Celestite formation, bacterial sulphate reduction and carbonate cementation of Eocene reefs and basinal sediments (Igualada, NE Spain)

Petrographic and geochemical studies of an Upper Eocene reef and associated basinal sediments from the mixed carbonate–siliciclastic fill of the south‐eastern Pyrenean foreland basin near Igualada (NE Spain) provide new insights into the evolution of subsurface hydrology during the restriction of a marine basin. The reef deposits are located on delta‐lobe sandstones and prodelta marls, which are overlain by hypersaline carbonates and Upper Eocene evaporites. Authigenic celestite (SrSO₄) is an important component in the observed diagenetic sequences. Celestite is a significant palaeohydrological indicator because its low solubility constrains transportation of Sr²⁺ and SO₄^2? in the same diagenetic fluid. Stable isotopic analyses of carbonates in the reef indicate that meteoric recharge was responsible for aragonite stabilization and calcite cementation. Sulphur and oxygen isotope geochemistry of the celestite demonstrates that it formed from residual sulphate after bacterial sulphate reduction, but also requires that there was a prior episode of sulphate recycling. Meteoric water reaching the reef and basinal areas was most probably charged with SO₄^2? from the dissolution of younger Upper Eocene marine evaporites. This sulphate, combined with organic matter present in the sediments, fuelled bacterial sulphate reduction in the meteoric palaeoaquifer. Strontium for celestite precipitation was partly derived in situ from dissolution of aragonite corals in the reef and basinal counterparts. However, ⁸⁷Sr/⁸⁶Sr data also suggest that Sr²⁺ was partly derived from dissolution of overlying evaporites. Mixing of these two fluids promoted celestite formation. The carbonate stable isotopic data suggest that the local meteoric water was enriched in ¹⁸O compared with that responsible for stabilization of other reefs along the basin margin. Furthermore, meteoric recharge at Igualada post‐dated evaporite deposition in the basin, whereas other parts of the same reef complex were stabilized before evaporite formation. This discrepancy resulted from the spatial distribution of continental siliciclastic units that acted as groundwater conduits.     

Sulfur Content and Isotopic Ratio of Cambro-Ordovician Carbonate Rocks from South Korea: A Possible Source for Mesozoic Magmatic-hydrothermal Ore Sulfur

Abstract: Carbonate rocks of Cambrian (18 samples) and lower-middle Ordovician (11 samples) ages from South Korea were analyzed for sulfur contents of structurally substituted sulfate (SSS) and sulfides and their δ³⁴S values. The δ³⁴S values of SSS ranging from +25.9 to +45.2 permil, are averaged as +33.6 and +33.5 permil for the Cambrian and Ordovician rocks, respectively, which indicate high δ³⁴S values of the Cambro-Ordovician seawater. The SSS contents in the carbonate rocks are low being 2.9 to 17.3 ppm S (averaged as 7.0 ppm S). Sulfide sulfur, on the contrary, is much abundant containing 3 to 1,880 ppm S and the δ³⁴S values range widely between –17.6 and +31.1 permil. Sulfide sulfur of the studied rocks excluding impure carbonates has an average content of 187 ppm S and δ³⁴S value of +12.8 permil (n=24). The estimated δ³⁴S (sulfate–sulfide) values, which range from 13.8 to 25.4 permil in general with a few exceptions from 36.5 up to 52.3 permil for some impure carbonates, may provide evidence for the persistent oceanic anoxia with its temporary recovery during the Cambro-Ordovician time.
The SSS and sulfide sulfurs have often higher δ³⁴S values than the Mesozoic-Cenozoic ore sulfur (Ishihara et al., 2000). Since carbonate rocks are very reactive with circulating hydrothermal ore solution, high δ³⁴S values of the Korean ore deposits might be caused to some extent by ³⁴S enrichment from the host carbonates, resulting in the low SSS contents observed.     

Modelling of meteorological conditions at an urban scale for the PUMA winter campaign

For the winter 2000 campaign of the Pollution of Urban Midlands Atmosphere project, observation and numerical modelling of meteorological conditions over the West Midlands conurbation, UK, was undertaken. Modelling was performed using the regional atmospheric meteorological system (RAMS). This paper presents a comparison of modelled and observed wind and temperature for 25 and 26 January 2000. The RAMS model uses two nested grids with a mesh size of 2 km for the inner grid which is embedded in the outer grid with a mesh size of 8 km. Statistical evaluation of the model results against the observational data of wind speed, direction and temperature at 10 m was conducted. In general, the modelling results are in a reasonable agreement with observation. The statistical evaluation suggests that model performance is poorer for the inner grid than the outer grid as the model uncertainties (mainly mean bias) transfer from the outer to inner one. The low indices of agreement of temperature and wind are mainly associated with the systematic root-mean-square-difference values. For temperature, the systematic bias may also be affected by representation of cloud amount by the model. For wind, the model tends to have a poor performance for calm conditions, as under a stable anti-cyclonic situation local wind patterns associated with topography may develop, although the topography of the region is relatively flat. The results for the inner grid reveal some subtle spatial patterns at a scale smaller than 10 km near hills and valleys with differences in elevation of a few hundred metres.     

Development and testing of numerical methods for two-way nested air pollution modelling

A new 3-D model REGINA (REGIonal high resolutioN Air pollution model) is under development at the National Environmental Research Institute (NERI). The model is based on pieces from several models developed over the last decades at NERI. The aim of the work is to develop a nested model which can operate with very high resolution in both space and time. To fulfill this aim the choice and implementation of accurate numerical methods is crucial. The model will be applied for studying air pollution phenomena (both monitoring, forecasting and scenarios) over Denmark. The present paper is focussed on the modification, implementation and testing of a numerical method for treating the horizontal advection in the model as well as the implementation of two-way nesting techniques. The horizontal transport in the model is solved using an accurate space derivative algorithm. This method is traditionally implemented with periodic boundary conditions, however, this is not an option for nested modelling. A new method for calculating non-periodic boundary conditions has been developed in order to overcome this problem. Extensive testing of the numerical solution of the advection and the coupling of the solution of advection and chemistry in the model using Molenkamp–Crowley rotation tests have been carried out. The results show that the model with the current implementation of numerical methods is suitable for calculating air pollution levels with high resolution.     

用ANSYS模拟结构-地基动力相互作用振动台试验的建模方法

本文以结构－地基动力相互作用振动台模型试验为基础，结合通用有限元软件ANSYS，对结构－地基动力相互作用体系进行有限元计算建模的一些问题作了研究，主要包括柔性土容器的模拟、土体动力本构模型的选用、土体与结构交界面上的状态非线性模型、网格划分、重力的考虑、结构中钢筋的处理以及对称性的应用等。文中给出了利用上述建模方法对结构－地基动力相互作用体系进行计算的一些加速度时程结果，并与试验结果相对照，吻合较好。通过计算分析，验证了简化处理方法的合理性和计算模型的可行性。     

基于GTP的地下工程与围岩一体化真三维空间构模

针对地下工程开挖体的基本特征及其真三维建模要求，在广义三棱柱(GTP)模型的基础上进行扩展，提出采用E—GTP模型来构建地下工程开挖体的真三维模型。通过与其围岩地质体的G—GTP模型的耦合，实现了基于GTP的工程开挖体与围岩地质体的一体化建模。该模型将地下三维空间实体抽象为点、线、面、体四类对象，通过结点、TIN边、侧边、TIN面、侧面和GTP体元共6个基本几何元素进行统一表达。该文重点讨论了E—GTP的建模原理与方法，并介绍了基于面向对象思想的一体化空间数据结构。     

我国入境旅游的特点和发展趋势分析

入境旅游人数以及旅游(外汇)收入是衡量一个国家旅游实力和开放程度的重要指标。本文在回顾中国入境旅游发展历史的基础上，通过对我国20多年入境旅游方面有关指标的分析总结了我国入境旅游具有增长的持续性、波动性和阶段性，入境旅游发展的脆弱性和集中性等特点。针对入境旅游未来的发展趋势提出加快我国入境旅游发展的建议。     

不同浓度Li2SO4水溶液结构的X射线衍射研究

用θ～ 2θ型粉末衍射仪反射法精确测量了不同浓度的Li2 SO4水溶液的衍射数据 ,通过数据处理给出了溶液的结构函数和径向分布函数 ,由几何结构模型的最小二乘法精修 ,得到了溶液中阳离子和阴离子第一、二水合层的结构参数。     

原子荧光光谱法测定地球化学样品中的砷、锑和汞的方法改进

在原子荧光光谱法中，通过改进地球化学样品的分解条件，预还原条件及测定条件，使砷、锑和汞能在同一介质中测定，而且实现了砷与汞的双道同时测定。方法的检测出限、准确度及精密度均能达到行业要求。     

b值在地震预测中的三类应用及其物理基础与须注意的问题

将b值在地震预测中的直接应用归为三类：1）根据b值的动态变化预测地震。2）根据G－R律求出各级地震平均复发周期或年均发生率，推测未来一定时段如50年或100年内发生各级地震的危险性。3）根据G－R直线在横轴的截距，预测强余震的震级。讨论了这三种用法的物理基础及现有工作中容易出现的问题。