全球碳循环研究中的δ13C方法及其进展

随着分析技术的进步,δ13C观测在全球碳循环研究中越来越受到重视。在讨论关于碳循环中δ13C的Suess效应、分布特征和同位素分馏等基本概念的基础上,结合现有的观测事实,介绍应用δ13C辨别碳的源汇问题的方法,通过比较不同KeelingPlot方法分析该方法在研究大气CO2背景特征中的意义。着重讨论δ13C在研究大气C...     

示波极谱法测量电锌液中微量镍

提出在丁二酮肟-亚硝酸钠-氨水-氯化铵体系中,准确测定电锌液中微量镍的新方法:克服原子吸收光谱法测定微量镍回收率偏低问题。     

Formation of the Dongmozhazhua Pb–Zn Deposit in the Thrust‐Fold Setting of the Tibetan Plateau,China: Evidence from Fluid Inclusion and Stable Isotope Data

The Dongmozhazhua deposit, the largest Pb–Zn deposit in south Qinghai, China, is stratabound, carbonate‐hosted and associated with epigenetic dolomitization and silicification of Lower–Middle Permian—Upper Triassic limestones in the hanging walls of a Cenozoic thrust fault system. The mineralization is localized in a Cenozoic thrust‐folded belt along the northeastern edge of the Tibetan plateau, which was formed due to the India–Asia plate collision during the early Tertiary. The deposit comprises 16 orebodies with variable thicknesses (1.5–26.3 m) and lengths (160–1820 m). The ores occur as dissemination, vein, and breccia cement. The main sulfide assemblage is sphalerite + galena + pyrite + marcasite ± chalcopyrite ± tetrahedrite, and gangue minerals consist mainly of calcite, dolomite, barite, and quartz. Samples of pre‐ to post‐ore stages calcite yielded δ¹³C and δ¹⁸O values that are, respectively, similar to and lower than those yielded by the host limestones, suggesting that the calcite formed from fluids derived from carbonate dissolution. Fluid inclusions in calcite and sphalerite in the polymetallic sulfidization stage mostly comprise liquid and gas phases at room temperature, with moderate homogenization temperatures (100–140°C) and high salinities (21–28 wt% NaCl eq.). Micro‐thermometric fluid inclusion data point to polysaline brines as ore‐forming fluids. The δD and δ¹⁸O values of ore fluids, cation compositions of fluid inclusions, and geological information suggest two main possible fluid sources, namely basinal brines and evaporated seawater. The fluid inclusion data and regional geology suggest that basinal brines derived from Tertiary basins located southeast of the Dongmozhazhua deposit migrated along deep detachment zones of the regional thrust system, leached substantial base metals from country rocks, and finally ascended along thrust faults at Dongmozhazhua. There, the base‐metal‐rich basinal brines mixed with bacterially‐reduced H₂S‐bearing fluids derived from evaporated seawater preserved in the Permo–Triassic carbonate strata. The mixing of the two fluids resulted in Pb–Zn mineralization. The Dongmozhazhua Pb–Zn deposit has many characteristics that are similar to MVT Pb–Zn deposits worldwide.     

芦苇、菖蒲和水葱对水体中Zn2+的富集效应研究

采用水培方法,在不同ZnCl2浓度(0mg/L、50mg/L、100mg/L、300mg/L、800mg/L、1500mg/L和2500mg/L)处理的水体中,对湿地植物芦苇(Phragmites australis)、菖蒲(Acorus calamus)和水葱(Scirpus tabernaemontani)进行培养,研究植物的不同部位对Zn2+的积累能力。结果表明,在相同ZnCl2浓度处理下的水体中,水葱、菖蒲和芦苇体内的平均Zn2+积累浓度存在差异,菖蒲体内的Zn2+积累浓度最高。在不同ZnCl2浓度处理下的水体中,水葱体内的平均Zn2+积累浓度在ZnCl2浓度为1500mg/L时最高,为31050.84mg/kg(植物地上部分为10206.67mg/kg,地下部分为20844.17mg/kg);菖蒲和芦苇体内的平均Zn2+积累浓度则在ZnCl2浓度为2500mg/L时最高,分别为54130.67mg/kg(地上部分为16774.00mg/kg,地下部分为37356.67mg/kg)和25423.34mg/kg(地上部分为4506.67mg/kg,地下部分为20916.67mg/kg)。这3种植物都可以作为利用植物修复重金属污染水体的遴选物种。其中,菖蒲对Zn2+的吸收能力明显高于水葱和芦苇。     

The origin of the Maozu carbonate-hosted Pb–Zn deposit,southwest China: Constrained by C–O–S–Pb isotopic compositions and Sm–Nd isotopic age

The Maozu Pb–Zn deposit, located on the western margin of the Yangtze Block, southwest China, is a typical carbonate-hosted deposit in the Sichuan–Yunnan–Guizhou Pb–Zn metallogenic province with Pb + Zn reserves of about 2.0 million tonnes grading 4.15 wt.% Pb and 7.25 wt.% Zn. Its ore bodies are hosted in Sinian (635–541 Ma) Dengying Formation dolostone and show stratiform, vein and irregular textures. Ores are composed of sphalerite, galena, pyrite, calcite, dolomite, quartz and fluorite with massive, banded, disseminated and veined structures. The C–O–Sm–Nd isotopic compositions of hydrothermal calcites and S–Pb isotopic compositions of sulfides were analyzed to constrain the origin of the Maozu deposit. δ¹³C_PDB and δ¹⁸O_SMOW values of hydrothermal calcites range from −3.7‰ to −2.0‰ and +13.8‰ to +17.5‰, respectively, and plot near the marine carbonate rocks field in a plot of δ¹³C_PDB vs. δ¹⁸O_SMOW, with a negative correlation. It suggests that CO₂ in the hydrothermal fluids was mainly originated from marine carbonate rocks, with limited influence from sedimentary organic matter. δ³⁴S_CDT values of sulfides range from +9.9‰ to +19.2‰, similar to that of Cambrian to Triassic seawater sulfate (+15‰ to +35‰) and evaporate (+15‰ to +30‰) in the Cambrian to Triassic sedimentary strata. It suggests that reduced sulfur was derived from evaporate in sedimentary strata by thermo chemical sulfate reduction. Sulfides have low radiogenic Pb isotope compositions (²⁰⁶Pb/²⁰⁴Pb = 18.129–18.375, ²⁰⁷Pb/²⁰⁴Pb = 15.640–15.686 and ²⁰⁸Pb/²⁰⁴Pb = 38.220–38.577) that plot in the field between upper crust and the orogenic belt evolution curve in the plot of ²⁰⁷Pb/²⁰⁴Pb vs. ²⁰⁶Pb/²⁰⁴Pb, and similar to that of age corrected Proterozoic basement rocks (Dongchuan and Kunyang Groups). This indicates that ore-forming metals were mainly derived from basement rocks. Hydrothermal calcite yields a Sm–Nd isotopic age of 196 ± 13 Ma, possibly reflecting the timing of Pb–Zn mineralization in the SYG province, younger than the Permian Emeishan mantle plume (∼260 Ma). All data combined suggests that hydrothermal fluids circulated through basement rocks where they picked up metals and migrated to surface, mixed with reduced sulfur-bearing fluids and precipitated metals. Ore genesis of the Maozu deposit is different from known magmatic–hydrothermal, Sedimentary Exhalative or Mississippi Valley-types, which maybe represent a unique ore deposit type, named as the SYG-type.     

（∈y，∈yVqδ）-模糊n-序超群

把模糊集理论应用到n-序超群,在交换n-序超群中引入了（∈y,∈yVqδ）模糊n-序子超群和（∈y,∈yVqδ）模糊n-序可逆子超群的概念,并研究了其性质。     

云南维西娃渣铁铅锌多金属矿床

矿床属与中三叠统中酸性火山岩有关的喷流型（或火山沉积改造型）铁铅锌多金属矿,并受地层构造双重控制.     

滇东北渔户村组内的富铅锌矿床成矿地质特征及成因

渔户村组为滇东北富铅锌矿床的重要产出层位。通过茂粗、金沙厂、五星、乐红、大海等矿床，总结了滇东北渔户村组内的富铅锌矿床的地质特征及成因，认为其与喷流沉积成矿作用和后期改造作用有关，为海底火山喷流沉积－改造成因。     

喀斯特与非喀斯特区土壤含水量与植物叶片δ13C关系的对比研究—— 以贵州清镇市王家寨小流域为例

通过测定贵州省清镇市王家寨小流域内不同背景区(喀斯特与非喀斯特)土壤的含水量以及16种植物叶片的δ13 C值,比较了不同背景区从退化生态到非退化生态过程中各样地之间,以及石漠化和土山样地不同坡位之间土壤含水量与植物叶片δ13 C值的相关关系。研究结果表明,不管是喀斯特背景区还是非喀斯特背景区从退化到非退化的过程中,随着土壤含水量的逐渐增大,植物叶片的δ13 C值与土壤含水量呈现显著的负相关关系,即土壤含水量越大,植物的水分利用效率就越低;而从不同坡位土壤含水量与植物叶片δ13 C值的相关关系分析表明,石漠化样地植物叶片δ13 C值并不随坡位土壤含水量的不同呈现出规律性的变化,而坡位自上而下土山样地植物叶片的δ13 C值则表现出随土壤含水量的增大而逐渐趋负。这些研究结果均反映了植物叶片的δ13 C值对不同生境土壤水分条件的适应机制,其中石漠化样地上的植物对土壤含水量变化的响应最迅速和最敏感。      

西部中国沙棘叶片稳定碳同位素组成的空间特征及其气候意义

分析了西部中国沙棘（Hippophate rhamnoides sinensis）叶片稳定碳同位素组成特征及其与环境因子之间的关系。结果表明,中国沙棘叶片δ13C值在-30.40‰~-24.91‰之间变化,平均值约为-27.62‰,属于C3植物。随纬度和经度的升高,中国沙棘叶片δ13C值明显升高,而随海拔的升高而降低,具有明显的空间分布特征。中国沙棘叶片δ13C值与温度没有明显的关系,随蒸发量和日照时间的升高而升高,随降水量的升高有降低趋势,具有明显的气候意义。表明中国沙棘具有较高的水分利用效率,水分是控制中国沙棘δ13C值变化或生长的主导因子。