强烈气洗作用导致原油成分变化的定量计算:以库车坳陷天然气藏为例

库车坳陷以产天然气为主,同时产出少量原油和凝析油,油气充注不同步,普遍具有"油早气晚"的特点,晚期大量天然气的侵入,必然对早期聚集的油藏发生改造作用。对气藏中原油成分变化的定量计算和讨论,可为天然气的注入强度定量评价提供直接证据。未遭受气洗的原油,正构烷烃摩尔浓度的对数与相应的碳数呈线性关系,而气洗作用可使轻组分的正构烷烃最先溶解于干气中,并随着天然气继续向前运移,原始油藏中的轻组分正构烷烃大大减少。以此为理论基础,建立了正构烷烃损失的定量计算模型。结果表明克拉2构造原油正构烷烃损失程度最高,平均可达70%左右,大北构造带原油正构烷烃损失程度差异较大,与该地区断块发育有关。气洗作用导致原油正构烷烃减少,而金刚烷、多环芳烃等在天然气中溶解度较低的化合物得以浓缩富集,相对含量大大增加。轻芳烃含量也会随之而增加,原油芳香度增加,石蜡度降低。在模拟实验基础上对气洗程度进行了定量评价,初步估算表明,克拉2构造原油遭受的气洗作用最强,是其他构造带的2～5倍。     

重力驱动作用——滦平盆地下白垩统西瓜园组沉积时期主要的搬运机制

通过对冀北滦平盆地下白垩统西瓜园组沉积地层的实地考察,发现盆地内发育丰富的重力驱动作用沉积物。文中描述西瓜园组发育的滑动和滑塌现象,指出露头剖面中存在的挤压变形现象并非构造成因,而是由于滑动块体和滑塌块体前端的挤压应力环境造成的。在介绍西瓜园组重力流沉积发育环境的基础上,对露头中存在的若干重力流沉积进行了描述,并使用砂质碎屑流这一概念对这些现象进行了较为合理的成因解释。通过对滑动和滑塌(重力块体运动)和砂质碎屑流—浊流(重力流)沉积物研究,结合前人对该地区冲积扇—扇三角洲的研究成果,认为重力驱动作用是滦平盆地下白垩统西瓜园组沉积时期主要的搬运机制。     

沾化凹陷桩西油田古近系东营组重力流水道的沉积特征及形成条件

济阳坳陷沾化凹陷桩西油田古近系东营组下段砂体平面呈条带状展布,与曲流河单河道沉积砂体形态类似。砂岩的沉积成因是建立高精度时间地层格架、预测储集层属性参数空间分布及挖潜剩余油的关键基础之一。综合分析区域地质背景、地层沉积序列、岩石学性质、沉积组合以及砂体几何形态等方面,认为桩西油田东下段砂岩是在半深湖—深湖环境沿湖盆长轴方向延伸的远源滑塌型重力流水道—浊流水道沉积;沉积物源主要来自北部埕北低凸起附近的扇三角洲和水下扇。根据重力流水道的成因机制,将东下段浊流水道划分为水道中心微相、水道边缘微相和水下漫溢微相。单一水道中心微相沉积序列相当于鲍玛序列的AB、ABD或AC组合,主要沉积中厚层正递变层理含砾细砂岩相和块状层理混合碎屑岩相,属中孔中低渗储集层。研究区滑塌型浊流水道形成的外部控制因素是火山喷发及控盆断层的幕式活动所导致的长期基准面下降;内部控制因素是充足的物源、垂直湖盆长轴方向的阶梯状断裂以及负向湖盆底形等。建立了反映该区浊流水道的沉积特征及发育条件的沉积模式。     

海拉尔盆地基底晚古生代adakite的发现及其地质意义

海拉尔盆地的前中生代基底隶属中亚造山带东段的兴蒙造山带。 在盆地基底地层中发现了具有adakite成分特征的粗面安山岩、英安岩和闪长玢岩。 这些火成岩与晚古生代沉积地层交互或伴生, 共同构成晚中生代裂陷盆地的基底。 地球化学研究表明, 这些火成岩基本上属于高钾钙碱性和准铝质岩石系列, 具有高SiO₂和Al₂O₃含量, 高Sr、Sr/Y和La/Yb值, 富集轻稀土(LREE), 亏损重稀土(HREE)、Y和高场强元素(HFSE),Eu表现弱的负异常或轻微的正异常, 相容元素Mg、Cr和Ni含量低, 这些特征与增厚下地壳部分熔融成因的adakite非常相似, 而明显不同于典型的由俯冲洋壳熔融形成的adakite。 样品的(⁸⁷Sr/⁸⁶Sr)_i值基本一致,为0.7041, (¹⁴³Nd/¹⁴⁴Nd)_i值为0.51243~0.51247, ε_Nd (t)为正值(+3.7~+4.5), 显示其岩浆源区可能源于弱亏损地幔, 或亏损地幔受到地壳物质混染。 本文认为海拉尔地区晚古生代adakite型岩浆很可能是由当时新底侵的玄武质下地壳在角闪岩相向榴辉岩相过度或榴辉岩相条件下部分熔融形成。 这些adakite岩石的出现反映了兴蒙造山带晚古生代受到了古亚洲洋的俯冲消减引起的强烈的地幔玄武质岩浆底侵作用, 并由此导致地壳垂向上显著的增生加厚过程。     

通过第一性原理预测内地核的成分与结构

内地核成分与结构的确定一直是地球深部研究的重要课题。目前地核的公认成分是铁和少量的镍。但由于地核密度低于纯粹的铁镍合金(固态内核2%～3%,液态外核6%～7%),其中必定掺杂有一定量的轻元素,其种类与浓度有待确定。除成分外,地核条件下铁的晶体结构也存在争议。根据地震学观测,声波沿地轴方向的传播速度比赤道平面方向快大约3%～4%。这意味着内地核是各向异性的;但在极端高压下,晶体结构中的原子应该按致密的密排六方结构(h.c.p)排列,而h.c.p结构对声波传输是高度各向同性的,这就需要确定地核条件下铁的晶体结构。根据第一性原理计算得到的高压下体系能量以及爱因斯坦谐振子模型,本项研究估算了给定结构的自由能以及掺杂轻元素后的影响。根据计算结果可以定性的分析得出,在高压OK下致密的h.c.p结构显然比疏松的体心立方(b.c.c)更稳定;而随着温度的升高,原子核的振动造成b.c.c结构的自由能比h.c.p结构下降得更快,因此在高温下b.c.c结构更稳定;掺杂轻元素后,这种优势变得更加明显,而3.6at.%的Si则恰好同时解释了2%～3%的密度缺失和b.c.c结构在内地核条件下的稳定性。因此我们建议内地核的基本结构与成分应为以体心立方结构存在的铁,掺杂约3.6at.%的硅元素,内地核温度至少在5500K以上。这一结论与其它更复杂的方法得到的结果一致。     

基于PCP-C耦合模型的流域洪水分类研究

洪水过程受多要素综合影响,因此多指标的综合分类方法成为目前洪水分类研究的主要趋势.针对目前多指标洪水综合分类方法中存在的诸多不足,可采用主成分投影-聚类(PCP-C)耦合模型进行洪水分类.该方法首先对原始指标数据进行无量纲化(均值化)处理,再对处理后的数据矩阵进行正交变换,由此将原指标转换成彼此正交的综合指标,并利用各主成分设计一个理想决策向量,以各被评价对象相应的决策向量在理想决策方向上的投影值作为一维的综合分类指标.最后通过对各分类样本的一维投影值的聚类分析,得到分类结果.实例分析表明,建议方法简单,模型构建容易,计算简便,分类直观简洁,可行性强.     

专家揭秘地灾频发原因

今年以来,我国部分地区出现了泥石流、滑坡、塌陷等地灾,威胁到群众安全。地壳缘何如此“脆弱”？记者近日就此问题采访了有关专家。他们认为,地表破坏和地质活跃期的到来是今年以来地灾频繁发生的主要原因。专家建议应从多渠道入手防治地灾。     

柴西乌南-绿草滩地区古近系下干柴沟组下段储盖组合与勘探潜力

运用层序地层学的理论和方法,综合钻井、测井和三维地震资料,在柴西乌南-绿草滩地区古近系下干柴沟组下段识别出两个层序界面,将其划分为1个长期基准面旋回(三级层序)LSC1和4个中期基准面旋回(四级层序)MSC1、MSC2、MSC3和MSC4。在等时地层格架约束下,详细分析了研究区储集层、盖层及储盖组合的发育规律与基准面旋回的内在联系,指出本区古近系下干柴沟组下段具有较大的油气勘探潜力。     

http://www.sciencedirect.com/science/article/pii/S1674987110000071

<正>The lithospheric structure of China and its adjacent area is very complex and is marked by several prominent characteristics.Firstly,China's continental crust is thick in the west but thins to the east,and thick in the south but thins to the north.Secondly,the continental crust of the Qinghai—Tibet Plateau has an average thickness of 60—65 km with a maximum thickness of 80 km,whereas in eastern China the average thickness is 30—35 km,with a minimum thickness of only 5 km in the center of the South China Sea.The average thickness of continental crust in China is 47.6 km,which greatly exceeds the global average thickness of 39.2 km.Thirdly,as with the crust,the lithosphere of China and its adjacent areas shows a general pattern of thicker in the west and south,and thinner in the east and north.The lithosphere of the Qinghai—Tibet Plateau and northwestern China has an average thickness of 165 km, with a maximum thickness of 180—200 km in the central and eastern parts of the Tarim Basin,Pamir, and Changdu areas.In contrast,the vast areas to the east of the Da Hinggan Ling—Taihang—Wuling Mountains,including the marginal seas,are characterized by lithospheric thicknesses of only 50—85 km.Fourthly,in western China the lithosphere and asthenosphere behave as a "layered structure", reflecting their dynamic background of plate collision and convergence.The lithosphere and asthenosphere in eastern China display a "block mosaic structure",where the lithosphere is thin and the asthenosphere is very thick,a pattern reflecting the consequences of crustal extension and an upsurge of asthenospheric materials.The latter is responsible for a huge low velocity anomaly at a depth of 85—250 km beneath East Asia and the western Pacific Ocean.Finally,in China there is an age structure of "older in the upper layers and younger in the lower layers" between both the upper and lower crusts and between the crust and the lithospheric mantle.     

http://www.sciencedirect.com/science/article/pii/S1674987110000058

<正>The thermo-electric coefficients of twenty-six magnetite samples,formed either by magmatism or metamorphism,were tested by the thermo-electric instrument BHET—06.Results showed that the coefficient is of a constant value of about -0.05 mV/℃.It is emphasized that because every magnetite grain was tested randomly,the coefficient is independent of the crystallographic direction.This fact means the thermal voltage generated from a single magnetite crystal can be accumulated,and as a result a new thermo-electric field can arise when a gradient thermal field exists and is active within the earth's crust.Because magnetite is widespread in the earth's crust(generally appearing more in the middle-lower crust),there is more-than-random probability that the additional thermo-electric field can be generated when certain thermal conditions are fulfilled.We,therefore,used the thermo-electric effect of magnetite to study the mechanism responsible for the presence of abnormal geo-electric fields during earthquake formation and occurrence, because gradient thermal fields always exist before earthquakes.The possible presence of additional thermo-electric fields was calculated under theoretical seismological conditions,using the following calcu-lation formula:E= - 0.159(σ×△T×φ×ρ_2×[(h~2-2x~2)cosα+ 3hxsinα]/ρ_1(h~2 +x~2)~(5/2)).In the above formula,σis thermo-electric coefficient of magnetite,△T is the temperature difference acting on it,φis a sectional area on a block of magnetite vertically perpendicular to the direction of the thermal current.ρ_1 andρ_2 are the respective resistivities of magnetite and the crust,and h,α,and x,respectively,h is the depth of embedded magnetite block,αmeans the angle created by the horizontal line and ligature of the two poles of magnetite block,and x is the distance from observation point to projective center point of the magnetite block on earth surface.According to simulations calculated with this formula,additional thermo-electric field intensity may reach as high as n to n×10~2 mV/km.This field is strong enough to cause obvious anomalies in the background geo-electric field,and can be easy probed by earthquake monitoring equipment. Therefore,we hypothesize that geo-electric abnormalities which occur during earthquakes may be caused by the thermo-electric effect of magnetite.