细基江蓠脂肪酸组成研究

研究表明,南海细基江蓠Gracilaria tenuistipitata中主要含有C_9—C_(30)一元饱和脂肪酸,其中n-十六酸含量占脂肪酸组分的40％以上。单烯和二烯酸的含量较低,缺乏多烯酸及前列腺素类化合物。此外,还含有少量二元酸类、4-及5-羰基羧酸,其中后两者是首次在红藻中发现。南海细基江蓠的脂肪酸组成特征与南海海域水质较清、光照充足及水温较高等环境因素有关。     

4-溴苯甲酸-2,3,4,5,6-五溴苯酯的合成(英文)

以苯酚和4—溴苯甲酸为原料,合成一种尚未见文献记载的新化合物——4—溴苯甲酸—2,3,4,5,6—五溴苯酯,用无水三氯化铝催化苯酚的全溴化。此产物可望在阻燃剂方面得到应用。     

β-1, 4-半乳糖基转移酶抑制剂的研究进展

β-1,4-半乳糖基转移酶(β-1,4-GalT)抑制剂的研究是当今糖化学和糖生物学的前沿研究领域之一。本文就β-1,4-GalT抑制剂(包括供体类似物、受体类似物、过渡态类似物)的设计、合成及活性评价诸方面予以综述。     

光测力学方法在薄壁钢-混凝土组合结构节点试验中的应用

应用光测力学中的数字散斑图像处理技术和网格法对对称荷载下的薄壁钢-混凝土组合结构节点的试验进行了监测,得到了节点的一些相关位移,并与百分表法测量的结果进行了比较。结果表明,两种方法用于轻钢组合结构构件的位移测量是足够精确的,可以根据试验的不同要求选择测量方法。     

Mechanism of Secondary Pore Formation and Prediction of Favorable Reservoir of Paleogene in Jiyang Sag,Eastern China

Jiyang (济阳) sag is an oil rich basin,consisting of Huimin (惠民),Dongying (东营),Zhanhua (沾化),and Chezhen (车镇) depressions.The elastic rock of Paleogene has undergone early and middle diagenetic stages and now the main clastic reservoir is in the middle diagenetic stage.Primary and secondary pores are developed in Paleogene sandstone,the latter is generated from the dissolution of feldspar and calcite cement in rocks owing to the organic acid from the maturated source rock,but the materials dissolved are different in different depressions.The reservoir secondary pores of Dongying depression are generated from the dissolution of calcite cement,the ones of Zhanhua and Huimin depressions from the dissolution of feldspar,the secondary pores of Chezhen depression from the dissolution of feldspar in upper section,and the dissolution of calcite cement in the lower section of Paleogene,respectively.The secondary pores are developed in two depths and the depth goes down from west to east,from south to north in Jiyang sag.The major controlling factors for secondary pore development are maturity and location of source rock.Lastly,the favorable reservoirs are evaluated according to reservoir buried depth,sedimentation,and diagenesis.The reservoir with high quality is located in the northern and central parts in Dongying depression; there are some good reservoirs in Gndao (孤岛),Gudong (孤东),and Gunan (孤南) areas in Zhanhua depression,and the favorable reservoirs are located in the north steep slope and the south gentle slope of Chezhen depression and central uplift,south gentle slope of Huimin depression.     

黄土高原西部白草塬剖面L1 和S1 记录的古地磁场特征

文章详细介绍了黄土高原西部白草塬剖面L1和S1的高精度岩石磁学和古地磁学结果,讨论了白草塬剖面记录古地磁场的特征,从古地磁学角度探讨白草塬剖面黄土沉积的连续性.白草塬剖面黄土沉积物中,磁铁矿和磁赤铁矿是主要的亚铁磁性矿物,粗粒的碎屑磁铁矿是其天然剩磁和特征剩磁的主要载体.白草塬剖面L1和S1没有记录任何地磁漂移.其中,L1没有记录Mono Lake或Laschamp地磁漂移的原因可归结于黄土沉积物堆积过程的不连续性和/或粗颗粒载磁矿物的重磁化,但前者是主要原因,而堆积过程的不连续性是导致S1没有记录Blake地磁漂移的主要原因.因此,白草塬剖面的L1和S1分别存在约2000年和 4000～6000年的沉积不连续.     

火山沉积岩及其矿床研究中伽马测井曲线解释的误区

根据酸性凝灰岩和酸性火山事件粘土岩的自然伽马测井曲线,对当前流传的"沉积岩层的放射性强度(或放射性核素的含量)随泥质含量的增加而增高"的概念和用自然伽马值及经验公式求泥质含量提出质凝。酸性凝灰岩的自然伽马曲线有高异常响应,若解释为泥岩显然是误解,故将沉积岩伽马曲线高异常一律解释为泥岩是片面的。各类火山事件粘土岩的伽马值相差悬殊,但其泥质含量几乎相等,用它们的伽马值计算泥质含量误差甚大。最后对铝土矿层的伽马曲线稍加解释,指出核测井应用的远景。     

Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters     

Isotopes and Geochronology of the Meixian-type Pb-Zn-(Ag)Deposits,Central Fujian Rift,South China:Implications for Geological Events

Central Fujian Rift is another new and important volcanogenic massive sulfide Pb-Zn polymetallic metallogenetic belt. In order to find out the material genesis and mineralization period of Meixian-type Pb-Zn-Ag deposits, S and Pb isotope analysis and isotope geochronology of ores and wall rocks for five major deposits are discussed. It is concluded that the composition of sulfur isotope from sulfide ore vary slightly in different deposits and the mean value is close to zero with the 834S ranging from -3.5‰ to ＋5.6‰ averaging at ＋2.0‰, which indicates that the sulfur might originate from magma or possibly erupted directly from volcano or was leached from ore-hosted volcanic rock. The lead from ores in most deposits displays radioactive genesis character （206pb/204pb〉18.140, 207Pb/204pb〉15.584, 208pb/204pb〉38.569） and lead isotope values of ores are higher than those of wall rocks, which indicates that the lead was likely leached from the ore-hosted volcanic rocks. Based on isotope data, two significant Pb-Zn metallogenesis are delineated, which are Mid- and Late-Proterozoic sedimentary exhalative metailogenesis （The single zircon U-Pb, Sm-Nd isochronal and Ar-Ar dating ages of ore- hosted wall rocks are calculated to be among 933-1788 Ma.） and Yanshanian magmatic hydrothermal superimposed and alternated metallogenesis （intrusive SHRIMP zircon U-Pb and Rb-Sr isochronal ages between 127-154 Ma）.     

鄂尔多斯地块早白垩世构造-热事件:杭锦旗玄武岩的Ar-Ar年代学证据

在鄂尔多斯地块北部杭锦旗黑石头沟,于下白垩统砂岩之上发现了一层玄武岩。其SiO2(46.93%)较低而碱含量(K2O+Na2O=6.21%)较高,组合指数σ=8.0,含标准矿物Ne,属于碱性橄榄玄武岩。Ar-Ar激光阶段加热定年结果表明,该玄武岩具有126.2±0.4Ma的Ar-Ar年龄。年龄数据表明杭锦旗黑石头沟玄武岩形成于早白垩世,反映鄂尔多斯地块在早白垩世发生了一次构造-岩浆-热事件,这与华北、乃至整个中国东部在早白垩世发生了较普遍的构造-岩浆-热事件具有一致性。这次构造-岩浆-热事件可能引起深部流体自地下深部上涌及在地块内部运移,为各种成矿元素的迁移、沉淀、富集和成矿创造了合适条件。