催化光度法测定痕量铁的新指示反应研究

研究了在表面活性剂胶束增溶增敏下，以邻菲罗啉为活化剂，痕量铁催化抗坏血酸还原２－羟基－４－溴苯基氮氨基偶氮苯的褪色反应及动力学条件，探讨了反应机理，建立了高选择性测定痕量铁的新方法，本法线性范围０－０．０３２μｇ／ｍｌ，检出限为８．７×１０＾－１０ｇ／ｍｌ。已用于人发等样品中痕量铁的测定。     

矿物肥料的抗旱作用实践与机理的初步研究

光合作用是绿色植物通过叶绿体，利用光能的催化反应把二氧化碳和水合成储存能量的一种过程，特别是水在光合作用下，若不能与二氧化碳保持一定比例的平衡，则光合作用不能继续进行，势必影响到作物的产量。因此，若施用抗旱肥料，不仅光合作用得到新的平衡，更由于光照强度大，时间也长，使合成有机物的丰度大为改观。所以，作物若施用新肥，不仅抗旱，还能保产与增收。     

碱性岩的概念及其分类命名综述

碱性岩是根据化学成分判别碱性程度属于碱性和强碱性的岩浆岩，像非碱性岩一样，碱性岩也分为超基性、基性、中性和酸性碱性岩。笔者拟定了基性碱性岩的种属划分方案，并在前人方案的基础上，对超基性、中性、酸性碱性岩的种属划分进行了修改和补充。     

极谱催化波测定天然水中微量锗的研究

系统研究了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４－Ｖ体系报道极谱催化波的影响因素，测定了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４三元配合物的配合比为１：２：１。实验初步证明了该体系催化波为具有吸附性质的平行催化波。本法检出限为０．１４ｍｇ．ｍＬ＾－１，相对标准偏差小于９．８９％，标准回收率为９３．７０％－１０９．０％，０－５０ｍｇ．ｍＬ＾－１的锗具有良好的线性关系。     

加压色层法分离稀土元素的研究

本文简要地比较了分离稀土的几种方法。重点论述了加压色层法在分离稀土元素速度快、效率高的优点。在采用比常压法高得多的线性流速和低的分配比时,加压色层法的分离效果仍优于常压法,甚至用常压法在低流速下不能分离的,用加压法在高的线性流速下仍然得到很好的分离。     

催化褪色光度法测定痕量锰的研究及应用

本研究了在ＰＨ＝４．０醋酸－醋酸钠缓冲溶液中，锰催化ＫＩＯ４氧化５－Ｂｒ－ＰＡＤＡＰ的褪色反应及其动力学条件，建立了一个痕量锰的高灵敏度新方法，方法灵敏度为１．３２×１０＾－１０ｇ／ｍｌ，测定范围Ｍｎ＾２＋浓度为０￣１．５μｇ／ｍｌ，用于测定人发，自来水，茶叶中痕量锰，结果满意。     

Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.     

催化动力学光度法在测定痕量亚硝酸根中的应用

亚硝酸根是氮循环的中间产物,易与仲胺、酰胺等反应生成致癌的亚硝酸胺化合物,因此,它是水质、环境、食品等检测的一个重要项目。亚硝酸根的测定通常采用Griess法,但所使用的α-奈胺是一种致癌物质,易污染环境。催化光度法测定亚硝酸根有较高的灵敏度,笔者发现,在磷酸介质中,亚硝酸根对溴酸钾氧化酰胺黑10B褪色反应具有灵敏的催化作用,