Ab Initio Prediction of ^29Si-NMR Chemical Shifts

The ability of several ab initio models to predict experimental 29Si-NMR chemical shift is examined. The shielding values of trimethylsilyl chloride (A), t-butyldimethylsilyl chloride (B) and allyltrimethylsilane (C) are calculated by GIAO, CSGT and IGAIM methods, using HF/6-31G^*, B3LYP/6-31G^* , HF/6-311 G^**, B3LYP/6-311 G^** and MPWlPW91/6-311 G^** models respectively. The 29Si chemical shifts calculated by GIAO method using HF/6-311 G^** model are highly in agreement with those obtained experimentally. All of the models above reproduce the trends of chemical shifts in all cases studied, suggesting that the models are of practical value.     

银盘恒星运动学和化学丰度与银河系结构

大样本的银盘恒星的运动学数据和元素丰度特征是研究银河系结构及演化，尤其是银盘形成和演化的2个重要探针。本文首先介绍了银河系的总体结构特征，然后较详细的综述了以上2个探针的重要性。对我国LAMOST项目在研究银河系结构方面，尤其是银盘的形成和演化方面的能力作了合理的分析。     

台湾地层检讨(续)

所谓‘大寮层’者,以页岩与砂岩之交互层为主,厚约350公尺,在其上部,砂岩发育较佳,而在山下部则反是。砂岩往住带石灰质并含有化石,尤其在上部有富含Ditrupa sp之灰质的砂岩发现,所谓Ditrupa化石带是也。此外尚有下列之化石发现:     

层序-岩相古地理图及其编制

在中国岩相古地理研究历史简要回顾基础上,以层序地层学理论为指导,就如何编制层序-岩相古地理图进行了讨论,首先是编图单元的选择,一是以层序内的体系域为成图单元,二是以相关界面为成图单元.具体方法是在对所研究的层位进行精细的层序地层分析的基础上,进行层序对比,建立等时地层格架.在上述基础上系统编制不同层序内的各体系域或有关界面沉积时的古地理图.以此方法所编制的层序-岩相古地理图具有重要的理论和现实意义,主要表现为更具有等时性、成因连续性和实用性,能更好地反映一个地区在统一地质作用场中的各种地质信息和综合效应;可以揭示出一些新的地质现象,对于覆盖区相带展布及变化具更合理的预测性.进而以中国南方二叠纪为例,在层序划分、对比的基础上,系统编制了一个完整的海平面变化旋回条件下的层序-岩相古地理图,并描述了其平面展布特点.     

The Geologic Time Scale and the Italian stratigraphic record

The construction of the Geologic Time Scale (GTS) is a titanic scientific challenge that has been under way for two centuries and will require much dedicated effort in the future. Italy preserves a paramount stratigraphic record of Mesozoic and Cenozoic marine sediments that have been significant in the development of the modern GTS. The Italian stratigraphic record has been histori-cally important in introducing and defining the standard Chronostratigraphic Units (CUs) of the Neogene and Quaternary. Pelagic successions from Northern Apen-nines and Southern Alps have been used in the seventies for integrating the late Cretaceous-Paleogene Geomag-netic Polarity Time Scale (GPTS) with planktonic microfossil biostratieraohv and standard CUs. This was a major contribution to the construction of a new gener-ation of GTS based on integrated magnetobiochronol-ogy. The middle Miocene to early Pleistocene marinerecord from Sicily and southern Italy has been funda-mental for establishing the recently developed Astro-nomical Time Scale (ATS). In prospect, there are many potentials still to be exploited in the Italian marine stratigraphic record for implementing the GTS by defin-ing GSSPs of various CUs, improving magneto-biochronology and extending downwards the ATS.     

SORPTION AND DESORPTION CHARACTERISTICS OF CADMIUM BY FOUR DIFFERENT SOILS IN NORTHEAST CHINA

1IN TR O D U C TIO NA s a persistentand toxic pollutant, cadm ium (C d) canresultin m any adverse health effects in a variety oftis-suesand organssuch asthe lung,kidney,urinary,blad-der,pancreas,breast and prostate (SA TA R U G etal.,2003).C adm ium in so…