峨眉山玄武岩与铅锌矿床成矿关系初探—以云南会泽铅锌矿床为例

本文以云南会泽铅锌矿为例，从成矿时代、成矿物来源、成矿流体来源和成矿热动力等方面初步讲座主峨眉山玄武岩与铅锌矿床成矿的关系。结果表明：矿床成矿时代可能与峨眉山玄武岩岩浆活动时代相近；峨眉山玄武岩在成矿过程中提供了部分成矿物质；伴随峨眉山玄武岩岩浆活动过程去气作用（包括地幔去气作用和岩浆去气作用）形成的流体参与了会泽铅锌矿成矿流体的形成；峨眉山玄武岩岩浆活动为成矿热动力的主要来源。     

末次冰盛期以来东北地区霍拉盆地湖泊沉积物记录的C3/C4植被演化

利用气相色谱-质谱（GC-MS）联用技术对我国大兴安岭北部霍拉盆地湖泊沉积物进行了有机分子地球化学分析,检测出了丰富的正构烷烃。本研究主要讨论了正构烷烃的分布特征及其长链正构烷烃的单体碳同位素组成,结合AMS ¹⁴C年代数据,重建中国东北大兴安岭地区末次冰盛期以来的古植被及古气候变化。正构烷烃分布特征表明,末次冰盛期以来,霍拉盆地湖沼沉积物长链正构烷烃呈现明显的奇碳优势,主峰碳主要为nC₃₁,指示有机质主要来源于陆生高等植物,且草本植物输入占优势,木本植物输入丰富。陆生高等植物来源的长链正构烷烃单体稳定碳同位素的记录显示,末次冰盛期晚期以来古莲剖面沉积物长链正构烷烃（nC₂₇、nC₂₉和nC₃₁）稳定碳同位素整体偏负;此外,利用二元模式估算了C₃/C₄植物相对生物量,结果表明,自末次冰盛期以来我国东北大兴安岭地区C₃植物占绝对优势,然而在全新世大暖期C₄植物生物量呈现明显扩张趋势,这表明气候变暖对C₄植物量的增加有重要影响。

     

Genetic significance of fluid inclusions in the CSA Cu–Pb–Zn deposit, Cobar, Australia

CSA mine exploits a ‘Cobar-type’ Cu–Pb–Zn±Au±Ag deposit within a cleaved and metamorphosed portion of the Cobar Supergroup, central New South Wales. The deposit comprises systems of ‘lenses’ that encompass veins, disseminations and semi-massive to massive Cu–Pb–Zn ores. The systems and contained lenses truncate bedding, are approximately coplanar with regional cleavage and similarly oriented shear zones and plunge parallel to the elongation lineation. Systems have extreme vertical continuity (>1000 m), short strike length (400 m) and narrow width (100 m), exhibit vertical and lateral ore-type variation and have alteration haloes. Models of ore formation include classical hydrothermalism, structurally controlled remobilisation and polymodal concepts; syntectonic emplacement now holds sway.Fluid inclusions were examined from quartz±sulphide veins adjacent to now-extracted ore, from coexisting quartz–sulphide within ore, and from vughs in barren quartz veins. Lack of early primary inclusions precluded direct determination of fluids associated with D₂–D₃ ore and vein emplacement. Similarly, decrepitation (by near-isobaric heating) of the two oldest secondary populations precluded direct determination of fluid phases immediately following D₂–D₃ ore and vein emplacement. Post-decrepitation outflow (late D₃ to early post-D₃) is recorded by monophase CH₄ inclusions. Entrained outflow of deeply circulated meteoric fluid modified the CH₄ system; modification is recorded by H₂O+CH₄ and H₂O+(trace CH₄) secondary populations and by an H₂O+(trace CH₄) primary population. The contractional tectonics (D₂–D₃) of ore emplacement was superseded by relaxational tectonics (D_4P) that facilitated meteoric water penetration and return flow.Under D₂ prograde metamorphism, entrapment temperatures (Tt) and pressures (Pt) for pre-decrepitation secondary inclusions are estimated as Tt300–330 °C and Pt1.5–2 kbar≈Plith (the lithostatic pressure). Decrepitation accompanied peak metamorphism (T350–380 °C) in mid- to late-D₃, while in late-D₃ to early post-D₃, essentially monophase CH₄ secondary inclusions were entrapped at Tt350 °C and Pt=1.5–2 kbar≈Plith. Subsequently, abundant CH₄ and entrained meteoric water were entrapped as H₂O+CH₄ secondaries under slowly decreasing temperature (Tt330–350 °C) and constant pressure (Pt1.5–2 kbar). Finally, with increasingly dominant meteoric outflow, H₂O+(trace CH₄) populations record decreasing temperatures (Tt>300 to <350 down to 275–300 °C) at pressures of Phydrostatic<Pt (1 kbar) <Plith (1.5 kbar).The populations of inclusions provide insight into fluid types, flow regimes and P–T conditions during parts of the deposit's evolution. They indirectly support the role of basin-derived CH₄ fluids in ore formation, but provide no insight into a basement-sourced ore-forming fluid. They fully support post-ore involvement of meteoric water. The poorly constrained entrapment history is believed to span 10 Ma from 395 to 385 Ma.     

Comparison of Cu and Zn cycling in eutrophic lakes with oxic and anoxic hypolimnion

Data on the cycling of Cu and Zn in two eutrophic lakes are presented: Lake Greifen that becomes seasonally anoxic in its hypolimnion and Lake Sempach that is aerated during winter and oxygenated during summer. They suggest that hypolimnetic oxygenation 1) enhances the release of copper from the sediment but 2) also accelerates the entrapment and deposition of Cu and Zn by freshly formed Mn- and Fe-oxides.     

小冰期十年际尺度亚洲季风变化的四川黑竹沟洞石笋记录

基于四川省黑竹沟洞一支石笋（编号：EB1）高精度²³⁰Th年龄和氧同位素数据,建立小冰期时期（1375~1810A.D.）气候变化时间序列。该序列δ¹⁸O值变化范围为-10.37‰~-8.58‰,敏感响应于区域气候变化过程。高分辨率δ¹⁸O变化序列能清晰地捕捉到10年际尺度振荡旋回。该石笋记录根据δ¹⁸O值变化可分为4个阶段：1375~1540A.D.和1680~1780A.D.时段,δ¹⁸O值整体偏负,指示季风增强时期;1540~1680A.D.和1780~1810A.D.时段,δ¹⁸O值整体偏正,处于弱季风阶段。与贵州董哥洞、甘肃万象洞和印度Jhumar洞石笋记录对比发现在小冰期时期δ¹⁸O变化特征具有一定的相似性,表明上述区域降水可能共同受控于印度季风水汽输送影响,反映了区域性夏季风经向环流及其降水变化特征。通过EB1石笋记录与北半球温度曲线的对比发现,两者在百年尺度上同相位变化,可能指示北高纬气候的控制作用。而该石笋与秘鲁东北部Cascayunga洞石笋记录的进一步对比结果显示亚洲季风与南半球季风记录呈反相位关系,证实了ITCZ位置的南北移动在半球间能量传递和交换过程中的重要作用。功率谱分析结果显示小冰期季风波动具有显著的25a和9a周期旋回,接近太阳黑子22a和11a周期频率,表明太阳活动变化可能是小冰期十年际尺度亚洲季风波动的重要驱动因素。

     

云南兰坪中排李子坪铅锌矿矿床成因

铅锌矿产于下白垩统景星组下段泥质粉砂岩、钙质砂岩和中侏罗统花开左组上段砂岩夹薄层泥灰岩介壳灰岩中,脉状、透镜状、层状、似层状等产出。NNE向断裂的交叉夹持部位的旁侧派生次级断裂及层间破碎带是主要容矿构造,矿床成因为沉积-中低温热液改造构造控矿型。     

碳酸盐岩碳同位素地层学研究中数据的有效性

碳酸盐岩碳稳定同位素组成数据能否有效地反应原始大洋的同位素组成是稳定同位素地层学研究成败的关键,因此,如何准确地判断碳同位素比值的有效性成为该稳定同位素地层学研究中的焦点问题之一。碳同位素值有效性受成岩作用、地层缺失、样品处理过程等多方面因素影响,但成岩作用是诸多因素中最普遍、最主要的,因而正确判别碳同位素值可靠性通常也就是对样品及其同位素组成经受成岩改造程度的评定。确保碳同位素测试结果可靠应主要把握前期严格选样和后期数据分析两个重要环节。前期选样包括野外和室内两步,是在宏观尺度上对数据可靠性的把握;后期数据分析则主要是在严格选样的基础上,利用碳(及附带的氧)同位素自身数据特征以及借助Mn、Fe、Sr等微量元素特征从元素级别的微观角度对同位素值有效性做出进一步判别。     

热液脉型铅-锌-银矿床富铁闪锌矿中硫化物包裹体成因探讨

通过对热液脉型的铅－锌－银矿床（３个）和银矿床（１个）和闪锌矿中硫化物包囊体的特征研究表明,石英－硫化物阶段富铁闪锌矿（主矿物）的硫化物包裹体十分发育：沿生长带产出的乳滴状黄铜矿与主矿物为共同沉淀成因;沿穿切主矿物的黄铜矿或石英细脉两侧,和受粗粒黄铜矿溶蚀的富铁闪锌矿近接触部位发育的乳滴状黄铜矿为渗透－交代产物;沿解理（裂隙）或粒间、粒内产出的各种形态磁黄铁矿是充填－交代的结果;沿解理分布的脉状毒     

近400年来新疆策勒红柳沙包稳定氧同位素与气候变化

建立红柳沙包沉积纹层年代序列和提取气候环境信息是高分辨率古气候环境变化研究的重要手段。利用策勒达玛沟红柳沙包高度约450 cm沉积纹层红柳落叶的稳定氧同位素数据,结合策勒气象站1960~2011年观测数据,运用移动平均法对稳定氧同位素和气象数据进行平滑处理后,运用相关分析及逐步回归法,定量重建了策勒地区近400年来的4月平均气温和3月降水量序列。研究结果表明:红柳落叶δ^18O平均值为33.96‰,波动范围为27.18‰~44.07‰,波动幅度为16.89‰,δ^18O变化受多个气候要素的综合影响。δ^18O与4月平均气温呈显著负相关,与2月和12月平均气温呈显著正相关;δ^18O与10月、4月、5月、9月、7月以及全年的空气相对湿度呈显著正相关;δ^18O与3月、9月和8月的降水量呈显著正相关,与2月降水量呈显著负相关;δ^18O与2月日照时数呈显著正相关,与9月和10月的日照时数呈显著负相关。策勒地区近400年来气候变化可划分4个阶段:1635~1725年为暖干期,1726~1792年为冷湿期,1793~1897年为暖干期,1898~2009年为冷湿期。     

Geological and C–O–S–Pb–Sr isotopic constraints on the origin of the Qingshan carbonate-hosted Pb–Zn deposit,Southwest China

Located in the western Yangtze Block, the Qingshan Pb–Zn deposit, part of the Sichuan–Yunnan–Guizhou Pb–Zn metallogenic province, contains 0.3 million tonnes of 9.86 wt.% Pb and 22.27 wt.% Zn. Ore bodies are hosted in Carboniferous and Permian carbonate rocks, structurally controlled by the Weining–Shuicheng anticline and its intraformational faults. Ores composed of sphalerite, galena, pyrite, dolomite, and calcite occur as massive, brecciated, veinlets, and disseminations in dolomitic limestones.

The C–O isotope compositions of hydrothermal calcite and S–Pb–Sr isotope compositions of Qingshan sulphide minerals were analysed in order to trace the sources of reduced sulphur and metals for the Pb–Zn deposit. δ¹³C_PDB and δ¹⁸O_SMOW values of calcite range from –5.0‰ to –3.4‰ and +18.9‰ to +19.6‰, respectively, and fall in the field between mantle and marine carbonate rocks. They display a negative correlation, suggesting that CO₂ in the hydrothermal fluid had a mixed origin of mantle, marine carbonate rocks, and sedimentary organic matter. δ³⁴S values of sulphide minerals range from +10.7‰ to +19.6‰, similar to Devonian-to-Permian seawater sulphate (+20‰ to +35‰) and evaporite rocks (+23‰ to +28‰) in Carboniferous-to-Permian strata, suggesting that the reduced sulphur in hydrothermal fluids was derived from host-strata evaporites. Ores and sulphide minerals have homogeneous and low radiogenic Pb isotope compositions (²⁰⁶Pb/²⁰⁴Pb = 18.561 to 18.768, ²⁰⁷Pb/²⁰⁴Pb = 15.701 to 15.920, and ²⁰⁸Pb/²⁰⁴Pb = 38.831 to 39.641) that plot in the upper crust Pb evolution curve, and are similar to those of Devonian-to-Permian carbonate rocks. Pb isotope compositions suggest derivation of Pb metal from the host rocks. ⁸⁷Sr/⁸⁶Sr ratios of sphalerite range from 0.7107 to 0.7136 and (⁸⁷Sr/⁸⁶Sr)_200Ma ratios range from 0.7099 to 0.7126, higher than Sinian-to-Permian sedimentary rocks and Permian Emeishan flood basalts, but lower than Proterozoic basement rocks. This indicates that the ore strontium has a mixture source of the older basement rocks and the younger cover sequence. C–O–S–Pb–Sr isotope compositions of the Qingshan Pb–Zn deposit indicate a mixed origin of the ore-forming fluids and metals.