俯冲带温度条件下橄榄石中硅氧四面体的非谐振动:透射红外光谱研究

橄榄石既是上地幔的主要矿物,又是俯冲板块的主要矿物。在正常地幔温度条件下,橄榄石中原子之间的振动是非谐振动,这已成为学界共识;然而,对于俯冲带的较低温情况,橄榄石中原子之间的振动的非谐性是否重要,目前还没有比较一致的结论。本研究利用透射红外光谱的方法,系统研究了室温下不同厚度橄榄石中硅氧四面体的红外光谱特征,并着重对其在2100~1500cm-1区域形成的二倍频峰/合频峰进行了指认。在此基础上,本研究通过采集不同温度下的透射红外光谱数据(最高温度达约450℃),确立了橄榄石中硅氧四面体的相应基频峰及二倍频峰峰位对温度的依赖性,进而得出其相应红外振动的非谐系数(χ)随温度(T)的变化关系,具体为:χ838=6.37(2)×10-7×T+0.0014(1)及χ993=7.86(3)×10-7×T+0.0015(1),其中温度的单位为℃。外推到600℃时,有χ838=0.0018(1)及χ993=0.0020(2)。这些结果表明,在俯冲带的较低温条件下,橄榄石中硅氧四面体的内部振动的非谐性可能不重要。     

Mangshan Loess in Central China and the Paleomonsoon Variationssince the Last Interglaciation

The Mangshan Yuan is a loess platform on the southern bank of the Yellow River, which is located in northwestern Zhengzhou of Henan Province, China. The typical Zhaoxiayu section of the Mangshan Yuan preserves stratigraphical loess units above S10 with a total thickness of 172.1 m, which includes 15.7 m of the last interglacial paleosol S1, 77.3 m of the last glacial loess L1 that consist of 41.6 m of the late stade L1LL1, 13.2 m of the interstade L1SS1 and 22.5 m of the early stade L1LL2. Based on the age marking points by correlating magnetic susceptibility of the section with the SPECMAP curve, the timescale of the section was constructed, and the average accumulation rate and the resolution of each loess strata over the S2 were subsequently calculated using the     

青藏铁路设计与建设——第六届国际冻土工程会议回顾

The 6^th International Symposium on Permafrost Engineering was successfully held in China in September 2004. About 150 scientists and engineers from 7 countries attended the symposium in Lanzhou on 5～7 September, and about 35 people from 6 countries participated in the field trip along the QinghaiTibet Highway/Railway on 8～13 September and the seminar in Lhasa on 14 September 2004. During the Symposium, the latest progress on permafrost engineering and the surveys, design and construction of the Qinghai-Tibet Railway were exchanged and inspected. Fifty-eight technical papers in English from the Symposium were published in the first volume of the Proceedings of the Symposium, as a supplement of the Journal of Glaciology and Geocryology, before the symposium. About 6 papers from the symposium are published in the second volume in the volume 27(1) of the Journal of the Glaciology and Geocryology, after the symposium. The Qinghai-Tibet Railway (QTR) under construction will traverse 632 km of permafrost, and the engineers are facing unprecedented engineering and environmental challenges. With the QTR under construction and to be completed in 2007, permafrost engineering has become the research focus of permafrost scientists and engineers in China. Many encouraging and promising achievements in permafrost engineering have been obtained during the past three years. However, there are still numerous engineering and environmental problems needing to be solved or resolved. In the discussions, some experts pointed out that methods, such as removal of snow cover on the embankments and toe areas, light-color embankments and side slope surfaces, awnings for shading the solar radiation, hairpin or tilted thermosyphons, could be applied to actively cool the roadbed of the QTR. Some new ideas on utilization of the natural cold reserves were proposed to protect the QTR permafrost roadbed from thawing. Many questions and answers on the survey, design, construction, operations, maintenance and environmental protection were exchanged in situ and in the Lhasa seminar with participation by some major railway designers, regulators and administrators.     

《冰川冻土》征稿简则

正1.本刊是我国冰、雪、冻土和冰冻圈研究领域唯一的学报级学术期刊,积极支持在冰、雪、冻土和冰冻圈及全球变化基础研究和应用研究中具创造性、高水平和面向国民经济建设的新思想、新观点、新方法和新学说;促进国内外学术交流,传播与冰冻圈和全球变化相关的科学知识,为寒区国民经济建设服务.2.本刊刊登的论文、报道和综述内容主要包括:冰、雪、冻土(含人工冻土)的性质、过程及其控制;冰冻圈的资源与环     

扬子东部冶山和山里陈埃达克质侵入岩年代学与地球化学:岩石成因和动力学意义

冶山和山里陈岩体构造上属于扬子地块东部,毗邻郯庐断裂带东侧,主要岩石类型为石英闪长玢岩。它们的单矿物(角闪石,黑云母)40Ar/39Ar坪年龄分别为131.22±0.77 Ma和130.07±0.48 Ma。冶山和山里陈岩体具有与埃达克岩类似的地球化学特征,如w(SiO2)>56%,高Al2O3[w(Al2O3)=14.95%～17.67%]、Sr[w(Sr)=495×10-6～2086×10-6]、Sr/Y(44～159)和La/Yb(26～68),低重稀土元素,如w(Yb)=0.82×10-6～1.56×10-6),w(Y)=9.14×10-6～20.32×10-6,无明显-正Eu异常(δEu=0.90～1.11)。另外,样品普遍具有较高的MgO[w(MgO)=2.01%～4.98%]、IMg(45～71)和Cr[w(Cr)=19.2×10-6～199×10-6]、Ni[w(Ni)=13.8×10-6～58.8×10-6]。它们的Sr-Nd-Pb同位素特征为:(87 Sr/86 Sr)i=0.7059～0.7062,εNd(t)=-14.75～-12.15,(206 Pb/204 Pb)t=16.082～16.847,(207 Pb/204 Pb)t=15.303～15.461,(208Pb/204Pb)t=35.889～36.919。冶山和山里陈埃达克质侵入岩可能是由于扬子与华北地块在三叠纪的碰撞及扬子地块东部的地壳拆离作用,导致下地壳增厚并发生拆沉熔融,岩浆在上升过程中与地幔橄榄岩发生了反应。郯庐断裂带两侧早白垩世时期的埃达克(质)岩可能形成于断裂带早白垩世时期由左行平移向伸展活动转变的阶段,其源动力很可能是受到滨太平洋板块构造的影响。     

羌塘盆地那底岗日地区中侏罗世碳酸盐岩碳、氧、锶同位素与古海洋沉积环境

本文首次利用碳酸盐岩C,O,Sr稳定同位素探讨了羌塘盆地那底岗日地区中侏罗世海洋沉积环境的演变。测试结果表明,该区中侏罗世碳酸盐岩δ     

葛亭煤矿1160采区水文地质条件分析

处于济宁煤田鲁西南断块坳陷区济宁地堑西侧的葛亭矿井,构造类型为中等-复杂型.在分析了矿区水文地质条件的基础上,认为第四系含水层岩组,山西组3煤层顶、底板砂岩裂隙水和奥陶系岩溶水是矿井充水的主要水源,断裂带及陷落柱是充水的主要通道.奥灰水会由于强大的水压力向上冲破煤层至奥灰顶界面之间的压盖隔水层而涌人矿井造成奥灰水底鼓.根据对矿区16煤和17煤层突水系数的分析计算,认为16煤层在-265m以浅区域开采是安全的,17煤层在-220m以浅是安全的.在矿井开采过程中,应加强对陷落柱的观测,对主要断层应留足防水煤柱,加强探放水工作.     

昆仑山北坡岛状冻土区西大滩大型饮用矿泉群成因分析

在对昆仑山北坡岛状冻土区西大滩大型饮用矿泉群水文地质、导水与控水断裂、水化学等方面实地调查和EH-4高频、电测深勘探的基础上,认为矿泉群的补给源为昆仑山玉珠峰一带的现代冰川底部冰雪覆盖融区水、冰雪消融水、大气降水和地表水.补给源水通过具多期活动性的F3和F4正断层组破碎带补给深层地下水.深层地下水在西倾近南北向正断层组F2及F2-1,2的导水断层破碎带富集并继续向北径流,径流至F1南倾活动性逆断层上盘时,形成富水"三角区",并沿F1断层破碎带排泄出地表,是西大滩大型饮用矿泉群形成的主因.     

冷冻管直径对冻土冻结影响规律的试验研究

近年来冻结施工方法越来越多地使用在城市土木工程施工中,但由于受冻土冻结理论基础的缺失和研究方法的局限,长时间以来人们对冻结法的设计始终没有找到较为理想的方案,参数变量选取遇到很大困难,同时在施工阶段没有较为标准统一的技术规范参照,使得该工法的实际应用往往出现工程量浪费、施工混乱和工程质量无保障等情况,而其中冷冻管直径是主要影响参数。通过同轴管土体冻结试验的研究,采用不同直径的冷冻管进行冻结试验,利用Fluent模型分析冻结过程的温度场分布规律,确定了最优冷冻管管径的选择方法,为冻结法的设计及施工提供依据。     

敞开酸溶-电感耦合等离子体光谱法测定钨矿石和钼矿石中微量元素

钨矿石和钼矿石具有丰富的共生或伴生元素,检测共生或伴生元素的含量有利于矿产资源的综合利用.在国家标准方法中钨矿石和钼矿石的共生或伴生元素含量是按元素分别检测,效率很低.本文在敞开体系中用盐酸+硝酸+氢氟酸+高氯酸消解样品,以7％盐酸溶解盐类,电感耦合等离子体发射光谱同时测定钨矿石和钼矿石中铋、钴、铜、锂、镍、磷、铅、锶、钒、锌等10种微量元素.选定了各元素的分析谱线和光谱级次,采用离峰背景校正法消除背景干扰,干扰元素校正系数法消除元素间的谱线重叠干扰.方法检出限为1.43 ～ 18.8 μg/g,加标回收率为90％ ～ 110％.经钨矿石和钼矿石标准物质分析验证,测定结果与标准值基本吻合,方法精密度(RSD,n=10)小于8％.该方法克服了碱熔引入大量碱金属元素以及可能引入杂质的缺陷,又不用处理钨酸和钼酸沉淀,能快速测定钨矿石和钼矿石中微量共生或伴生元素.