中火山岩岩石特征及其意义

白云鄂博矿区Ｈ＿９地层岩石被中外学者长期看作是板岩或页岩，经近期研究发现岩性极为复杂。Ｈ＿９地层岩石是一套呈互层产出的粗面岩、流纹岩、流纹英安岩、变辉绿岩、白云岩、石英岩、黑云母岩、钠闪石－长石岩、钠辉石－长石岩、红柱石－黑云母角岩及碳质绢云板岩等。文中详细论述了这些火山岩石的结构构造、矿物成分和岩石化学成分，以及微量元素。对Ｈ＿９地层中火山岩，尤其是粗面质火山碎屑岩的确定，对了解白云鄂博矿床的成因和白云鄂博群形成的地质背景有重要意义。     

中国海及大陆架沉积物标准物质系列评介

自20世纪90年代末以来,在有关国家专项的支持下,中国先后研制了分别取自黄海、东海和南海的共9个大陆架沉积物地球化学标准物质,基本构成了一个比较有代表性的中国海及大陆架沉积物标准物质系列,为中国海洋国土及专属经济区调查研究工作提供了有力技术支撑.本文简介了这些标准的研制背景、概况,着重评介了这些标准物质的特点,特别说明了该标准物质系列在海洋地质调查与研究中应用及在地质分析技术发展上的意义.     

黑色电气石矿物组成与红外辐射特性的关系

作者对产自云南马关－麻粟坡矿带、广西钟山八步矿区的黑色电气石进行了矿物组成及化学成分的分析测试。实验表明，不同矿点黑色电气石的矿物组成和化学成分存在明显差异，化学成分对红外辐射特性存在一定影响，氧化镁含量较高的镁电气石具有高的红外法向比辐射率。论文对电气石的化学成分与成因的相互关系进行了讨论，为合理选矿，有效利用黑色电气石资源提供了实践和理论依据。     

缅甸 Mong Hsu 红宝石的颜色成因

摘 要 Mong Hsu 红宝石原石具有独特的暗蓝至紫色的核心色带‚即黑心。这种黑心可以借 助热处理法加以去除‚从而改善其颜色。通过对 Mong Hsu 红宝石化学成分及可见光谱的研 究‚阐明了其颜色成因与化学成分的关系‚分析了蓝紫色调的形成机理‚这些均为红宝石的 热处理提供了理论依据。     

长江河源区的河水主要元素与Sr同位素来源

长江源区河水化学成分来自雨雪、蒸发盐岩、碳酸盐岩和硅酸盐岩。主要支流楚玛尔河、北麓河的主要阳离子为Na 、Ca2 和Mg2 ,占阳离子总量的97%以上.Ca Na,Mg Na,K Na的比值较低,87Sr 86Sr为0 709180±20～0 710280±11,河水成分以蒸发岩类溶解为主。发源于唐古拉山北坡的长江源头,及其支流主要阳离子为Ca2 ,Mg2 ,Na 占阳离子总量的97%以上,Ca Na,Mg Na,K Na的比值较楚玛尔河等河流高,87Sr 86Sr为0 708954±20～0 710455±18,表现为以碳酸盐岩和硅酸盐岩的溶解为主。计算表明,长江河源区河水中主要化学成分来自蒸发岩中Na 和Cl-,在河流水化学成分中占比例最大,长江河水中Cl-含量从河源区向下游明显逐渐减小,反应出河源区高寒干旱环境下河流蒸发岩的化学侵蚀作用较强的特征。