Influence of Temporal Variations in River Discharge, pH, Alkalinity and Ca on the Speciation and Concentration of Heavy Metals in Some Mining Polluted Rivers

Dissolved (dialysis in situ) and total concentrations ofCu, Zn, Cd and Al in eight mining polluted rivers in the Røros area, central Norway, were determinedby atomic absorption spectrometry (flame and graphite furnace) and compared to pH, Caconcentration and alkalinity through seasonal variations in river discharge. Totalconcentrations of the metals were highest during early spring flood and during summer andautumn rain episodes. Dissolved concentrations also increased as the spring floodproceeded, but small discharge peaks within this 2 month period as well as a considerableautumn flood episode appeared to lower rather than to raise the dissolved metal concentrations.Consequently the dissolved fractions of Zn, Cd and Al showed a significant negative correlationwith river discharge, and were low at the discharge peaks. Possibly high sediment concentrationsoccurring at high flood conditions more than counteracted desorption induced by pHdecrease, and led to decreased dissolved fractions through adsorption. Cu speciationon the other hand seemed to be more closely linked to pH. Alkalinity and Ca concentration,both assumed to protect aquatic life from metal pollution, were significantly lowerduring episodes with high Cu and Al total concentrations.     

峨眉山玄武岩与铅锌矿床成矿关系初探—以云南会泽铅锌矿床为例

本文以云南会泽铅锌矿为例，从成矿时代、成矿物来源、成矿流体来源和成矿热动力等方面初步讲座主峨眉山玄武岩与铅锌矿床成矿的关系。结果表明：矿床成矿时代可能与峨眉山玄武岩岩浆活动时代相近；峨眉山玄武岩在成矿过程中提供了部分成矿物质；伴随峨眉山玄武岩岩浆活动过程去气作用（包括地幔去气作用和岩浆去气作用）形成的流体参与了会泽铅锌矿成矿流体的形成；峨眉山玄武岩岩浆活动为成矿热动力的主要来源。     

北祁连石居里地区Cu(Zn)-S矿床地质特征及综合成矿模式

文章主要论述了北祁连山西段石居里矿田内Ⅵ号沟、Ⅷ号沟、九个泉等矿床的基本地质特征，并与北祁连山东段老虎山地区银硐沟、猪嘴哑吧等矿床对比。结合其早古生代构造演化历史、古洋脊或弧间、弧后拉张环境确定矿床类型，将上述3个矿床归属为蛇绿岩Cu(Zn）－S型矿床（类塞浦路斯型）。建立综合成矿模式的基本要求：（1）矿床具有一定的时控性，有一定的含矿层位；（2）生长性断裂的积极参与；（3）海底火山喷发、喷气中心与次级盆地双向控制；（4）多元热流体成矿系统。     

Heavy Metal Load of Sediments of the River Gurk (Carinthia/Austria) — Merits and Limitations of Sequential Leaching Schwermetallbelastung des Sediments der Gurk in Kärnten — Vorzüge und Einschränkungen sequentieller Löseverfahren

By means of the analysis of sediments cored in the small river Gurk (Carinthia/Austria), the input of Ag, Cd, Ce, Cr, Hg, La, Mo, Ni, V, and W from a chemical industrial plant could be detected. To estimate the actual load, and to obtain data for comparison with other sites, both unsieved fine sediments and sediments sieved to 20 μm were investigated from the same cores. Environmental mobilities of toxic heavy metals (Co, Cr, Cu, Ni, Zn) have been shown by sequential leaching following Tessier/Förstner. In the last step, HNO₃ leaches a purely geogenic fraction, which is fairly constant along the investigated river. Whereas the additional Cr from the input of the chemical plant is mainly found in the oxalate-leachable fraction, short-time-load to unpolluted sediments in the laboratory is found mainly in hydroxylamine/acetic acid. Both is due to the high affinity of Cr to Fe- and Mn-oxides. Adsorption/desorption experiments reveal that the low carbonate content of the Gurk sediments increases the importance of Fe/Mn-oxides for the sorption of Cr compared to other samples containing carbonate. The Ni-load was primarily found in weak-acid-leachable and oxalate-leachable fractions. Similarly, the oxalate-leachable fraction is dominant for adsorption of other metals and phosphorus. Other interelement relationships among the amounts leached, which are attributable partly to carbonate-, silicate-, organic or coating phases, have been found by means of factor analyses together with marker fractions for each type.     

云南茶树林铅锌矿电磁波找矿效果

茶树林铅锌矿，过去认为震旦系赋矿，钻探验证未见矿。本次利用物探方法实施深部探矿。依据物探异常，结合地质规律综合分析，认为是构造控矿。布置验证坑道，沿断裂破碎带发现新的厚大、品位高铅锌矿体，收到良好的找矿效果。     

Genesis of the Changba–Lijiagou Giant Pb-Zn Deposit, West Qinling, Central China: Constraints from S-Pb-C-O isotopes

The extensive Changba-Lijiagou Pb-Zn deposit is located in the north of the Xihe–Chengxian ore cluster in West Qinling. The ore bodies are mainly hosted in the marble, dolomitic marble and biotite-calcite-quartz schist of the Middle Devonian Anjiacha Formation, and are structurally controlled by the fault and anticline. The ore-forming process can be divided into three main stages, based on field geological features and mineral assemblages. The mineral assemblages of hydrothermal stage I are pale-yellow coarse grain, low Fe sphalerite, pyrite with pits, barite and biotite. The mineral assemblages of hydrothermal stage II are black-brown cryptocrystalline, high Fe shalerite, pyrite without pits, marcasite or arsenopyrite replace the pyrite with pits, K-feldspar. The features of hydrothermal stage III are calcite-quartz-sulfide vein cutting the laminated, banded ore body. Forty-two sulfur isotope analyses, twenty-five lead isotope analyses and nineteen carbon and oxygen isotope analyses were determined on sphalerite, pyrite, galena and calcite. The δ34 S values of stage I(20.3 to 29.0‰) are consistent with the δ34 S of sulfate(barite) in the stratum. Combined with geological feature, inclusion characteristics and EPMA data, we propose that TSR has played a key role in the formation of the sulfides in stage I. The δ34 S values of stage II sphalerite and pyrite(15.1 to 23.0‰) are between sulfides in the host rock, magmatic sulfur and the sulfate(barite) in the stratum. This result suggests that multiple S reservoirs were the sources for S2-in stage II. The δ34 S values of stage III(13.1 to 22‰) combined with the structure of the geological and mineral features suggest a magmatic hydrothermal origin of the mineralization. The lead isotope compositions of the sulfides have 206 Pb/204 Pb ranging from 17.9480 to 17.9782, 207 Pb/204 Pb ranging from 15.611 to 15.622, and 208 Pb/204 Pb ranging from 38.1368 to 38.1691 in the three ore-forming stages. The narrow and symmetric distributions of the lead isotope values reflect homogenization of granite and mantle sources before the Pb-Zn mineralization. The δ13 CPDB and δ18 OSMOW values of stage I range from-0.1 to 2.4‰ and from 18.8 to 21.7‰. The values and inclusion data indicate that the source of fluids in stage I was the dissolution of marine carbonate. The δ13 CPDB and δ18 OSMOW values of stage II range from-4 to 1‰ and from 12.3 to 20.3‰, suggesting multiple C-O reservoirs in the Changba deposit and the addition of mantle-source fluid to the system. The values in stage III are-3.1‰ and 19.7‰, respectively. We infer that the process of mineralization involved evaporitic salt and sedimentary organic-bearing units interacting through thermochemical sulfate reduction through the isotopic, mineralogy and inclusion evidences. Subsequently, the geology feature, mineral assemblages, EPMA data and isotopic values support the conclusion that the ore-forming hydrothermal fluids were mixed with magmatic hydrothermal fluids and forming the massive dark sphalerite, then yielding the calcite-quartz-sulfide vein ore type at the last stage. The genesis of this ore deposit was epigenetic rather than the previously-proposed sedimentary-exhalative(SEDEX) type.     

含铁闪锌矿热容的实验测定与分析

利用美国ＤｕＰｏｎｔ公司的９９００型差示扫描量热仪对３个含铁闪锌矿样品的热容进行了实验测定,并讨论了定压摩尔热容实验值与实验温度的关系。实验结果表明,在实验条件下,含铁闪锌矿的定压摩尔热容与纯闪锌矿的定压摩尔热容存在显著差异,Ｆｅ置换Ｚｎ是造成这种差异的主要原因。     

新疆可可塔勒铅锌成矿带成矿规律

阿尔泰山南缘可可塔勒铅锌成矿带主要由麦兹、克兰、冲乎尔 3个泥盆纪含矿火山沉积盆地组成 ,产于陆缘裂谷带内侧 (近陆一侧 ) ,下泥盆统康布铁堡组上亚组流纹—英安质火山沉积建造是主含矿层位。按特征矿物组合的不同可分为块状硫化物型、磁铁硫化物型和萤石方铅矿型 3个矿化类型。含矿盆地中规模较大的矿床产于断陷深度大、火山活动强烈的次级火山洼地中。铅锌矿化空间上具有南北分带、东西分区的分布规律性 ,时间上具有较明显的演化性 ,由早到晚 (层位自下而上 )典型的演化序列为 :Fe→ Fe、Pb、Zn→ Pb、Zn、Ag→Pb、Ag( F,Ba)。不同级别的构造控制了不同级别的矿化 ,构成了构造控矿系列     

秦岭地区铅锌矿成矿浅析

秦岭横亘中国中部,地跨七省,铅锌矿产资源成矿规律明显。迄今已探明３３个矿床,可划分八个成因类型,包括矽卡岩型,热液型,石英脉型,构造蚀变岩型,沉积型,火山沉积型,火山岩型及沉积再造型。     

辽宁早前寒武纪金、铜、铅、锌(银)矿床的变质成矿系列研究

金、铜、铅、锌(银)矿是辽宁地区的优势矿种,过去和现在都曾从多个不同角度或多个方面予以研究论述,但从成矿系列理论研究则是作者(1994)在Ⅱ轮区划工作中所做的一种新的尝试。根据程裕淇先生的成矿系列理论,辽宁地区早前寒武纪变质岩系中的金、铜、铅、锌(银)矿床属变质成矿系列组合,可进一步划分为三个成矿系列,六个成矿亚系列,九个矿床(种)类型和十二个矿床式。成矿系列特征表明成矿物质与原岩的含矿性关系非常密切,成矿物质或元素具有随原岩建造时空演化而演化的特点,成矿具有鲜明的专属性和层控性,是典型或比较典型的层控变质矿床。金矿床的形成和分布均与韧性剪切带及其糜棱岩有关,表明辽宁前寒武纪金矿床的形成不仅与变质作用有关,而且韧性剪切作用也是极其重要的成矿条件;铜、锌(银)和铅、锌(银)矿床以块状硫化物型为主,其成矿多与火山作用关系十分密切,变质作用过程中,发生重就位或再富集,或热液交代富集成矿。由太古宙至早元古代不同成矿系列或成矿亚系列中的矿床具有自下而上有序的空间分布规律。