珠江河口经济动物体铜铅锌镉的含量

分别于2000年4月、2001年4月和2002年8月对珠江河口水域海洋经济动物体内Cu、Pb、Zn、Cd四种重金属元素的含量进行了调查分析,结果表明,14种经济动物体肌肉Cd、Cu、Pb、Zn各元素的平均含量分别是0.08、2.67、0.05、5.69mg·kg~(-1),其变化范围为nd～0.46mg·kg~(-1)、0.24～11.85mg·kg~(-1)、nd～0.26mg·kg~(-1)、1.55～18.36mg·kg~(-1)。甲壳类与头足类生物体内铜铅锌镉含量比较接近,远远高于鱼类的含量。所检测的14种经济类海洋动物中,虾姑、乌贼Cu的含量高于其余三种元素的含量,其余12种生物Zn的含量比另三种元素含量高。三次调查该水域经济类海洋动物体铜铅锌镉的含量基本一致。与水产品中有毒有害物质限量标准比较,14种被测样品铜、铅和镉的含量全部符合该标准的要求。     

Chandra observations of the X-ray jet in 3C 66B

Our Chandra observation of the FR I radio galaxy 3C 66B has resulted in the first detection of an X-ray counterpart to the previously known radio, infrared and optical jet. The X-ray jet is detected up to 7 arcsec from the core and has a steep X-ray spectrum, α ≈1.3±0.1 . The overall X-ray flux density and spectrum of the jet are consistent with a synchrotron origin for the X-ray emission. However, the inner knot in the jet has a higher ratio of X-ray to radio emission than the others. This suggests that either two distinct emission processes are present or differences in the acceleration mechanism are required; there may be a contribution to the emission from the inner knot from an inverse Compton process or it may be the site of an early strong shock in the jet. The peak of the brightest radio and X-ray knot is significantly closer to the nucleus in the X-ray than in the radio, which may suggest that the knots are privileged sites for high-energy particle acceleration. 3C 66B's jet is similar both in overall spectral shape and in structural detail to those in more nearby sources such as M87 and Centaurus A.     

贵州都匀大亮锌矿床闪锌矿稀土元素地球化学特征及其指示意义北大核心CSCD

贵州都匀大亮锌矿床是牛角塘铅锌矿田的重要组成部分,目前所开采的对象为近年来在“陡倾斜带”中新发现的矿体,其研究还十分薄弱。本研究采用ICP-MS测试技术,对大亮锌矿闪锌矿进行了稀土元素测试,以揭示该矿床成矿作用。结果表明,10件闪锌矿样品的ΣREE值低,质量分数为(0.15~0.40)×10^(-6)(平均0.24×10^(-6))。样品的LREE/HREE值变化范围为7.07~15.76(平均10.95),(La/Yb)_(N)值范围为4.75~28.57(平均11.54),(La/Sm)_(N)值为2.16~6.01(平均3.49),(Gd/Yb)^(N)值为0.34~3.68(平均1.67)。闪锌矿样品稀土元素呈现轻稀土富集的右倾模式,且轻稀土元素的分异程度远远高于重稀土元素。样品具有显著Eu正异常(δEu为6.60~54.29,平均18.10),无明显的Ce异常(δCe主要为0.93~1.09,平均1.01)。闪锌矿轻稀土富集及显著Eu正异常的特点表明,其稀土元素为矿石初始沉淀时从成矿热液中继承而来,未明显受到后期地质作用的影响。稀土元素特征表明该闪锌矿形成于较低温度和极强还原条件。大亮锌矿闪锌矿Y/Ho比值为11.33~32.17(平均22.71),与区域矿床及地层的对比表明成矿物质主要来自下伏地层,可能有少量来自赋矿围岩。     

甘肃厂坝-李家沟超大型铅锌矿床成矿金属来源——来自闪锌矿原位S-Pb和Zn同位素证据

甘肃厂坝-李家沟铅锌矿床位于西秦岭多金属成矿带内的西成矿集区,为矿集区内重要的超大型铅锌矿床。矿体赋存在中泥盆统安家岔组的白云石化大理岩及石英片岩中,其成因认识一直存在争议,主要分歧集中在是同生还是后生。文章对不同成矿阶段的闪锌矿,采用多接收电感耦合等离子体质谱(MC-ICP-MS)测定Zn同位素组成、采用激光剥蚀-多接收电感耦合等离子体质谱(LA-MC-ICP-MS)原位微区分析技术测定S、Pb同位素组成,示踪成矿物质来源,并分析矿物沉淀机制,为深入理解矿床成因提供新的精细证据。研究结果显示,Ⅰ、Ⅱ、Ⅲ三个成矿阶段闪锌矿的δ⁶⁶Zn分别为0.08‰~0.29‰,平均0.20‰;0.19‰~0.37‰,平均0.30‰;0.36‰~0.37‰,平均0.37‰。其中,Ⅰ阶段的闪锌矿δ³⁴S_Ⅰ值为20.9‰~26.1‰,平均24.4‰;Ⅱ阶段的闪锌矿δ³⁴S_Ⅱ值为12.2‰~21.9‰,平均19.1‰;Ⅲ阶段的闪锌矿δ³⁴S_Ⅲ值为18.2‰~24.7‰,平均21.5‰。3个阶段的矿石矿物Pb同位素组成变化不大,²⁰⁶Pb/²⁰⁴Pb为17.922~18.013,²⁰⁷Pb/²⁰⁴Pb为15.567~15.647,²⁰⁸Pb/²⁰⁴Pb为37.990~38.266。δ⁶⁶Zn同位素值显示,成矿金属早期来源于围岩海相碳酸盐岩,由于混合了岩浆热液或者是瑞利分馏作用,在成矿作用中后期δ⁶⁶Zn同位素逐渐上升。δ³⁴S同位素值显示,早期硫源主要为地层中的硫酸盐,中后期的δ³⁴S同位素值降低,可能是成矿流体中岩浆热液中的S^2-成分逐渐增多导致,闪锌矿为硫酸盐通过TSR反应沉淀成矿。Pb同位素指示成矿物质来源于上地壳,并混入了部分古老的变质基底的成分。笔者研究发现,厂坝-李家沟铅锌矿的成矿机制为不同来源的流体混合,随着pH值、成矿流体的温度发生变化而沉淀成矿。     

武都万象洞方解石现代沉积体系δ~(18)O值月变化特征

万象洞所在地大气降水同位素值年内波动较大,变化起止时间存在显著的年际差异。观测期内,武都降水同位素δD-δ18O组合特征与周边城市降水同位素多年平均值重建的区域降水雨水线基本重合,洞穴所在地区降水同位素具有很好的区域代表性。洞穴滴水同位素值年内变化幅度较小,基本反映了当地大气降水同位素值的月加权平均水平。洞穴次生碳酸盐与洞穴滴水之间符合同位素平衡分馏基本规律。季节尺度上,不同监测点滴水及次生碳酸盐δ18O值因受地下水混合作用强弱差异及洞穴温度的小幅变化等影响而略有差异;年际变化上,夏季风爆发前后降雨量的权重及爆发时间的早晚对洞穴滴水-碳酸盐体系同位素水平存在一定的影响。万象洞洞穴滴水、石笋氧同位素信号在年代际尺度上可以很好地指示区域内大气降水的同位素变化特征。     

Compositions and Pressure–Temperature Conditions of Metamorphic Fluids Overprinting the Talate VMS Pb–Zn Deposit, Southern Altay, China

The Talate Pb-Zn deposit,located in the east of the NW-SE extending Devonian Kelan volcanic-sedimentary basin of the southern Altaides,occurs in the metamorphic rock series of the upper second lithological section of the lower Devonian lower Kangbutiebao Formation(D_1k_1~2).The Pb-Zn orebodies are stratiform and overprinted by late sulfide—quartz veins.Two distinct mineralization periods were identified:a submarine volcanic sedimentary exhalation period and a metamorphic hydrothermal mineralization period.The metamorphic overprinting period can be further divided into two stages:an early stage characterized by bedding-parallel lentoid quartz veins developed in the chlorite schist and leptite of the ore-bearing horizon,and a late stage represented by pyritechalcopyrite-quartz veins crosscutting chlorite schist and leptite or the massive Pb-Zn ores.Fluid inclusions in the early metamorphic quartz veins are mainly CO_2-H_2O-NaCI and carbonic(CO_2±CH_4±N_2) inclusions with minor aqueous inclusions.The CO_2-H_2O-NaCl inclusions have homogenization temperatures of 294-368℃,T_(m,CO2) of-62.6 to-60.5℃,T_(h,CO2) of 7.7 to 29.6℃(homogenized into liquid),and salinities of 5.5-7.4 wt%NaCl eqv.The carbonic inclusions have T_(m,CO2)of-60.1 to-58.5℃,and T_(h,Co2) of-4.2 to 20.6℃.Fluid inclusions in late sulfide quartz veins are also dominated by CO_2-H_2O-NaCl and CO_2±CH_4 inclusions.The CO_2-H_2O-NaCl inclusions have T_(b,tot) of142 to 360℃,T_(m,CO2)of-66.0 to-56.6℃,T_(h,CO2) of-6.0 to 29.4℃(homogenized into liquid) and salinities of 2.4-16.5 wt%NaCl eqv.The carbonic inclusions have T_(m,Co2)of-61.5 to-57.3℃,and T_(h,CO2) of-27.0to 28.7℃.The aqueous inclusions(L-V) have T_(m,ice) of-9.8 to-1.3℃ and T_(h,tot) of 205 to 412℃.The P-T trapping conditions of CO_2-rich fluid inclusions(100-370 MPa,250-368℃) are comparable with the late- to post-regional metamorphism conditions.The CO_2-rich fluids,possibly derived from regional metamorphism,were involved in the reworking and metal enrichment of the primary ores.Based on these results,the Talate Pb-Zn deposit is classified as a VMS deposit modified by metamorphic fluids.The massive Pb-Zn ores with banded and breccia structures were developed in the early period of submarine volcanic sedimentary exhalation associated with an extensional subduction-related back-arc basin,and the quartz veins bearing polymetallic sulfides were formed in the late period of metamorphic hydrothermal superimposition related to the Permian-Triassic continental collision.     

西藏古堆—隆子地区Sb,Pb,Zn化探元素的分形研究及其地质意义

文章根据西藏古堆—隆子地区Sb,Pb,Zn化探元素品位分析结果,结合区域地质资料,基于分形几何学的理论基础,对研究区Sb,Pb,Zn的分布规律进行了定量研究。结果表明,4个研究区Sb,Pb都具有多重分维的性质,且与矿化有关的分维值D2ⅡD2Ⅲ,同一研究区同一元素的各组分维值差距较大,Ⅲ区和Ⅳ区的Zn只有一个维数值,说明典型矿床发育的地区成矿元素具有多重的分维结构和低分维值D2,基于此理论成功验证了恰嘎研究区具有寻找锑矿前景。通过研究Sb,Pb,Zn的分形特征,揭示出化探元素的分维结构和分维值的大小与矿化程度有关,并为找矿勘查工作提供一定的地质依据。     

Study on the relationship between speciation of heavy metals and their ecotoxicity

Heavy metal is a main pollutant in the marine ecosystem, so study on the effect of heavy metal on phytoplankton is important. Algae (Chaetoceros sp.,Dunaliella sp.,Dicrateria zhanjiangenis Hu. var. sp.) were laboratory cultured to observe the effect of heavy metals on their growth. The effect of different metal ion concentration, the detoxication effect of complexation agents and the growth of algae in different media and different nutrition levels were studied to evaluate the effect of metal speciation. It is proved that trace amount of heavy metals can stimulate the growth of algae cells but that high concentration is lethal. The sequence of toxicity is Cd²⁺>Zn²⁺>Pb²⁺. In ordinary nutrition conditions, the detoxication sequence of complexation agents toChaetoceros sp. is EDTA >sodium salicylate>sodium oxalate >sodium citrate>sulfanilic acid>O-phenanthroline. This is in good conformity with the stability constant sequence of these agents with copper and good evidence that toxicity of metal ion is related to its activity and not to its total concentration. Project supported by the Fund of Excellent Young Teachers of State Educational Commission of China.     

Estimation of heavy metals (Cu,Zn, Pb) input into Punat Bay

The fate of heavy metals (Cu, Pb, Zn) from their sources to the final sink was analysed. Investigations included the identification of sources, the input from each source as well as transport towards their temporary (soil, vegetation, and marine water) and final sink (marine sediments). Research was conducted in the catchment area of Punat Bay on the island of Krk (Northern Adriatic, Croatia). Four sources were identified: long-range transport, traffic, antifouling paints and eroded material which annually introduced about 158 kg of Cu, 175 kg of Pb and 666 kg of Zn into the Bay. Antifouling paints were significant but not the main source of pollution in this area as was considered in previous investigations. Due to long-range transport, the input of Zn was almost four times greater, whereas the input of Pb was almost six times greater than the input from antifouling paints. Aerosols emitted from motor vehicles still represent the mayor source of Pb in this area. Cu originates mostly from antifouling paints and long-range transport. It was estimated that only around 30% of analysed elements introduced into the water column would be deposited in their final sink, i.e. marine sediments.